Regionalization of unit hydrograph Parameters: 2. Uncertainty analysis

Hydrologic model parameters obtained from regional regression equations are subject to uncertainty. Consequently, hydrologic model outputs based on the stochastic parameters are random. This paper presents a systematic analysis of uncertainty associated with the two parameters, N and K, in Nash's IUH model from different regional regression equations. The uncertainty features associated with N and K are further incorporated to assess the uncertainty of the resulting IUH. Numerical results indicate that uncertainty of N and K from the regional regression equations are too significant to be ignored.     

河北唐山地区中寒武统张夏组鲕粒灰岩的岩石学研究

本区张夏组鲕粒灰岩内,广泛见到细径放射鲕和较粗的同心-放射鲕.放射鲕中存在连生体,我们称之“连生鲕”.与赵震等(1984)人工合成的静水鲕对比,区内放射鲕亦系静水条件下生成;因未见长串连生体,仅呈现数鲕(2—4个)连生,表明鲕粒生成后遭到搅动水拆开.由此可以认为,本组鲕粒灰岩属间歇高能成因模式的产物。又按该类岩石显示的成岩特征,可知本区鲕粒灰岩经历过多种成岩环境,至今仍保留较为明显的大气成岩环境的标志.     

鄂尔多斯盆地南部延长组富铀凝灰岩地球化学特征及形成机制

本文系统地研究了鄂尔多斯盆地南部延长组凝灰岩元素和同位素地球化学特征。结果表明：凝灰岩主量元素具有高K、高Al、Si中等至高、低Na的特征; REE总体特征为轻稀土富集、重稀土亏损,∑REE在4857～40212 μg/g 之间变化,Eu呈现出负异常,在034～082内变化,δCe范围在080～208之间; 微量元素中U含量在312～144 μg/g 之间,Ba、U、Th、Hf和Ce呈明显正异常,Nb、P、Ti和Rb呈现负异常。详细的分析表明：U的富集和一些微量元素如Ta、Dy、Lu等相关,Th与∑REE存在明显的正相关性,这些变化可能和盆地中铀矿的富集有关; 凝灰岩的硫同位素总体呈现深源特征。根据以上的研究对凝灰岩的形成原因及形成环境进行了探讨。鄂尔多斯盆地南部延长组凝灰岩来源于秦岭造山带火山作用,其中的铀元素富集是由于砂岩型铀矿中铀向凝灰岩迁移而被还原所致。本研究对盆地砂岩型铀矿的铀运移和富集机理认识具有一定指导意义。     

浅谈灰土挤密桩与DDC桩在工程实践中应用与发展

DDC桩是挤密桩的一种新型桩。根据宝鸡某大型电厂中DDC桩与灰土挤密桩地基处理工程实例,从挤密机理、挤密效果、复合地基承载力与抗变形性状及复合地基浸水稳定性等诸方面进行了系统地分析对比,进而探讨挤密桩地基的应用与发展。     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

石笋记录的西南地区MIS4阶段夏季风的演化

基于重庆市丰都县羊子洞石笋Y-02的12个²³⁰Th年龄和503个氧同位素数据重建了中国西南地区60~73ka B.P.时段夏季风的演化历史。Y-02的δ¹⁸O记录显示中国季风区D/O18、D/O19a和D/O19共3个千年尺度夏季风增强事件与格陵兰间冰阶（GIS）18~19相对应。此外,Y-02记录显示：紧接着D/O18事件以后,夏季风强度突然减弱,而此时北半球高纬度地区正经历着明显的降温过程。Y-02记录捕捉到的这次东亚夏季风突然且短暂的一次减弱过程,可能是H6事件或者是H6事件季风最弱的时段。Y-02的δ¹⁸O记录显示,D/O18事件是一次较强烈的千年尺度季风增强事件,持续时间近千年,而D/O19事件在持续时间和强度上不如D/O18事件,这不同于格陵兰冰芯记录。中国季风区气候变化与格陵兰地区存在着如此紧密的联系进一步支持：东亚夏季风演化受到北半球高纬度地区气候变化的影响,但是对具体的气候事件响应可能存在不同的模式。

     

On Evaluating Characteristics of the Solute Transport in the Arid Vadose Zone

The transport of bromide (Br) under matric heads of 0, ?2, ?5, and ?10 cm using undisturbed soil columns was investigated for understanding the solute transport in arid soils. Undisturbed soil cores were collected at ground surface, directly below where tension infiltrometer measurements were made in the Amargosa Desert, Nevada, United States. Laboratory experiments were conducted by introducing water containing Br tracer into a soil column maintained at steady‐state conditions. The observed data of breakthrough curves (BTC) were well fitted to an one‐region model, except for the cores at saturation, and a core at the matric head of ?5 cm, from which the observed data were better fitted to a two‐region model. Fitted pore water velocities with the one‐region model ranged from 1.2 to 56.6 cm/h, and fitted dispersion coefficients (D) ranged from 2.2 to 100 cm²/h. Results for the core analyzed with the two‐region model indicated that D ranged from 27.6 to 70.9 cm²/h at saturation, and 25.7 cm²/h at the matric head of ?5 cm; fraction of mobile water (β) ranged from 0.18 to 0.65, and mass transfer coefficient (ω) ranged from 0.006 to 0.03. In summary, the water fluxes and Br dispersion coefficients at investigated matric heads were very high due to the coarseness of the soils and possibly due to preferential flow pathways. These high water fluxes and Br dispersion coefficients would lead to a higher risk of deeper leaching accumulating nitrate nitrogen to the groundwater, and have significant effects on the desert ecosystem.     

关于垃圾填埋场渗滤系统渗透性能经时变化的研究

利用模拟实验对垃圾填埋场中渗滤系统的渗透性能与填埋时间的关系进行了研究。采用焚烧灰、土工织物和碎石导流层组成渗透系统,研究了实验时间对渗滤系统的渗透系数以及结晶物颗粒直径的影响。结果表明:由于垃圾焚烧灰中硅酸钙和铝酸钙的结晶作用,随着渗透时间的增加,吸附在土工织物表面的物质逐渐增多,使颗粒之间更紧密,导致空隙减小影响渗滤系统的渗透性能。根据研究结果,在垃圾焚烧灰填埋时,垃圾焚烧灰压实密度不要太高,这样有利于渗滤液的排放。     

Relationship Between Land Cover Ratio and Urban Heat Island from Remote Sensing and Automatic Weather Stations Data

Urban heat island (UHI) effect has a close relation to land covers type. This paper investigates the relationship between land cover ratio and UHI in Guangzhou, south of China using remote sensing and automatic weather stations data. The temperature data were obtained by Automatic weather stations (AWS) of Guangzhou in October, 2004, at the same time with the CBERS remote sensing image acquired. Firstly, the hourly mean temperature was computed from hourly AWS data. Secondly, the CBERS remote sensing image was classified using support vector machine (SVM) and land covers classification were output. Thirdly, the classification result was overlapped with a round buffer with 1.5 KM radius centered on the AWS, and then the land cover ratio, Edge Density (ED) and Mean Fractal Dimension (MFRACT) of buffers were computed out. Finally, the correlation coefficient between hourly mean temperature and land cover ratio, ED and MFRACT was calculated. It concluded that UHI intensity was heavier during nighttime than daytime. Stations with higher vegetation ratio and higher ED had lower heat island effect. On the contrary, stations with higher impervious ratio and lower ED had more serious heat island effect. The positive–negative of correlation coefficient between hourly mean temperature and vegetation ratio during 11:00–17:00 h (local time) was opposite to that during other time. ED was negatively correlated with hourly mean temperature except during 11:00–17:00 h. On the contrary, MFRACT was positively correlated with hourly mean temperature. It implied that fragmentations of patches were favorable to UHI alleviation, and complexities of patch were unfavorable factors.