Groundwater-flow modeling in the Yucatan karstic aquifer, Mexico

The current conceptual model of the unconfined karstic aquifer in the Yucatan Peninsula, Mexico, is that a fresh-water lens floats above denser saline water that penetrates more than 40 km inland. The transmissivity of the aquifer is very high so the hydraulic gradient is very low, ranging from 7–10 mm/km through most of the northern part of the peninsula. The computer modeling program AQUIFER was used to investigate the regional groundwater flow in the aquifer. The karstified zone was modeled using the assumption that it acts hydraulically similar to a granular, porous medium. As part of the calibration, the following hypotheses were tested: (1) karstic features play an important role in the groundwater-flow system; (2) a ring or belt of sinkholes in the area is a manifestation of a zone of high transmissivity that facilitates the channeling of groundwater toward the Gulf of Mexico; and (3) the geologic features in the southern part of Yucatan influence the groundwater-flow system. The model shows that the Sierrita de Ticul fault, in the southwestern part of the study area, acts as a flow barrier and head values decline toward the northeast. The modeling also shows that the regional flow-system dynamics have not been altered despite the large number of pumping wells because the volume of water pumped is small compared with the volume of recharge, and the well-developed karst system of the region has a very high hydraulic conductivity. Electronic Publication     

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.     

Geomagnetic Effects of Corotating Interaction Regions

We present an analysis of the geoeffectiveness of corotating interaction regions (CIRs), employing the data recorded from 25 January to 5 May 2005 and throughout 2008. These two intervals in the declining phase of Solar Cycle 23 are characterised by a particularly low number of interplanetary coronal mass ejections (ICMEs). We study in detail how four geomagnetic-activity parameters (the Dst, Ap, and AE indices, as well as the Dst time derivative, \(\mathrm{dDst}/\mathrm{d}t\)) are related to three CIR-related solar wind parameters (flow speed, \(V\), magnetic field, \(B\), and the convective electric field based on the southward Geocentric solar magnetospheric (GSM) magnetic field component, \(\mathit{VB}_{s}\)) on a three-hour time resolution. In addition, we quantify statistical relationships between the mentioned geomagnetic indices. It is found that Dst is correlated best to \(V\), with a correlation coefficient of \(\mathrm{cc}\approx0.6\), whereas there is no correlation between \(\mathrm{dDst}/\mathrm{d}t\) and \(V\). The Ap and AE indices attain peaks about half a day before the maximum of \(V\), with correlation coefficients ranging from \(\mathrm{cc}\approx0.6\) to \(\mathrm{cc}\approx0.7\), depending on the sample used. The best correlations of Ap and AE are found with \(\mathit{VB}_{s}\) with a delay of 3 h, being characterised by \(\mathrm{cc}\gtrsim 0.6\). The Dst derivative \(\mathrm{dDst}/\mathrm{d}t\) is also correlated with \(\mathit{VB}_{s}\), but the correlation is significantly weaker \(\mathrm{cc}\approx 0.4\)?–?0.5, with a delay of 0?–?3 h, depending on the employed sample. Such low values of correlation coefficients indicate that there are other significant effects that influence the relationship between the considered parameters. The correlation of all studied geomagnetic parameters with \(B\) are characterised by considerably lower correlation coefficients, ranging from \(\mathrm{cc}=0.3\) in the case of \(\mathrm{dDst}/\mathrm{d}t\) up to \(\mathrm{cc}=0.56\) in the case of Ap. It is also shown that peak values of geomagnetic indices depend on the duration of the CIR-related structures. The Dst is closely correlated with Ap and AE (\(\mathrm{cc}=0.7\)), Dst being delayed for about 3 h. On the other hand, \(\mathrm{dDst}/\mathrm{d}t\) peaks simultaneously with Ap and AE, with correlation coefficients of 0.48 and 0.56, respectively. The highest correlation (\(\mathrm{cc}=0.81\)) is found for the relationship between Ap and AE.     

Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.     

Monitoring of landslide displacements using UAS and control methods based on lines

This study describes a new methodology for monitoring landslide displacements using a set of linear elements included in the terrain. These linear elements are digitized using the products obtained from several photogrammetric flights implemented by means of unmanned aircraft systems in several dates. The control of the displacements between dates is carried out using some new metrics and methods based on lines. The results of the control of the lines are used to analyse the general and particular behaviour of the landslide. Using this type of elements allows us to study some singular behaviour of linear elements included in the landslides (e.g. an affected road can react as a block). The methodology has been tested with success using a real case of an active slope with several landslides which was studied on three separate dates. The results have demonstrated the viability of using this methodology for studying the evolution of the landslides and their consequences regarding certain elements included in the terrain.     

Episodic Biogeochemical Variability in a Low-Flow Mediterranean Estuary

To investigate to what extent episodic physical processes regulate nutrient availability and phytoplankton assemblages of the Mahon estuary (Minorca Island), we carried out an intensive field study during 2010–2011. During the study period, environmental conditions spanned from intense stratification to a continuous mixing and from lack of riverine inflow to intense runoff. Our data reveals a sequence of biogeochemical states of the estuary that result from the interplay between runoff, other non-periodic forcings (winds, sea level oscillations), and variations in water renewal. Seasonal runoff was revealed as a major driver of winter circulation and of the influx of inorganic nutrients, in particular nitrate. However, because of the combination between runoff and flushing time, the effects of floodwater events on phytoplankton are short-lived (days). Conversely, during summer, when freshwater influx declines, water renewal relies on pulsed atmospheric forcing that may be of local or remote origin. As depicted from the low nitrate concentrations (<1 μM) and enhanced ammonium (>1 μM), this change in circulation and external loads carries nutrient assimilation within the estuary head and forces the use of remnant nutrients through regenerating pathways to sustain an enhanced phytoplankton biomass at the lower estuary. Episodic variability represented between 52 and 65% of the annual chlorophyll variance. Despite the fact that episodic pulses represented intense departures from base biogeochemical state of the estuary, at time scale larger than weeks, the phytoplankton community composition and dynamics was largely regulated by the integrated effect of these episodes and other environmental drivers associated with seasonality rather than by individual storm events only. Our results suggest that even though the system presents good recovery capacity to individual storm episodes, it may be more vulnerable to increased nutrient fluxes during summer, as well as to changes in episode timing and frequency.     

Kinetic,equilibrium and thermodynamic studies of thiamethoxam adsorption by multi-walled carbon nanotubes

Because of their high adsorption capacity, carbon nanotubes have caught the attention of the scientific community and a number of experimental results confirmed their ability to adsorb many toxins from water. The aim of this work was to study the kinetics, equilibrium and thermodynamics of thiamethoxam adsorption by multi-walled carbon nanotubes in aqueous solutions. To further elucidate the influence of nanotube structure on the adsorption mechanism, the experiments were performed on both fresh (pristine) and nitric acid-modified multi-walled carbon nanotubes. The results of the kinetic studies were analyzed using three kinetic models, while the adsorption equilibrium was tested against four different adsorption models. Based on the results, and the physico-chemical properties of the adsorbent and adsorbate, it is proposed that the dominant mechanism for thiamethoxam molecules attaching to multi-walled carbon nanotubes is caused by aromatic π–π interactions (electron donor–acceptor interactions). The results of thermodynamic calculations based on the adsorption data indicate the exothermic nature of the process, regardless of the carbon nanotube type used. The decrease in entropy and the consequent negative change in Gibbs free energy, as expected, confirm the spontaneity of thiamethoxam adsorption on both pristine and functionalized multi-walled carbon nanotubes.