Neutron activation analysis of the 1965 taal volcanic ash

Neutron activation analysis of the Taal volcanic ash revealed the presence of unusual amount of scandium in the volcanic ash as compared to the standard basalt BCR-1. The BCR-1 value for Fe/Sc is 2760 while that of Taal ash is about 2649. It is suggested that the eruption was probably characterized by the ejection of scandium-rich materials. Scandium may be used as supplementary evidence in evaluating an impending future Taal volcanic activity.     

Numerical modelling of aeolian erosion over a surface with non‐uniformly distributed roughness elements

The present study is focused on the analysis of the mean wall friction velocity on a surface including roughness elements exposed to a turbulent boundary layer. These roughness elements represent non‐erodible particles over an erodible surface of an agglomeration of granular material on industrial sites. A first study has proposed a formulation that describes the evolution of the friction velocity as a function of geometrical parameters and cover rate with different uniform roughness distributions. The present simulations deal with non‐uniform distributions of particles with a random sampling of diameters, heights, positions and arrangements. The evolution (relative to geometrical parameters of the roughness elements) of the friction velocity for several non‐uniform distributions of roughness elements was analysed by the equation proposed in the literature and compared to the results obtained with the numerical simulations. This comparison showed very good agreement. Thus, the formulation developed for uniform particles was found also to be valid for a larger spectrum of particles noted on industrial sites. The present work aims also to investigate in detail the fluid mechanics over several roughness particles. Copyright © 2013 John Wiley & Sons, Ltd.     

Seasonal variability in somatic and reproductive investment of the bivalve Scrobicularia plana (da Costa, 1778) along a latitudinal gradient

Monthly investment in soma and gonads in the bivalve Scrobicularia plana is described for three populations along its distributional range: Minho estuary, Portugal; Westerschelde estuary, The Netherlands and Buvika estuary, Norway. Seasonal cycles in body mass (BMI), somatic mass (SMI) and gonadal mass (GMI) indices were observed for all populations. In Portugal, BMI and SMI peaked in mid-autumn, while in The Netherlands both indices were at their highest in mid-spring. Norway showed a different pattern with two distinct peaks: one in mid-autumn and a second peak in spring. GMI reached maximum values in July in Portugal and Netherlands and in June in Norway. Overall, mean BMI and SMI were lower in Portugal while mean GMI was lower in Norway. The spawning period lasted the whole summer in Portugal, but was shorter (only two months) in The Netherlands and Norway. The reproductive investment in The Netherlands was significantly higher than in Portugal and Norway, with the lowest values being observed in Norway. Differences in annual cycles between populations were attributed to environmental factors, namely temperature and food availability. Temperature seems important in shaping the reproductive pattern with more northern populations showing shorter reproductive periods starting later in the year, and a lower reproductive output. In addition, winter water temperatures can explain the lower mean body and somatic mass values observed in Portugal. Food availability influenced the physiological performance of the species with peaks in somatic mass coinciding with phytoplankton blooms. This relation between physiological performance and environmental factors influences S. plana distribution, densities and even survival, with natural consequences on its commercial importance.     

Geological and anthropogenic influences on sediment metal composition in the upper Paracatu River Basin, Brazil

This work reports a geochemical study of sediments from the upper Paracatu River Basin. The objective is to define the influences of Au, Zn, and Pb mineral deposits and mining activities on the sediment metal sources, distribution, and accretion. The samples were analyzed using ICP/OES, AAS, and XRD techniques and were treated with principal components analysis and the geo-accumulation index. The main geochemical processes that control the sediment composition are pyrite oxidation, muscovite weathering, carbonate dissolution, and the erosion of oxisols enriched with Zn and Pb. The upper Rico Stream has high Al, Fe, Cu, Cr, Co, and Mn concentrations due erosion of oxisols and pyrite oxidation and muscovite alteration present in the parental rock. The artisanal alluvial gold mining increased the primary rock-minerals?? weathering and Hg sediment concentration. The lower Escuro River and Santa Catarina Stream are enriched with Zn and Pb due the erosion of metal-rich soils formed over galena, sphalerite, calamine, and willemite mineral deposits located upstream. Elements such as Ca, Mg, and Ba have low concentrations throughout the sampled area due the high solubility of these metals-bearing minerals. The dispersion of metals is limited by the basin geomorphology and their affinity to silt-clayey minerals and Fe and Mn oxides and hydroxides in circumneutral pH waters.     

Detrital zircon U–Pb ages and whole-rock geochemistry of the Neoproterozoic Paulistana and Santa Filomena complexes,Borborema Province,northeastern Brazil: implications for source area composition,provenance, and tectonic setting

The Paulistana and Santa Filomena Complexes are situated in the southern part of the Borborema Province (northeastern Brazil), in the Riacho do Pontal Orogen, and represent meta-volcano-sedimentary sequences. We present compositional variations in the metasedimentary rocks and new U–Pb detrital zircon data. Major and trace elements indicate that the metasedimentary rocks from the Paulistana and Santa Filomena Complexes are composed mostly of immature to mature sediments derived from felsic-intermediate sources with moderate to slightly high chemical weathering. The geochemical signatures of the sediment protoliths for both complexes are characteristic of continental magmatic arc settings with minor contribution from recycled sediment sources. The source area for the Paulistana Complex rocks follow the compositional trend between calc-alkaline granites and granodiorites, whereas the Santa Filomena Complex rocks have a more restricted composition trending to more granodioritic sources. For the Paulistana Complex, two main source ages were identified: (1) Tonian (ca. 950 Ma – sample RPE-58) and Tonian–Stenian (ca. 1.0 Ga – sample RPE-103). These data coupled with geochemical information suggest that the Cariris Velhos arc system was the main source area for the Paulistana Complex. Regarding the Santa Filomena metasedimentary rocks, potential source-areas include: (1) Neoarchaean rocks (~2.6 Ga) represented by the adjacent basement rocks of the Riacho do Pontal Orogen; (2) Rhyacian–Orosirian rocks (2.2–2.0 Ga) of the Riacho do Pontal Orogen and the Pernambuco–Alagoas terrain, which include an augen-gneiss with arc-related geochemical signature; (3) Statherian granites (1.7–1.6 Ga); and (4) Cariris Velhos crust (1000–920 Ma). The metasedimentary rocks of the Paulistana Complex were deposited in a rift stage (ca. 900 Ma), which is related to the break-up of the Rodinia supercontinent. The metasedimentary rocks of the Santa Filomena Complex most probably were deposited in another rift stage (ca. 750–700 Ma) and could be correlatives of the rift formation of the Canindé Domain (Sergipano Orogen).     

Ontogenic variation and effect of collection procedure on leaf biomechanical properties of Mediterranean seagrass Posidonia oceanica (L.) Delile

Leaf mechanical traits are important to understand how aquatic plants fracture and deform when subjected to abiotic (currents or waves) or biotic (herbivory attack) mechanical forces. The likely occurrence of variation during leaf ontogeny in these traits may thus have implications for hydrodynamic performance and vulnerability to herbivory damage, and may be associated with changes in morphologic and chemical traits. Seagrasses, marine flowering plants, consist of shoot bundles holding several leaves with different developmental stages, in which outer older leaves protect inner younger leaves. In this study we examined the long‐lived seagrass Posidonia oceanica to determine ontogenic variation in mechanical traits across leaf position within a shoot, representing different developmental stages. Moreover, we investigated whether or not the collection procedure (classical uprooted shoot versus non‐destructive shoot method: cutting the shoot without a portion of rhizome) and time span after collection influence mechanical measurements. Neither collection procedure nor time elapsed within 48 h of collection affected measurements of leaf biomechanical traits when seagrass shoots were kept moist in dark cool conditions. Ontogenic variation in mechanical traits in P. oceanica leaves over intermediate and adult developmental stages was observed: leaves weakened and lost stiffness with aging, while mid‐aged leaves (the longest and thickest ones) were able to withstand higher breaking forces. In addition, younger leaves had higher nitrogen content and lower fiber content than older leaves. The observed patterns may explain fine‐scale within‐shoot ecological processes of leaves at different developmental stages, such as leaf shedding and herbivory consumption in P. oceanica.     

Evaluation of the presence of major anionic surfactants in marine sediments

The contamination of aquatic environments has become the focus of increasing regulation and public concern due to their potential and unknown negative effects on the ecosystems. The present work develops a monitoring and statistical study, based on the analysis of variance test (ANOVA) and the multivariable analysis, both for insoluble soap and LAS in order to compare the behavior of different anionic surfactants in this environmental compartment. First, a novel and successfully validated methodology to analyze insoluble soap in these samples is developed. The matrix effect and the comparison of different extraction techniques were also performed. The optimized analytical methodologies were applied to 48 representative samples collected from the Almeria Coast (Spain) and then a statistical analysis to correlate anionic surfactant concentration and several variables associated with marine sediment samples was also developed. The results obtained showed relevant conclusions related to the environmental behavior of anionic surfactants in marine sediments.     

Dark matter as an effect of the quantum vacuum

The interaction between the quantum vacuum and a weak gravitational field is calculated for the vacuum fields of quantum electrodynamics. The result shows that the vacuum state is modified by the gravitational field, giving rise to a nonzero interaction energy. This suggests a model that fits in the main properties of the hypothetical dark matter in galactic haloes.     

Analyzing the spatial interactions between rainfall levels and flooding prediction in São Paulo

Rainfall is one of the primary triggers for many geological and hydrological natural disasters. While the geological events are related to mass movements in land collapse due to waterlogging, the hydrological ones are usually assigned to runoff or flooding. Studies in the literature propose predicting mass movement events as a function of accumulated rainfall levels recorded at distinct periods. According to these approaches, a two-dimensional rainfall levels feature space is segmented into the occurrence and non-occurrence decision regions by an empirical critical curve (CC). Although this scheme may easily be extended to other purposes and applications, studies in the literature need to discuss its use for flooding prediction. In light of this motivation, the present study is unfolded in (1) verifying that defining CCs in the rainfall levels feature space is a practical approach for flooding prediction and (2) analyzing how geospatial components interact with rainfall levels and flooding prediction. A database containing the rainfall levels recorded for flooding and non-flooding events in São Paulo city, Brazil, regarding the period 2015–2016, was considered in this study. The results indicate good accuracy for flooding prediction using only partial rain, which can be improved by adding physical characteristics of the flooding locations, demonstrating a direct correlation with spatial interactions, and rainfall levels.