Pattern and pathways for mercury lifespan bioaccumulation in Carcinus maenas

Carcinus maenas is an important and exploited natural resource in temperate estuaries, being consumed by local populations and also used as fish bait. Through bioaccumulation and bioamplification processes occurring in polluted estuarine ecosystems, this species may directly or indirectly represent a major pathway for Human contamination. No information is available on the overall lifespan bioaccumulation pattern of mercury for this species, which would be an invaluable tool for assessing the risks associated with C. maenas harvest in contaminated areas. Taking that in mind, the main objectives of this work were to clarify the lifespan bioaccumulation pattern of mercury for this species. A consistent lifespan accumulation pattern was found for this species, both for total and organic mercury, and coherent differences were found between genders, suggesting different physiological responses to contamination. From our results two scenarios emerge: (a) for low mercury contamination areas where the diet is the major pathway for metal uptake, with higher levels in muscle and hepatopancreas (twice as high as in gills) and higher organic mercury fractions (as high as 80-90% in muscle), crabs bioaccumulate with age and (b) on high contaminated areas, environmental exposure is predominant, with higher levels found in gills (reaching 0.8 mg kg(-1)), lower organic fractions and no mercury increment with age. Detoxification strategies, dietary differences and species mobility may account for these two accumulation patterns.     

Suffusion evaluation of coarse-graded soils from Rhine dikes

Acta Geotechnica - An experimental study on internal erosion of coarse-grained soils collected from the Rhine River is presented. The tests performed on laboratory column aim to assess the...     

Large geographic and temporal extensions of the Río de la Plata Craton,South America,and its metacratonic eastern margin

Integration of existing isotopic and geological data allows a reconsideration of the distribution and age of the Río de la Plata Craton within South America. The reinterpretation increases the area of the craton to about 2,400,000 km² with implications for the tectonic map of South America and for global reconstruction of palaeocontinents. Four areas previously considered as separate cratons (Luís Alves, Curitiba, Tebicuary, and Paranapanema) are interpreted as part of the same Río de la Plata Craton. The craton is organized into six provinces and domains: Buenos Aires–Piedra Alta, Taquarembó, Tebicuary, Luís Alves, Encantadas, and Nico Pérez. The term ‘Transplatense’ is proposed to replace ‘Trans-Amazonian’ for Rhyacian events that occurred within the Río de la Plata Craton. The craton is formed not only by dominant Rhyacian rocks and local Archaean rocks, but also by Statherian and Mesoproterozoic rocks. The domains are all partially to totally covered by Phanerozoic basins (Paraná, Chacoparanense, Claromecó, Salado, Balcarce, and Colorado) which makes their investigation difficult. The Ediacaran–Cambrian collisions of the Brasilian orogen generated tectonic mixtures of orogenic and cratonic zones. This is more evident in the eastern margin of the craton, which behaved as a metacraton.     

Basin‐scale predictive models of alluvial architecture: Constraints from the Palaeocene–Eocene,Bighorn Basin,Wyoming, USA

Basin‐scale models are required to interpret ancient continental sedimentary successions, and reduce uncertainty in assessing geological resources in basins. Recently, modern studies show distributive fluvial systems to comprise a substantial proportion of modern sedimentary basins, but their role in ancient basin fills has yet to be quantitatively documented at the basin scale. This study analysed key fluvial characteristics to construct a detailed basin‐wide model of the Palaeogene Fort Union and Willwood formations (Bighorn Basin, Wyoming), using observations from modern studies, and ancient system scale studies of distributive fluvial systems, to guide interpretations. Mapping showed these formations to be highly heterogeneous with channel‐body proportion (from 12 to 81%) and geometry types (large amalgamated bodies to isolated channels), grain size (silt to conglomerate), average channel‐body thickness (4 to 20 m) and average storey thickness (3 to 10 m) varying significantly across the basin. Distributive fluvial systems in the form of alluvial and fluvial fans in transverse configurations were recognized as well as a wide axial system, with heterogeneity in the formations being closely aligned to these interpretations. Furthermore, numerous individual depositional systems were identified within the formations (Beartooth Absaroka, Washakie, Owl Creek and axial). Predicted downstream distributive fluvial system trends (i.e. downstream decrease in channel proportion, size and grain size) were identified in the Beartooth, Absaroka and Owl Creek systems. However, predicted trends were not identified in the Washakie system where intrabasinal thrusting disturbed the sequence. Importantly, a wide axial fluvial system was identified, where reverse downstream distributive fluvial system trends were present, interpreted to be the result of the input of transverse systems of variable size. This study provides a new level of detail in the application of basin‐scale models, demonstrating their usefulness in trying to understand and predict alluvial architecture distribution and heterogeneity, with important implications for economic resources and palaeogeographic reconstructions.     

Metal concentrations, fluxes, inventories and chronologies in sediments from Sepetiba and Ribeira Bays: A comparative study

Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from ²¹⁰Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y⁻¹ in the inner bay to 2.6 mm y⁻¹ close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y⁻¹ before the 1960s and 0.76 cm y⁻¹ since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m³ s⁻¹ to 160 m³ s⁻¹. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits.     

Levels of persistent organic pollutants and residual pattern of DDTs in small cetaceans from the coast of São Paulo, Brazil

The State of São Paulo is the most developed area in Brazil and was impacted by persistent organic pollutants for several decades. This study investigated organochlorines in five species of small cetaceans (Pontoporia blainvillei, Stenella frontalis, Sotalia guianensis, Tursiops truncatus and Steno bredanensis) found dead along the coast of São Paulo between 1997 and 2003. DDTs (15.9 μg g⁻¹ lipid; mean for all pooled individuals) and PCBs (8.08 μg g⁻¹) exhibited the highest concentrations in the animals, reflecting large amounts formerly used in Brazil. Lower levels of mirex (0.149 μg g⁻¹), HCB (0.051 μg g⁻¹), CHLs (0.008 μg g⁻¹) and HCHs (0.007 μg g⁻¹) were detected in all species. Residual pattern of DDTs in dolphins suggests that o,p′-DDT is more recalcitrant than p,p′-DDT in the body of the animals and/or the environment. In contrast to p,p′-DDT, residues of o,p′-DDT seem to be preferentially converted into o,p′-DDD rather than o,p′-DDE.     

Study on the Historical Distribution of Metals in Aquatic Sediments

In this study, the historical distribution of metals, phosphorous, and sulfur at four different depths in the sediments of different lakes formed in the course of an urban river (in Londrina, Parana State, Brazil) were determined. The transport of metals along the course of the river was observed mainly for Mn, Cr, and Zn. High concentrations of Pb in the Capivara Bay and Cr in the river were attributed to contamination from a battery plant and a tannery, respectively. The concentrations of heavy metals in the deepest layers of the sediments remain high several years after deposition.     

Stochastic Modeling of Variably Saturated Transient Flow in Fractal Porous Media

This work presents the application of a Monte Carlo simulation method to perform an statistical analysis of transient variably saturated flow in an hypothetical random porous media. For each realization of the stochastic soil parameters entering as coefficients in Richards' flow equation, the pressure head and the flow field are computed using a mixed finite element procedure for the spatial discretization combined with a backward Euler and a modified Picard iteration in time. The hybridization of the mixed method provides a novel way for evaluating hydraulic conductivity on interelement boundaries. The proposed methodology can handle both large variability and fractal structure in the hydraulic parameters. The saturated conductivity K _s and the shape parameter _vg in the van Genuchten model are treated as stochastic fractal functions known as fractional Brownian motion (fBm) or fractional Gaussian noise (fGn). The statistical moments of the pressure head, water content, and flow components are obtained by averaging realizations of the fractal parameters in Monte Carlo fashion. A numerical example showing the application of the proposed methodology to characterize groundwater flow in highly heterogeneous soils is presented.     

Acid mine drainage and acid rock drainage processes in the environment of Herrerías Mine (Iberian Pyrite Belt, Huelva-Spain) and impact on the Andevalo Dam

The present work describes the process of acid water discharge into the Andévalo Dam (Iberian Pyrite Belt, Huelva-Spain) starting from the interpretation of rainfall data and chemical analyses regarding pH, conductivity, metal and sulphate content in water, from a time series corresponding to the sampling of two confluent channels that discharge water into the referred dam. Statistical data treatment allows us to conclude the existence of acid mine drainage processes in the Chorrito Stream, which are translated into very low pH values and high sulphate and metal concentrations in the water coming from Herrerías Mine. On the other hand, the Higuereta Stream shows, for the same parameters, much lower values that can be interpreted as the channel response to acid rock drainage processes in its drainage basin induced by the rocky outcrops of the Iberian Pyrite Belt.