A Middle Miocene carbonate embankment on an active volcanic slope: Ilhéu de Baixo,Madeira Archipelago,Eastern Atlantic

Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m³ of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd.     

Natural Variability of Shear Strength in a Granite Residual Soil from Porto

The renewal imposed by the Eurocodes regarding the methodologies of safety evaluation requires a statistical analysis of the variability of ground geotechnical parameters. However, the studies published in the reviewed literature do not cover the typical materials from the northeast region of Portugal—residual soils from granite—to which a strong heterogeneity is associated. Hence, a statistical characterization of the natural variability of a granite residual soil from Porto has been made through a significant amount of experimental tests, focusing on its geomechanical properties. In order to provide a database for probabilistic analysis of problems involving this type of soils, an appropriate statistical law has been used to model its variability, which has been quantified by means of coefficients of variation and scales of fluctuation.     

Assessment of troposphere mapping functions using three-dimensional ray-tracing

The troposphere delay is an important source of error for precise GNSS positioning due to its high correlation with the station height parameter. It has been demonstrated that errors in mapping functions can cause sub-annual biases as well as affect the repeatability of GNSS solutions, which is a particular concern for geophysical studies. Three-dimensional ray-tracing through numerical weather models (NWM) is an excellent approach for capturing the directional and daily variation of the tropospheric delay. Due to computational complexity, its use for positioning purposes is limited, but it is an excellent tool for evaluating current state-of-the-art mapping functions used for geodetic positioning. Many mapping functions have been recommended in the past such as the Niell Mapping Function (NMF), Vienna Mapping Function 1 (VMF1), and the Global Mapping Function (GMF), which have been adopted by most IGS analysis centers. A new Global Pressure Temperature model (GPT2) has also been developed, which has been shown to improve upon the original atmospheric model used for the GMF. Although the mapping functions mentioned above use the same functional formulation, they vary in terms of their atmospheric source and calibration approach. A homogeneous data set of three-dimensional ray-traced delays is used to evaluate all components of the mapping functions, including their underlying functional formulation, calibration, and compression method. Additionally, an alternative representation of the VMF1 is generated using the same atmospheric source as the truth data set to evaluate the differences in ray-tracing methods and their effect on the end mapping function. The results of this investigation continue to support the use of the VMF1 as the mapping function of choice when geodetic parameters are of interest. Further support for the GPT2 and GMF as reliable back-ups when the VMF1 is not available was found due to their high consistency with the NWM-derived mapping function. Additionally, a small latitude-dependent bias in station height was found in the current mapping functions. This bias was identified to be due to the assumption of a constant radius of the earth and was largest at the poles and at the equator. Finally, an alternative version of the VMF1 is introduced, namely the UNB-VMF1 which provides users with an independent NWM-derived mapping function to support geodetic positioning.     

A contribution to regional stratigraphic correlations of the Afro-Brazilian depression – The Dom João Stage (Brotas Group and equivalent units – Late Jurassic) in Northeastern Brazilian sedimentary basins

The Dom João Stage comprises an interval with variable thickness between 100 and 1200 m, composed of fluvial, eolian and lacustrine deposits of Late Jurassic age, based mainly on the lacustrine ostracod fauna (although the top deposits may extend into the Early Cretaceous). These deposits comprise the so-called Afro-Brazilian Depression, initially characterized as containing the Brotas Group of the Recôncavo Basin (which includes the Aliança and the Sergi Formations) and subsequently extended into the Tucano, Jatobá, Camamu, Almada, Sergipe, Alagoas and Araripe Basins in northeastern Brazil, encompassing the study area of this paper. The large occurrence area of the Dom João Stage gives rise to discussions about the depositional connectivity between the basins, and the real extension of sedimentation. In the first studies of this stratigraphic interval, the Dom João Stage was strictly associated with the rift phase, as an initial stage (decades of 1960–70), but subsequent analyses considered the Dom João as an intracratonic basin or pre-rift phase – without any relation to the active mechanics of a tectonic syn-rift phase (decades of 1980–2000). The present work developed an evolutionary stratigraphic and tectonic model, based on the characterization of depositional sequences, internal flooding surfaces, depositional systems arrangement and paleoflow directions. Several outcrops on the onshore basins were used to build composite sections of each basin, comprising facies, architectural elements, depositional systems, stratigraphic and lithostratigraphic frameworks, and paleocurrents. In addition to that, over a hundred onshore and offshore exploration wells were used (only 21 of which are showed) to map the depositional sequences and generate correlation sections. These show the characteristics and relations of the Dom João Stage in each studied basin, and they were also extended to the Gabon Basin. The results indicate that there were two main phases during the Dom João Stage, in which distinctive sedimentary environments were developed, reflecting depositional system arrangements, paleoflow directions were diverse, and continuous or compartmented basins were developed.     

Distribution of dissolved labile and particulate iron and copper in Terra Nova Bay polynya (Ross Sea,Antarctica) surface waters in relation to nutrients and phytoplankton growth

The distribution of the dissolved labile and of the particulate Fe and Cu together with dissolved oxygen, nutrients, chlorophyll a and total particulate matter was investigated in the surface waters of Terra Nova Bay polynya in mid-January 2003. The measurements were conducted within the framework of the Italian Climatic Long-term Interactions of the Mass balance in Antarctica (CLIMA) Project activities. The labile dissolved fraction was operationally defined by employing the chelating resin Chelex-100, which retains free and loosely bound trace metal species. The dissolved labile Fe ranges from below the detection limit (0.15 nM) to 3.71 nM, while the dissolved labile Cu from below the detection limit (0.10 nM) to 0.90 nM. The lowest concentrations for both metals were observed at 20 m depth (the shallowest depth for which metals were measured). The concentration of the particulate Fe was about 5 times higher than the dissolved Fe concentration, ranging from 0.56 to 24.83 nM with an average of 6.45 nM. The concentration of the particulate Cu ranged from 0.01 to 0.71 nM with an average of 0.17 nM. The values are in agreement with the previous data collected in the same area. We evaluated the role of the Fe and Cu as biolimiting metals. The N:dissolved labile Fe ratios (18,900–130,666) would or would not allow a complete nitrate removal, on the basis of the N:Fe requirement ratios that we calculated considering the N:P and the C:P ratios estimated for diatoms. This finding partially agrees with the Si:N ratio that we found (2.29). Moreover we considered a possible influence of the dissolved labile Cu on the Fe uptake process.     

Parallel finite element algorithm with domain decomposition for three-dimensional magnetotelluric modelling

We present a new finite element (FE) method for magnetotelluric modelling of three-dimensional conductivity structures. Maxwell's equations are treated as a system of first-order partial differential equations for the secondary fields. Absorbing boundary conditions are introduced, minimizing undesired boundary effects and allowing the use of small computational domains. The numerical algorithm presented here is an iterative, domain decomposition procedure employing a nonconforming FE space. It does not use global matrices, therefore allowing the modellization of large and complicated structures. The algorithm is naturally parallellizable, and we show results obtained in the IBM SP2 parallel supercomputer at Purdue University. The accuracy of the numerical method is verified by checking the computed solutions with the results of COMMEMI, the international project on the comparison of modelling methods for electromagnetic induction.     

Jurassic‐to‐present thermal history of the central High Atlas (Morocco) assessed by low‐temperature thermochronology

Apatite fission track (AFT) and (U–Th)/He data from the High Atlas have been obtained for the first time to constrain the tectono‐thermal evolution of the central part of the chain. Results from Palaeozoic basement massifs indicate long residence at low temperatures, consistently with their original location out of the deepest Mesozoic rift troughs and indicating minor exhumation. The best rocks for extracting the Alpine history of the Atlas Mountains are Jurassic intrusives, which yield AFT ages centred on c. 80 Ma; thermal models based on AFT data and constrained by (U–Th)/He suggest that these ages are included in a slow cooling trend from intrusion age to c. 50 Ma ago that we attribute to post‐rift thermal relaxation. This is followed by a stability period of c. 30 Ma and then by a final exhumational cooling until present exposure. Eocene intrusives yield AFT ages similar to those of Rb–Sr and K–Ar suggesting rapid emplacement in the uppermost crust.     

Static cylindrically symmetric gravitational field with cosmological constant

We show that a class of solutions for a vacuum cylindrically symmetric gravitational field with nonvanishing cosmological constant reduce to the welknown Levi-Civita metric close to the axis. All the circular geodesics in this generalized vacuum are time like, null or space like depending on the relative magnitudes of the two parameters appearing in the solutions.For other particles moving inZ=constant plane there are some cases where the trapping of timelike and null trajectories occur, while in other cases some of the particles may orbit round the axis in a fixed zone bounded by two limiting radii.     

A global model study of natural bromine sources and the effects on tropospheric chemistry using MOZART4

Halogens in the atmosphere chemically destroy ozone. In the troposphere, bromine has higher ozone destruction efficiency than chlorine and is the halogen species with the widest geographical spread of natural sources. We investigate the relative strength of various sources of reactive tropospheric bromine and the influence of bromine on tropospheric chemistry using a 6-year simulation with the global chemistry transport model MOZART4. We consider the following sources: short-lived bromocarbons (CHBr₃, CH₂BrCl, CHBr₂Cl, CHBrCl₂, and CH₂Br₂) and CH₃Br, bromine from airborne sea salt particles, and frost flowers and sea salt on or in the snowpack in polar regions. The total bromine emissions in our simulations add up to 31.7 Gmol(Br)/yr: 63 % from polar sources, 24.6 % from short-lived bromocarbons and 12.4 % from airborne sea salt particles. We conclude from our analysis that our global bromine emission is likely to be on the lower end of the range, because of too low emissions from airborne sea salt. Bromine chemistry has an effect on the oxidation capacity of the troposphere, not only due to its direct influence on ozone concentrations, but also by reactions with other key chemical species like HO _x and NO _x . Globally, the impact of bromine chemistry on tropospheric O₃ is comparable to the impact of gas-phase sulfur chemistry, since the inclusion of bromine chemistry in MOZART4 leads to a decrease of the O₃ burden in the troposphere by 6 Tg, while we get an increase by 5 Tg if gas-phase sulfur chemistry is switched off in the standard model. With decreased ozone burden, the simulated oxidizing capacity of the atmosphere decreases thus affecting species associated with the oxidation capacity of the atmosphere (CH₃OOH, H₂O₂).     

Instruments, Detectors and the Future of Astronomy with Large Ground Based Telescopes

Results of a survey of instrumentation and detector systems, either currently deployed or planned for use at telescopes larger than 3.5 m, in ground based observatories world-wide, are presented. This survey revealed a number of instrumentation design trends at optical, near, and mid-infrared wavelengths. Some of the most prominent trends include the development of vastly larger optical detector systems (> 10⁹ pixels) than anything built to date, and the frequent use of mosaics of near-infrared detectors – something that was quite rare only a decade ago in astronomy. Some future science applications for detectors are then explored, in an attempt to build a bridge between current detectors and what will be needed to support the research ambitions of astronomers in the future.