Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Sea surface wind and Sea ice in the Barents Sea using microwave sensing data from Meteor-M N1 and GCOM-W1 satellites in January–March 2013

Application of satellite passive microwave sensing for the retrieval of key climatic parameters in the Barents Sea is considered. Fields of surface wind, atmosphere water vapor content and cloud liquid water content were found from MTVZA-GY radiometer onboard the Meteor-M N1 satellite and AMSR2 onboard the GCOM-W1 satellite with the use of original algorithms. The fields are in a good agreement with the ancillary remote and in situ measurements, which follows from the analysis of the evolution of the extra tropical and polar cyclones and cold air outbreaks with storm winds leading to intense air-sea interaction, and the formation and drift of sea ice.     

Elevation‐dependent responses of streamflow to climate warming

Warming will affect snowline elevation, potentially altering the timing and magnitude of streamflow from mountain landscapes. Presently, the assessment of potential elevation‐dependent responses is difficult because many gauged watersheds integrate drainage areas that are both snow and rain dominated. To predict the impact of snowline rise on streamflow, we mapped the current snowline (1980 m) for the Salmon River watershed (Idaho, USA) and projected its elevation after 3 °C warming (2440 m). This increase results in a 40% reduction in snow‐covered area during winter months. We expand this analysis by collecting streamflow records from a new, elevation‐stratified gauging network of watersheds contained within high (2250–3800 m), mid (1500–2250 m) and low (300–1500 m) elevations that isolate snow, mixed and rain‐dominated precipitation regimes. Results indicate that lags between percentiles of precipitation and streamflow are much shorter in low elevations than in mid‐ and high‐elevation watersheds. Low elevation annual percentiles (Q₂₅ and Q₇₅) of streamflow occur 30–50 days earlier than in higher elevation watersheds. Extreme events in low elevations are dominated by low‐ and no‐flow events whereas mid‐ and high‐elevation extreme events are primarily large magnitude floods. Only mid‐ and high‐elevation watersheds are strongly cross correlated with catchment‐wide flow of the Salmon River, suggesting that changes in contributions from low‐elevation catchments may be poorly represented using mainstem gauges. As snowline rises, mid‐elevation watersheds will likely exhibit behaviours currently observed only at lower elevations. Streamflow monitoring networks designed for operational decision making or change detection may require modification to capture elevation‐dependent responses of streamflow to warming. Copyright © 2014 John Wiley & Sons, Ltd.     

Initialization and data assimilation experiments with a primitive equation model

The process of combining models of the ocean circulation with large data sets is known in meteorology as model initialization and data assimilation. This process is new to oceanographers, who only now are on the verge of having available world-wide synoptic maps of dynamic variables. In this paper we carry out a series of idealized initialization/assimilation experiments with a primitive equation (PE) model, which constitute a first step in developing a realistic process model and data assimilation techniques for the Gulf Stream system. The PE model is used in a spin-down mode and initialized with an analytic jet profile with geostrophically balanced fields.Two major questions are addressed in the present study. The first concerns the initialization process of a PE model during which internal/inertial gravity wave noise is produced. We ask: are the initialization shocks equally crucial for ocean models as they have been for their atmospheric counterparts? The results of an extensive series of balanced versus unbalanced initializations indicate that, for a PE model with a rigid lid, a brutally unbalanced initialization is required to produce strong internal gravity wave shocks. A geostrophically balanced initialization is sufficient to ensure smooth jet evolutions, with no apparent gravity waves, over long time durations in the spin-down mode. No sophisticated initialization procedures seem, therefore, to be required.The second question addressed is: which component of the flow is the most important in data assimilation to drive the model response towards a baseline reference ocean? We specifically compare the knowledge of the depth-integrated flow only, corresponding to measurements of the total transport, with the knowledge of the density field only, or equivalently the velocity shear. The knowledge of the interior density field is much more effective in decreasing the root-mean-square (r.m.s.) errors relative to the reference ocean. If the baroclinic structure is known, coarse horizontal resolutions of data insertion can be reached before significantly worsening the model estimates. If only the depth-averaged flow is known, a decrease in the horizontal resolution of data assimilation has an immediate effect: the r.m.s. errors sharply increase and the assimilation run diverges from the reference ocean. In the assimilation of the barotropic flow alone, even with dense resolution, the errors in the deep layers always show an increasing trend. The relative effectiveness of baroclinic versus barotropic data insertion can be rationalized in the context of geostrophic adjustment theory.     

Graphical estimation of extreme value prediction functions

Graphical application of the Type 1 (Gumbel) extreme value distribution is very simple since the distribution inverse gives a linear x-y plot. In contrast, the Type 2 and Type 3 extreme value distributions have nonlinear functions with respect to the same axes. A simple three-point graphical estimation procedure is described for these two distributions. This approach allows the nonlinear flood magnitude prediction functions to be located in any desirable position relative to the plotted annual maxima, subject to the constraint of having an extreme value form. The computation is very simple and requires only the location of a unique zero of a one-parameter function within a defined interval.     

青藏高原隆升的非线性动态有限元仿真研究

根据青藏高原的地质特征建立分析模型，采用3维动态有限元方法，在计算仿真板块速度场的基础上，计算在青藏高原的隆升过程中该地区地壳岩石的等效应力和位移随时间的变化，计算仿真得到的速度场与1998年GPS观测的速度场吻合良好；与过去一贯的假设相反，计算结果反映出地壳应力场不是静态的，而是此起彼伏，不断变化的，应力值最大且变化最剧烈的地区在克什米尔地区、鄂尔多斯地区和鲜水河－小江断裂带，与地震多发区域吻合。     

The Concept of a Multi-Functional Astronomy Complex and Dynamically Integrated Database Applied to Multi-Channel Observations with the MASTER Global Network

Astronomy Reports - The concept of a multi-functional astronomical complex as applied to robotic astronomy networks and systems is formulated. The practical realization of this concept in the...     

Sperm motility in the Pacific oyster (Crassostrea gigas) is affected by nonylphenol

Nonylphenol, a widespread aquatic pollutant with endocrine-disrupting potential has been found to affect sperm motility in the Pacific oyster, Crassostrea gigas (Thunberg). This marine invertebrate, a global aquaculture species, was exposed to nonylphenol at concentrations of 1 and 100 μg l⁻¹ for a duration of 72 h during the period of gametogenesis. Growth was monitored at regular intervals until sexual maturity when sperm motility was assessed. The growth rate of C. gigas remained unaffected by exposure to nonylphenol during gametogenesis. However, the number of individuals with motile sperm was significantly reduced.     

The orbital periods of revolution of a satellite

The relationship between the anomalistic and nodal periods of revolution of a satellite is investigated and it is shown that the anomalistic period of revolution can change even in a conservative system of forces and it is suggested that the mean nodal period represents the energy of the satellite.     

A comparative dental metrical and morphological analysis of a Middle Pleistocene hominin maxilla from Chaoxian (Chaohu), China

A hominin maxilla, discovered in 1983 in Chaoxian County, Anhui Province, eastern China represents one of several Asian hominins dating to the late Middle Pleistocene. Although the maxilla and associated occipital have been described, no detailed study of the dentition has been made. This study provides metrical and morphological information on the Chaoxian dentition and places it into a larger Middle to Late Pleistocene context. Implications for the taxonomy of Middle Pleistocene hominins are discussed.