Characteristics of the Sahara as a meteorite recovery surface

We describe the geological, geomorphological, and paleoclimatic setting of the Sahara of North Africa in particular, focused on the main meteorite dense collection areas (DCA; Morocco, Algeria, Tunisia, and Libya). We report on the outcome of several meteorite recovery field expeditions in Morocco and Tunisia since 2008, by car and by foot, that applied systematic search methods. The number of meteorites collected is 41 ordinary chondrites and one brachinite. The statistics of unpaired ordinary chondrites indicates that H chondrites are more abundant (21) than L chondrites (12), while LL chondrites are rare (2). Our meteorite density estimates for Tunisia and Morocco are in the order of magnitude of 1 met km^?2. An estimate of the total maximum number of meteorites that could be recovered from the Sahara is 780,000 meteorites. We selected 23 meteorites from Aridal, Bou Kra, Bir Zar, and Tieret DCAs for ¹⁴C dating. The results show a wide range of terrestrial ages from 0.4 to more than 40 kyr with a majority of meteorites showing ages between 0.4 and 20 kyr. The weathering degree of these meteorites is ranges from minor (W1) to strong (W4). The highest weathering grades result from repeated oscillations between high and low humidity in the Sahara. However, there appears to be no correlation between weathering grade and terrestrial age of meteorites.     

Joint cosmological formation of QSOs and bulge-dominated galaxies

Older and more recent pieces of observational evidence suggest a strong connection between QSOs and galaxies; in particular, the recently discovered correlation between black hole and galactic bulge masses suggests that QSO activity is directly connected to the formation of galactic bulges. The cosmological problem of QSO formation is analysed in the framework of an analytical model for galaxy formation; for the first time a joint comparison with galaxy and QSO observables is performed. In this model it is assumed that the same physical variable that determines galaxy morphology is able to modulate the mass of the black hole responsible for QSO activity. Both halo spin and the occurrence of a major merger are considered as candidates for this role. The predictions of the model are compared with available data for the type-dependent galaxy mass functions, the star formation history of elliptical galaxies, the QSO luminosity function and its evolution (including the obscured objects contributing to the hard-X-ray background), the mass function of dormant black holes and the distribution of black hole-to-bulge mass ratios. A good agreement with observations is obtained if the halo spin modulates the efficiency of black hole formation, and if the galactic haloes at z =0 have shone in an inverted order with respect to the hierarchical one (i.e., stars and black holes in bigger galactic haloes have formed before those in smaller ones). This inversion of hierarchical order for galaxy formation, which reconciles galaxy formation with QSO evolution, is consistent with many pieces of observational evidence.     

Chemical Analysis of Iron Meteorites by Inductively Coupled Plasma-Mass Spectrometry

Iron meteorites were analysed for nineteen siderophile and chalcophile elements by conventional inductively coupled plasma-mass spectrometry with the specific aim of demonstrating that this technique is an effective alternative to the more routine, yet complex, methodologies adopted in this field such as instrumental or radiochemical neutron activation analysis. Two aliquots of each meteorite sample, in the form of small shavings, were dissolved, one in 6 mol l^-1 HNO₃ and the other in aqua regia , and diluted to a final concentration of 1 mg sample per 1 ml of solution, without pre-concentrating the analytes. Nitric acid solutions were used for the determination of the elements Cr, Co, Ni, Cu, Ga, Ge and As; aqua regia solutions were analysed for the elements Mo, Ru, Rh, Pd, In, Sn, Sb, W, Re, Ir, Pt and Au. Samples were analysed by external calibration, carried out using synthetic multi-elemental solutions, and internal standardisation (with Be, Rb and Bi selected as internal standards). The results obtained from the analyses of nine geochemically well-characterized iron meteorites (Canyon Diablo, Odessa, Toluca, Coahuila, Sikhote-Alin, Buenaventura, Tambo Quemado, Gibeon, NWA 859) with widely variable chemical compositions are in good agreement with literature values for most elements. Detection limits were generally below the lowest concentration observed in iron meteorites. The most notable exception is for Ge, which cannot be successfully determined in the low-Ge meteorites of groups IVA, IVB and IIIF and a number of ungrouped irons. A test of the overall reproducibility of the adopted method, undertaken by repeatedly analysing the same Odessa IAB meteorite specimen, yielded relative standard deviations (1 s ) of between 1 and 6% for all elements except Cr (40%).     

A probabilistic approach for the classification of earthquakes as ��triggered�� or ��not triggered��

The occurrence time of earthquakes can be anticipated or delayed by external phenomena that induce strain energy changes on the faults. ??Anticipated?? earthquakes are generally called ??triggered??; however, it can be controversial to label a specific earthquake as such, mostly because of the stochastic nature of earthquake occurrence and of the large uncertainties usually associated to stress modelling. Here we introduce a combined statistical and physical approach to quantify the probability that a given earthquake was triggered by a given stress-inducing phenomenon. As an example, we consider an earthquake that was likely triggered by a natural event: the M?=?6.2 13 Jan 1976 Kópasker earthquake on the Grímsey lineament (Tj?rnes Fracture Zone, Iceland), which occurred about 3?weeks after a large dike injection in the nearby Krafla fissure swarm. By using Coulomb stress calculations and the rate-and-state earthquake nucleation theory, we calculate the likelihood of the earthquake in a scenario that contains only the tectonic background and excludes the dike and in a scenario that includes the dike but excludes the background. Applying the Bayes?? theorem, we obtain that the probability that the earthquake was indeed triggered by the dike, rather than purely due to the accumulation of tectonic strain, is about 60 to 90?%. This methodology allows us to assign quantitative probabilities to different scenarios and can help in classifying earthquakes as triggered or not triggered by natural or human-induced changes of stress in the crust.     

Organic pollutants (PAHs, PCBs) in sediments from the Mar Piccolo in Taranto (Ionian Sea, Southern Italy)

Polychlorinated biphenyls (PCBs) and 17 parent polycyclic aromatic hydrocarbons (PAHs) were determined in surface sediments from nine stations in the Mar Piccolo of Taranto (Ionian Sea, Southern Italy). Total PAH concentrations ranged from 380 to 12,750 microg/kg d.w., while total PCB levels ranged from 2 to 1684 microg/kg d.w.; this values were higher than those found in others marine coastal areas of the Mediterranean Sea. For PAHs, low molecular weight/high molecular weight, phenanthrene/anthracene and fluoranthene/pyrene ratio were used for discriminating between pyrolitic and petroleum origin. Results showed that PAHs were mainly of pyrolitic origin. PCB and PAH levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL, TEL-PEL indexes) for evaluation probable toxic effects on marine organism. Finally, ERM and PEL quotients were used to evaluate the degree to which chemicals exceed guidelines. Results suggest an ecotoxicological risk for benthic organisms mainly in the first inlet, where high concentrations of PCBs were found in sediments influenced by harbour activities.     

Effects of nutrient enrichment on macroalgal coralligenous assemblages

Effects of eutrophication on marine ecosystems have been widely studied, even if both the effects on deep subtidal rocky assemblages and response of different successional stages to nutrients impact are still not clear. In this context, the study aimed to evaluate the effects of nutrient enrichment on Mediterranean macroalgal assemblages associated with coralligenous habitat. A manipulative field experiment was carried out by supplying both mature and early successional stages of assemblages with nutrients. A total of 62 macroalgal species were identified. Multivariate and univariate analyses showed that the structure of both mature and early successional macroalgal assemblages of coralligenous significantly varied between areas treated with nutrients and not treated areas. Moreover, differences were stronger when macroalgal assemblages were in the early successional stage than in the mature one. Results highlighted the role played by nutrients in determining the structure of macroalgal coralligenous assemblages, furthermore suggesting possible synergetic effects with other kinds of disturbances.     

The relevance of energy damping in unreinforced masonry rocking mechanisms. Experimental and analytic investigations

Existing unreinforced masonry buildings frequently suffer out-of-plane local collapse mechanisms when undergoing earthquake ground motion. The energy damping that occurs during the motion, due to impacts of a wall against the foundation or against other walls, is a relevant parameter on the response. An experimental investigation has been carried out to estimate the dissipation of kinetic energy that takes place during free oscillations. Restraint conditions allow for two-sided rocking (wall resting on a foundation) and one-sided rocking (wall resting on a foundation adjacent to transverse walls). Five specimens have been tested, modelling walls acted out-of-plane (fa?ades). When one-sided rocking is under consideration, different depths of the contact surface between fa?ade and transverse walls are considered. In the case of two-sided rocking, the experimental coefficient of restitution is slightly lower than the analytic coefficient. In the case of one-sided rocking, an analytic formulation is proposed and this is compared against experimental data. Although the coefficient of restitution of one-sided rocking is less than half that of two-sided rocking, it is not equal to zero. Thus, it cannot induce a sudden stop of the motion. Hence, nonlinear time history analyses performed under this assumption may prove unsafe. Moreover, a comparison has been carried out between overturning maps, induced by twenty natural accelerograms, computed for the analytic coefficient of restitution and those computed for the experimental coefficient of restitution. The increased energy dissipation reduces the frequency of overturning and causes a more regular behaviour.