Malaco temperature reconstructions and numerical simulation of environmental conditions in the southeastern Carpathian Basin during the Last Glacial Maximum

We investigate the glacial climate conditions in the southeastern Carpathian Basin (Vojvodina, Serbia) based on the reconstruction of malacological palaeotemperatures and results from a high-resolution regional climate simulation. Land snail assemblages from eight loess profiles are used to reconstruct July temperatures during the Last Glacial Maximum (LGM). The malacological reconstructed temperatures are in good agreement with the simulated LGM July temperatures by the Weather Research and Forecast model. Both methods indicate increasing temperatures from the northwestern towards the southeastern parts of the study area. LGM aridity indices calculated based on the regional climate model data suggest more arid conditions in the southeastern parts compared with more humid conditions in the northwestern parts. However, for present-day conditions, the moisture gradient is reversed, exhibiting more humid (arid) conditions in the southeast (northwest). An explanation for the reversed LGM aridity pattern is provided by an analysis of the prevailing wind directions over the South Banat district (Serbia). The prevailing moist northwesterly winds during summer are not able to compensate for the annual lack of moisture induced by the dry winds from the southeast that are more frequent during the LGM for the other seasons.     

Dissolved Organic Carbon in Seepage Water – Production and Transformation during Soil Passage

Dissolved organic carbon (DOC) in seepage water can combine with organic pollutants, with Al and heavy metal ions and transport them through the soil profile with a potential to contaminate groundwater. We studied the production of DOC in aerobic decomposition experiments at 8 °C and moisture close to field capacity in soils from two sites with different microbial activities (spodic dystric Cambisols with moder (SLB) and mor‐moder (SLS) layers) using ¹³C‐depleted plants of differing decomposability (Epilobium angustifolium and Calamagrostis epigeios). Additionally, we investigated the DOC transformation during soil passage in decomposition experiments and in the field for the sites SLB and SLS. For SLS, decomposition of Epilobium resulted in a cumulative CO₂ production of 14% of the added C within 128 days. Priming effects were negligible. CO₂ production for the experiments using Calamagrostis was less with 11% for SLB and 10% for SLS. Cumulative DOC production was markedly high in the Epilobium decomposition experiment, being 25 g m^–2, out of which 11 g m^–2 were Epilobium‐derived (2% of the added C). For the Calamagrostis experiments, cumulative productions of DOC and Calamagrostis‐derived DOC (0.1% of the added C for SLS and SLB) were much less. During the soil passage, much of the DOC was removed by sorption or decomposition processes. Field studies at SLS and SLB using ¹³C natural abundance showed that ¹³C distribution of soil organic matter increased with depth, probably mainly due to a discrimination of C isotopes by decomposing microorganisms. DOC, however, showed a depletion of ¹³C from –28γ PDB to –29γ (SLB at 40 cm) or –28 to –30γ (SLS at 20 cm) with depth, owing to preferential decomposition of ¹³C‐enriched substances or preferential adsorption. This study indicates that DOC production is strongly affected by litter composition and that significant changes in DOC composition may occur during its passage through a soil depth of 40 cm.     

Impact of recent climate change on the hydrology of coastal Mediterranean rivers in Southern France

The purpose of this paper is to analyse the regional impact of recent climate change on the water resources in southern France. We produced spatial reconstructions of the monthly evolutions of temperature, precipitation and water discharge in 15 watersheds of six coastal river basins and examined the major changes based on trend analysis for the last 40 years. In this part of the Mediterranean, the general warming trend was strongly enhanced by changes in the atmospheric circulation patterns, characterized by a northward extension of the subtropical high pressure domain during spring and summer. During these seasons, monthly warming rates could achieve almost twice the mean annual warming rates. Although annual precipitation did not follow clear trends, water discharge significantly decreased in one third of the watersheds and accounted for an estimated 20% reduction of the water resources in this region. This concerns both the highest and lowest watersheds. In the former, the reduction is likely the result of a temperature induced switch of snowfall to rainfall at high altitudes. In the latter, the reduction of discharge seems to come from lower groundwater levels, which may be related to the temperature increase too, but also have other origins. The recent climatic evolution is consistent with most modelling simulations for the future, indicating that the reduction of the water resources will hold on, probably still enhanced by decreases in precipitation.     

Formation of the Wiesloch Mississippi Valley-type Zn-Pb-Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany

The Mississippi Valley-type (MVT) Zn–Pb–Ag deposit in the Wiesloch area, Southwest Germany, is controlled by graben-related faults of the Upper Rhinegraben. Mineralization occurs as vein fillings and irregular replacement ore bodies consisting of sphalerite, banded sphalerite, galena, pyrite, sulfosalts (jordanite and geocronite), barite, and calcite in the Middle Triassic carbonate host rock. Combining paragenetic information, fluid inclusion investigations, stable isotope and mineral chemistry with thermodynamic modeling, we have derived a model for the formation of the Wiesloch deposit. This model involves fluid mixing between ascending hot brines (originating in the crystalline basement) with sedimentary formation waters. The ascending brines originally had a near-neutral pH (around 6) and intermediate oxidation state, reflecting equilibrium with granites and gneisses in the basement. During fluid ascent and cooling, the pH of the brine shifted towards more acidic (around 4) and the oxidation state increased to conditions above the hematite-magnetite buffer. These chemical characteristics contrast strongly with those of the pore and fracture fluid residing in the limestone aquifer, which had a pH between 8 and 9 in equilibrium with calcite and was rather reduced due to the presence of organic matter in the limestone. Mixing between these two fluids resulted in a strong decrease in the solubility of silver-bearing sphalerite and galena, and calcite. Besides Wiesloch, several Pb–Zn deposits are known along the Upper Rhinegraben, including hydrothermal vein-type deposits like Badenweiler and the Michael mine near Lahr. They all share the same fluid origin and formation process and only differ in details of their host rock and fluid cooling paths. The mechanism of fluid mixing also seems to be responsible for the formation of other MVT deposits in Europe (e.g., Réocin, Northern Spain; Trèves, Southern France; and Cracow-Silesia, Poland), which show notable similarities in terms of their age, mineralogy. and mineral chemistry to the MVT deposit near Wiesloch.     

Hydrochemical Groundwater Evolution in the Bunter Sandstone Sequence of the Odenwald Mountain Range,Germany: A Laboratory and Field Study

Field and laboratory investigations were performed to identify the principal mechanisms of the hydrochemical groundwater evolution among low mineralised groundwater in the Triassic Bunter sandstone aquifer of the Odenwald low mountain range, central Germany. Hydrochemical composition comprises low pH, SO₄-rich shallow groundwaters issued by springs (Ca-Mg-SO₄-type) grading to SO₄-poor deep groundwaters with near-neutral pH (Ca-HCO₃-type). Batch experiments of the original rock were run to determine primary mineral alteration reactions and the origin of dissolved ions. Principal experimental reactions comprise the decomposition of anorthite, K-feldspar, biotite and jarosite as mineral components of the original sandstone rock and the formation of clay minerals of the smectite group (Ca-montmorillonite, beidellite), and iron hydroxides as secondary minerals. Mobilisation of fluid inclusion in quartz grains contributes to Na and Cl concentrations in the leachates. The evolution of deep groundwater circulation proceeds by mineral alteration reactions calculated by the inverse modelling of both primary and secondary minerals to produce low-T mineral phases. The dissolution of K-feldspar converts Ca-montmorillonite to illite (illitisation). The formation of Na-beidellite correlates with decreasing concentration of Na in solution. Mineral reactions further proceed to the formation of kaolinite as stable mineral phase. As indicated by modelled adsorption curves, the decrease of SO₄ concentrations during groundwater evolution relates to the adsorption of SO₄ on iron hydroxides. The leaching of calcite indicated for individual groundwaters relates to the distribution of loess in the appropriate catchment areas.     

Late Pleistocene loess‐palaeosol sequences in the Vojvodina region,north Serbia

Late Pleistocene loess‐palaeosol sequences are widespread in the Vojvodina region, with thicknesses reaching a maximum of about 20 m. Our investigations include more than 40 of these loess sections. Geochronology of the last glacial loess‐palaeosol sequences, based on luminescence dating and amino acid racemisation, provides correlations between Upper Pleistocene loess‐palaeosol sediments in Vojvodina and comparable deposits at other European localities. Sedimentary logs of magnetic susceptibility, grain‐size measurements and carbonate content, combined with malacological evidence, indicate two main relatively cold and arid phases during the last glacial period, related to intensive accumulation of loess units L1L1 and L1L2, as well as many brief episodes of dry and windy climatic conditions, suggesting a possible relationship with cold events recorded in the North Atlantic region. Generally, late Pleistocene climate in the region was dry and relatively warm, compared with glacial period sites in central Europe, and was characterised by sharp differences between glacial and interglacial modes. New data and interpretations presented in this study emphasise the significance of loess‐palaeosol sequences in Vojvodina for the reconstruction of the temporal and spatial evolution of late Pleistocene palaeoclimate in this part of Europe. Copyright © 2007 John Wiley & Sons, Ltd.     

The Ksar Ghilane 002 shergottite—The 100th registered Martian meteorite fragment

We report on the discovery of a new shergottite from Tunisia, Ksar Ghilane (KG) 002. This single stone, weighing 538 g, is a coarse‐grained basaltic shergottite, mainly composed of maskelynitized plagioclase (approximately 52 vol%) and pyroxene (approximately 37 vol%). It also contains Fe‐rich olivine (approximately 4.5 vol%), large Ca‐phosphates, including both merrillites and Cl‐apatites (approximately 3.4 vol%), minor amounts of silica or SiO₂‐normative K‐rich glass, pyrrhotite, Ti‐magnetite, ilmenite, and accessory baddeleyite. The largest crystals of pyroxene and plagioclase reach sizes of approximately 4 to 5 mm. Pyroxenes (Fs_26–96En_5–50Wo_2–41). They typically range from cores of about Fs₂₉En₄₁Wo₃₀ to rims of about Fs₆₈En₁₄Wo₁₇. Maskelynite is Ab_41–49An_39–58Or_1–7 in composition, but some can be as anorthitic as An₉₃. Olivine (Fa_91–96) occurs mainly within symplectitic intergrowths, in paragenesis with ilmenite, or at neighboring areas of symplectites. KG 002 is heavily shocked (S5) as indicated by mosaic extinction of pyroxenes, maskelynitized plagioclase, the occurrence of localized shock melt glass pockets, and low radiogenic He concentration. Oxygen isotopes confirm that it is a normal member of the SNC suite. KG 002 is slightly depleted in LREE and shows a positive Eu anomaly, providing evidence for complex magma genesis and mantle processes on Mars. Noble gases with a composition thought to be characteristic for Martian interior is a dominant component. Measurements of ¹⁰Be, ²⁶Al, and ⁵³Mn and comparison with Monte Carlo calculations of production rates indicate that KG 002 has been exposed to cosmic rays most likely as a single meteoroid body of 35–65 cm radius. KG 002 strongly resembles Los Angeles and NWA 2800 basaltic shergottites in element composition, petrography, and mineral chemistry, suggesting a possible launch‐pairing. The similar CRE ages of KG 002 and Los Angeles may suggest an ejection event at approximately 3.0 Ma.     

Diamonds from Jagersfontein (South Africa): messengers from the sublithospheric mantle

The diamond population from the Jagersfontein kimberlite is characterized by a high abundance of eclogitic, besides peridotitic and a small group of websteritic diamonds. The majority of inclusions indicate that the diamonds are formed in the subcratonic lithospheric mantle. Inclusions of the eclogitic paragenesis, which generally have a wide compositional range, include two groups of eclogitic garnets (high and low Ca) which are also distinct in their rare earth element composition. Within the eclogitic and websteritic suite, diamonds with inclusions of majoritic garnets were found, which provide evidence for their formation within the asthenosphere and transition zone. Unlike the lithospheric garnets all majoritic garnet inclusions show negative Eu-anomalies. A narrow range of isotopically light carbon compositions (δ¹³C −17 to −24 ‰) of the host diamonds suggests that diamond formation in the sublithospheric mantle is principally different to that in the lithosphere. Direct conversion from graphite in a subducting slab appears to be the main mechanism responsible for diamond formation in this part of the Earth’s mantle beneath the Kaapvaal Craton. The peridotitic inclusion suite at Jagersfontein is similar to other diamond deposits on the Kaapvaal Craton and characterized by harzburgitic to low-Ca harzburgitic compositions.