Chemical composition of wet and dry atmospheric depositions in an urban environment: local,regional and long-range influences

The results of a 8 year survey of wet and dry depositions collected in Bologna (Northern Italy) are presented and discussed: monthly fluxes of the main ions (hydrogen, sodium, potassium, calcium, magnesium, ammoniacal and nitrate nitrogen, sulphate and chloride) have been registered and statistically discussed. The trend of hydrogen ion, whose largest correlation in the global deposition was found with sulphate, is clearly downwards, with peaks mainly in winter months. By means of a data factor analysis, three main sources to explain the variability of the deposition chemistry were recognized: an anthropogenic contribution (particularly represented by NO₃ ⁻, SO₄ ²⁻, H⁺), the sea spray (Na⁺, Cl⁻ and, to a lesser extent, K⁺ and Mg²⁺) and a terrigenous fraction, particularly characterized by higher Ca²⁺ concentration; however, some concentration peaks of this ion have been found in association with some episodes of Saharan dust transportation.     

Effects of non-stoichiometry on the spinel structure at high pressure: Implications for Earth’s mantle mineralogy

A non-stoichiometric sample of spinel with composition ^T(Mg_0.4Al_0.6)^M(Al_1.8□_0.2)O₄ was investigated by single-crystal X-ray diffraction in situ up to about 8.7 GPa using a diamond anvil cell. The P(V) data were fitted using a third-order Birch-Murnaghan equation of state and the unit-cell volume V₀, the bulk modulus K_T0 and its first pressure derivative K′ were refined simultaneously providing the following coefficients: V₀ = 510.34(6) Å³, K_T0 = 171(2) GPa, K′ = 7.3(6). This K_T0 value represents the lowest ever found for spinel crystal structures. Comparing our data with a stoichiometric and natural MgAl₂O₄ (pure composition) we observe a decrease in K_T0 by about 11.5% and a strong increase in K′ by about 33%. These results demonstrate how an excess of Al accompanied by the formation of significant cation vacancies at octahedral site strongly affects the thermodynamic properties of spinel structure. If we consider that the estimated mantle composition is characterized by 3-5% of Al₂O₃ this could imply an Mg/Al substitution with possible formation of cation vacancies. The results of our study indicate that geodynamic models should take into account the potential effect of Mg/Al substitution on the incompressibility of the main mantle-forming minerals (olivine, wadsleyite, ringwoodite, Mg-perovskite).     

Relativistic simulations of the phase-transition-induced collapse of neutron stars

An increase in the central density of a neutron star may trigger a phase transition from hadronic matter to deconfined quark matter in the core, causing it to collapse to a more compact hybrid star configuration. We present a study of this, building on previous work by Lin et al.. We follow them in considering a supersonic phase transition and using a simplified equation of state, but our calculations are general relativistic (using 2D simulations in the conformally flat approximation) as compared with their 3D Newtonian treatment. We also improved the treatment of the initial phase transformation, avoiding the introduction of artificial convection. As before, we find that the emitted gravitational wave spectrum is dominated by the fundamental quasi-radial and quadrupolar pulsation modes but the strain amplitudes are much smaller than suggested previously, which is disappointing for the detection prospects. However, we see significantly smaller damping and observe a non-linear mode resonance which substantially enhances the emission in some cases. We explain the damping mechanisms operating, giving a different view from the previous work. Finally, we discuss the detectability of the gravitational waves, showing that the signal-to-noise ratio for current or second generation interferometers could be high enough to detect such events in our Galaxy, although third generation detectors would be needed to observe them out to the Virgo cluster, which would be necessary for having a reasonable event rate.     

Accurate hypocentre locations in the Middle-Durance Fault Zone, South-Eastern France

A one-dimensional velocity model and station corrections for the Middle-Durance fault zone (south-eastern France) were computed by inverting P-wave arrival times recorded on a local seismic network of 8 stations. A total of 93 local events with a minimum of 6 P-phases, RMS 0.4 s and a maximum gap of 220° were selected. Comparison with previous earthquake locations shows an improvement for the relocated earthquakes. Tests were carried out to verify the robustness of inversion results in order to corroborate the conclusions drawn from our findings. The obtained minimum 1-D velocity model can be used to improve routine earthquake locations and represents a further step toward more detailed seismotectonic studies in this area of south-eastern France.     

The mechanics of mudslides as a cyclic undrained–drained process

Data collected by monitoring suggest that the movement of mudslides essentially develops through alternating stages of undrained–drained deformation. Undrained conditions are established as a consequence of landslide mobilisation or reactivation. Every acceleration phase is followed by progressive deceleration associated with dissipation of excess pore pressure. This paper reports the results of some simple numerical analyses performed to investigate the role of pore pressure on mudslide behaviour.     

Fractal approaches in investigating the time dynamics of self-potential hourly variability

Fractal tools have been used to investigate the time dynamics of hourly self-potential data, recorded during the year 2001 by five geoelectrical stations located in one of the most seismic areas of southern Italy. Scaling behaviour has been revealed by means of different statistics: the Lomb Periodogram method, the Detrended Fluctuation Analysis, the Higuchi analysis and the mean distance spanned within the time L. The values of the scaling exponents estimated by means of these methods indicate that the temporal fluctuations of the geoelectrical signals are not typical of purely random stochastic processes (i.e. white noise), but evidence the presence of long-range correlations. Furthermore, it is found that these correlations are linear.     

Time-clustering analysis of volcanic occurrence sequences

We investigate the time dynamics of worldwide volcanic activity in order to find the presence of time correlation structures, by applying the Fano factor (FF) method. The analysis, performed on 35 time-occurrence volcanic eruptive sequences with volcanic explosivity index (VEI≥0) has revealed fractal behaviors in the most of the data sets considered, with fractal exponent α ranging from ∼0.2 to 0.9.