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51.
This study (2002/2004) examines the effect of artificial reef (AR) structures off the southern coast of Portugal on biogeochemical process and nutrient cycling. Organic and inorganic carbon, nitrogen, phosphorus and chlorophyll a were determined monthly in sediment cores and settled particles for a two-year period. Ammonium, nitrates, phosphates, silicates, total organic nitrogen and phosphorus, chlorophyll a and phaeopigments were also determined monthly in water samples within AR and control sites. Results of the two-year study showed that: (i) there was a significant exponential fit between organic carbon and chlorophyll a (r2=0.91; p<0.01) in reef sediment suggesting an increase of benthic productivity; (ii) organic carbon and nitrogen content in settled particles within AR environment was about four times higher two years after reef deployment; (iii) nutrients and chlorophyll a in the water column were higher at AR than control site. Two years after AR deployment, dissolved organic and inorganic compounds in near bottom water were 30-60% higher, emphasizing benthic remineralization processes at AR's organically rich sediment. Marked chemical changes in the ecosystem were observed during the two-year study period, reinforcing the importance of these structures for sandy coastal areas rehabilitation through trophic chain pull-out. 相似文献
52.
Due to their potential retention capacity, clay minerals have been proposed for use in the engineered barriers for the storage of high-level radioactive actinides in deep geological waste repositories. However, there is still a lack of data on the sorption of actinides in clays in conditions simulating those of the repositories. The present article examines the sorption of two lanthanides (actinide analogues) in a set of smectitic clays (FEBEX bentonite, MX80 bentonite, hectorite, saponite, Otay montmorillonite, and Texas montmorillonite). Distribution coefficients (Kd) were determined in two media: water and 0.02 mol L−1 Ca, the latter representing the cement leachates that may modify the chemical composition of the water in contact with the clay. The Kd values of the lanthanides used in the experiments (La and Lu) varied greatly (25-50 000 L kg−1) depending on the ionic medium (higher values in water than in the Ca medium), the initial lanthanide concentration (up to three orders of magnitude decrease inversely with lanthanide concentration), and the examined clay (up to one order of magnitude for the same lanthanide and sorption medium). Freundlich and Langmuir isotherms were used to fit sorption data to allow comparison of the sorption parameters among smectites. The model based on the two-site Langmuir isotherms provided the best fit of the sorption data, confirming the existence of sorption sites with different binding energies. The sites with higher sorption affinity were about 6% of the total sorption capacity in the water medium, and up to 17% in the Ca medium, although in this latter site sorption selectivity was lower. The wide range of Kd values obtained regarding the factors examined indicated that the retention properties of the clays should also be considered when selecting a suitable clay for engineered barriers. 相似文献
53.
C. A. Santos V. Urdaneta G. Jaimes L. Trujillo 《Rock Mechanics and Rock Engineering》2010,43(3):351-359
The effects of the rheological properties of fluids on the acoustic behavior of heterogeneous media like rocks are usually
very difficult to characterize. We show here that, in ultrasonic tests and their spectral characterizations, signal attenuation
is the most evident difference between water and oil saturated rock samples. Density effects, as explained by the inertial
component of the Biot’s poroelastic theory, along with entropic analysis seem to provide a good understanding of the pore-fluid
effects on the acoustic response of saturated rocks. 相似文献
54.
55.
Usama Massoud Fernando Santos Mohamed A. Khalil Ayman Taha Abbas M. Abbas 《Hydrogeology Journal》2010,18(3):699-710
The integration of geophysical data with direct hydrogeological measurements can provide a minimally invasive approach to characterize the subsurface at a variety of resolutions and over many spatial scales. The field of hydrogeophysics has attracted much attention during the last two decades. In this domain, the geophysical data inverted to geophysical models are interpreted in terms of the hydrogeology to serve as a basis for the definition of hydraulic models in the areas of interest. The hydraulic conductivity (K) value measured in a reference borehole has been combined with the electrical conductivity obtained from nearby geo-electromagnetic sounding data in the Cenomanian (Upper Cretaceous) aquifer, central Sinai, Egypt. The resulting relation was interpreted with Dar Zarrouk parameters to infer the transmissivity variations at other vertical electrical sounding locations, where K values are unknown. Coincident transient electromagnetic data have been adopted to increase accuracy while interpreting the aquifer geoelectrical properties. The results indicate that the transmissivity values in the aquifer of interest vary from 2,446 to 9,694 m2/day, and K varies from 12.9 to 57.0 m/day throughout the studied area. 相似文献
56.
While there is already a comprehensive understanding of the effects of environmental variables, such as dissolved oxygen, temperature and salinity, on the structure, biomass and metabolism of aquatic biota in estuarine habitats, the effect of sedimentation, a harmful underlying factor, remains unclear. The aim of this study was to assess the differences in fish assemblages along the freshwater to salt water gradient of a large tropical estuary, and to evaluate the effects on them of habitat disturbance associated with shallow water sedimentation in the intertidal areas. Fish and environmental variables were recorded in the upper, middle and lower salinity zones of the estuary at ebb tide in both the dry and wet seasons. Sediment samples associated with different levels of habitat disturbance were analysed using granulometry, and their organic content and dissolved oxygen levels were quantified. Water temperature, salinity, pH and dissolved oxygen levels were also measured. Habitat disturbance was found to be correlated with the density, biomass and richness of fish assemblages. A total of 77 species were recorded, forming two distinct fish assemblages, with the Eleotridae family dominating in the upper zone, and Gerreidae, Gobiidae and Tetraodontidae the most common in the middle and lower estuary. Changes in the structure of fish assemblages, including reductions in density, biomass and richness, were associated with disturbance to natural features, where muddy sediment was replaced by sandy sediment and the quantity of organic matter fell. Atherinella brasiliensis was the species which showed a preference for the disturbed areas in the middle and lower zones, while Dormitator maculatus showed a preference for them in the upper estuary. They may be taken as indicators of habitat disturbance due to shallow sedimentation. 相似文献
57.
Jean Pierre Ometto Ana Paula Aguiar Talita Assis Luciana Soler Pedro Valle Graciela Tejada David M. Lapola Patrick Meir 《Climatic change》2014,124(3):545-560
As land use change (LUC), including deforestation, is a patchy process, estimating the impact of LUC on carbon emissions requires spatially accurate underlying data on biomass distribution and change. The methods currently adopted to estimate the spatial variation of above- and below-ground biomass in tropical forests, in particular the Brazilian Amazon, are usually based on remote sensing analyses coupled with field datasets, which tend to be relatively scarce and often limited in their spatial distribution. There are notable differences among the resulting biomass maps found in the literature. These differences subsequently result in relatively high uncertainties in the carbon emissions calculated from land use change, and have a larger impact when biomass maps are coded into biomass classes referring to specific ranges of biomass values. In this paper we analyze the differences among recently-published biomass maps of the Amazon region, including the official information used by the Brazilian government for its communication to the United Nation Framework on Climate Change Convention of the United Nations. The estimated average pre-deforestation biomass in the four maps, for the areas of the Amazon region that had been deforested during the 1990–2009 period, varied from 205?±?32 Mg ha?1 during 1990–1999, to 216?±?31 Mg ha?1 during 2000–2009. The biomass values of the deforested areas in 2011 were between 7 and 24 % higher than for the average deforested areas during 1990–1999, suggesting that although there was variation in the mean value, deforestation was tending to occur in increasingly carbon-dense areas, with consequences for carbon emissions. To summarize, our key findings were: (i) the current maps of Amazonian biomass show substantial variation in both total biomass and its spatial distribution; (ii) carbon emissions estimates from deforestation are highly dependent on the spatial distribution of biomass as determined by any single biomass map, and on the deforestation process itself; (iii) future deforestation in the Brazilian Amazon is likely to affect forests with higher biomass than those deforested in the past, resulting in smaller reductions in carbon dioxide emissions than expected purely from the recent reductions in deforestation rates; and (iv) the current official estimate of carbon emissions from Amazonian deforestation is probably overestimated, because the recent loss of higher-biomass forests has not been taken into account. 相似文献
58.
B. Gudveig Baarli Mrio Cacho Carlos M. da Silva Markes E. Johnson Eduardo J. Mayoral Ana Santos 《Geological Journal》2014,49(1):90-106
Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m3 of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
59.
Luís Pinheiro Branco António Topa Gomes António Silva Cardoso Carla Santos Pereira 《Geotechnical and Geological Engineering》2014,32(4):911-922
The renewal imposed by the Eurocodes regarding the methodologies of safety evaluation requires a statistical analysis of the variability of ground geotechnical parameters. However, the studies published in the reviewed literature do not cover the typical materials from the northeast region of Portugal—residual soils from granite—to which a strong heterogeneity is associated. Hence, a statistical characterization of the natural variability of a granite residual soil from Porto has been made through a significant amount of experimental tests, focusing on its geomechanical properties. In order to provide a database for probabilistic analysis of problems involving this type of soils, an appropriate statistical law has been used to model its variability, which has been quantified by means of coefficients of variation and scales of fluctuation. 相似文献
60.
The troposphere delay is an important source of error for precise GNSS positioning due to its high correlation with the station height parameter. It has been demonstrated that errors in mapping functions can cause sub-annual biases as well as affect the repeatability of GNSS solutions, which is a particular concern for geophysical studies. Three-dimensional ray-tracing through numerical weather models (NWM) is an excellent approach for capturing the directional and daily variation of the tropospheric delay. Due to computational complexity, its use for positioning purposes is limited, but it is an excellent tool for evaluating current state-of-the-art mapping functions used for geodetic positioning. Many mapping functions have been recommended in the past such as the Niell Mapping Function (NMF), Vienna Mapping Function 1 (VMF1), and the Global Mapping Function (GMF), which have been adopted by most IGS analysis centers. A new Global Pressure Temperature model (GPT2) has also been developed, which has been shown to improve upon the original atmospheric model used for the GMF. Although the mapping functions mentioned above use the same functional formulation, they vary in terms of their atmospheric source and calibration approach. A homogeneous data set of three-dimensional ray-traced delays is used to evaluate all components of the mapping functions, including their underlying functional formulation, calibration, and compression method. Additionally, an alternative representation of the VMF1 is generated using the same atmospheric source as the truth data set to evaluate the differences in ray-tracing methods and their effect on the end mapping function. The results of this investigation continue to support the use of the VMF1 as the mapping function of choice when geodetic parameters are of interest. Further support for the GPT2 and GMF as reliable back-ups when the VMF1 is not available was found due to their high consistency with the NWM-derived mapping function. Additionally, a small latitude-dependent bias in station height was found in the current mapping functions. This bias was identified to be due to the assumption of a constant radius of the earth and was largest at the poles and at the equator. Finally, an alternative version of the VMF1 is introduced, namely the UNB-VMF1 which provides users with an independent NWM-derived mapping function to support geodetic positioning. 相似文献