A Fe K-edge XAS study of amethyst

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.     

Seismic design of floor–wall joints of multi-storey CLT buildings to comply with regularity in elevation

The effects of irregularity in elevation of cross-laminated timber buildings have not been fully analysed in literature to provide useful information for the design. In this work, a number of building configurations, regular or irregular in elevation, characterized by a different arrangement per storey of the floor–wall joints have been analysed by means of non-linear dynamic analyses. Comparative results in terms of ratio between the behaviour q-factor of the investigated irregular configurations and that of reference regular ones, show that less dissipative capacity can be expected if the building is irregular due to a disequilibrium among storeys between the actual and the required strength provided by the floor–wall joints. A correlation method to estimate the behaviour q-factor for perfectly regular cross-laminated timber buildings is here presented and extended to in-elevation irregular ones. A new empirical formulation to assess the reliable corrective factor accounting for the irregularity in elevation of cross-laminated timber buildings, according to Eurocode 8 provisions, is also proposed. A final discussion about the implications of in-elevation irregularity on the building design is reported.     

Numerical modelling of installation effects for diaphragm walls in sand

The scopes of this work are to study the mechanisms of load transfer and the deformations of the ground during slurry trenching and concreting in dry sand and to evaluate their effects on service structural loads, wall deflections and ground displacements behind the wall caused by subsequent excavation. A series of three-dimensional finite element analyses was carried out modelling the installation of diaphragm walls consisting of panels of different length. The soil was modelled as either linearly elastic-perfectly plastic or incrementally non-linear (hypoplastic) with elastic strain range. Plane strain analyses of diaphragm walls of identical cross section were also carried out in which wall installation was either modelled or the wall was wished in place (WIP). The analyses predict ground movements consistent with the experimental observations both in magnitude and trend. The results also show that the maximum horizontal wall deflections and structural loads reduce with increasing panel aspect ratio towards a minimum which is about twice the value computed for WIP analyses. Panel aspect ratios should be larger than about three to take advantage of the three-dimensional effects. The pattern and magnitude of surface vertical displacements obtained from linearly elastic-perfectly plastic analyses, no matter whether three- or two-dimensional, are unrealistic.     

Assessment of coastal flooding hazard along the Emilia Romagna littoral,IT

Aim of this paper is to develop simple tools for mapping — at regional and local scale — coastal areas exposed at flooding risk. A two-step simplified procedure for coastal management purposes is presented and is applied to Emilia Romagna (Italy), whose low and sandy coast faces the relatively mild Northern Adriatic Sea. The procedure is composed by a 1D conceptual model to determine flooding probability along wide coastal stretches and by a more detailed 2D Level II reliability method, that provides local quantitative statistical maps of inland flooding propagation. Qualitative maps obtained by literature approaches and quantitative results of flooding probability along the littoral show a good agreement. A coastal flood state indicator is proposed to rapidly assess coastal hazard.     

Population distribution and urban growth in Southern Italy, 1871–2011: emergent polycentrism or path-dependent monocentricity?

This study assesses changes in population distribution and the expansion of urban settlements in Southern Italy between 1871 and 2011. Four demographic phases are identified: (i) spatially balanced, mild population growth (1871–1921); (ii) moderate population increase concentrated in coastal and lowland areas (1921–1951); (iii) rapid and diffused population growth (1951–1981); and (iv) population stability with settlement dispersion (1981–2011). While urban growth in the years preceding the 1980s reinforced the polarization in rich and poor areas along the urban-to-rural gradient, since the early 1990s both urban and rural areas showed population dynamics that consolidated low-density settlements scattered around the largest cities. This path, however, does not reflect the evolution towards a more spatially balanced urban development, as observed in other European regions. Causes and consequences of the persistence of a fragmented urban hierarchy with dense settlements and sprawl concentrated around the main cities are finally discussed.     

Micro-seismic monitoring after the shipwreck of the Costa Concordia at Giglio Island (Italy)

A micro-seismic network was used for monitoring the wreck of the Costa Concordia cruise ship, wrecked and run agrounded along the Giglio Island coasts during the night of 13 January 2012, until its removal. The seismic traces were processed by means of real-time and “a posteriori” procedures to detect transients that could be ascribed to wreck movements on the sea bed to integrate this information in an early warning system for assessing the wreck stability. After a first discrimination of the transients using amplitude criteria we proceeded to the localization of the detected signals to focus the attention only on the transients originated in the shipwreck resting area. The results showed that most of the events localized on the wreck were likely related to human work activities or sudden internal brittle failure but not to displacements on the seafloor. Instead, the displacements are associated to the impact on the vessel of great sea storms which approach were well correlated with the increasing seismic noise at low frequency. The carried out procedures based on this unique dataset represent an opportunity to test seismic monitoring techniques also in not usual engineering context to support emergency management activities.     

Identifying rift zones on volcanoes: an example from La Réunion island,Indian Ocean

We describe a methodology for identifying complex rift zones on recent or active volcanoes, where structures hidden by recent deposits and logistical conditions might prevent carrying out detailed fieldwork. La Réunion island was chosen as a test-site. We used georeferenced topographic maps, aerial photos and digital terrain models to perform a statistical analysis of several morphometric parameters of pyroclastic cones. This provides a great deal of geometric information that can help in distinguishing the localisation and orientation of buried magma-feeding fractures, which constitute the surface expression of rift zones. It also allowed the construction of a complete GIS database of the pyroclastic cones. La Réunion is a perfect example where past and active volcanic rift zones are mostly expressed by clusters of monogenic centres. The data has been validated in the field and compared and integrated with the distribution and geometry of dyke swarms. Results show the presence of several main and secondary rift segments of different ages, locations and orientations, whose origin is discussed considering regional tectonics, local geomorphology, and volcano deformation.     

From sprawl to compactness and back: population dynamics (1848–2011) and the economic structure of a Mediterranean city

In the recent decades southern European cities experienced morphological changes and a demographic transition towards zero (or negative) growth and aging. Population dynamics shifted from the impressive growth of the post-industrial period into recent de-concentration processes determining the spillover of commercial and residential settlements across the surrounding rural areas. Based on long-term demographic data, the present study hypothesizes that urban expansion did not follow a one-way linear path from compactness to dispersion while reflecting differentiated growth patterns based on the specific socioeconomic context at the local scale. Along a sufficiently long time period non-linear expansion waves alternating settlement densification and scattering are expected to be found especially in complex urban contexts such as those developed in the Mediterranean region. This hypothesis was tested for a paradigmatic case study in southern Europe (Athens, Greece) using demographic data covering 160 years (1848–2011). Urban growth in Athens was assessed through the analysis of long-term census data made available on a district level. These data provide information on the spatial distribution of resident population and characterize distinct expansion waves according to the dominant socioeconomic context. Results of the study were discussed in the light of the debate on future development of the Mediterranean cities and the (changing) economic relations with the surrounding region.