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171.
ABSTRACT

In this paper recent improvements of the R-Index method are presented, based on its application on several projects in various geological and geotechnical contexts. The R-Index derives from a probabilistic procedure conceived for estimating the reliability level of the Geological and Geotechnical Design Model used to design underground structures, especially tunnels. The R-Index takes into account the geological complexity of a site and recommended empirical scores (based on expert judgement) for different quality levels of geological surveys and geotechnical and geophysical investigations.  相似文献   
172.
A recently described micrometeorite from the Nubian desert (Sudan) contains an exotic Al-Cu-Fe assemblage closely resembling that observed in the Khatyrka chondrite (Suttle et al., 2019; Science Reports 9:12426). We here extend previous investigations of the geochemical, mineralogical, and petrographic characteristics of the Sudan spherule by measuring oxygen isotope ratios in the silicate components and by nano-scale transmission electron microscopy study of a focused ion beam foil that samples the contact between Al-Cu alloys and silicates. O-isotope work indicates an affinity to either OC or CR chondrites, while ruling out a CO or CM precursor. When combined with petrographic evidence we conclude that a CR chondrite parentage is the most likely origin for this micrometeorite. SEM and TEM studies reveal that the Al-Cu alloys mainly consist of Al metal, stolperite (CuAl), and khatyrkite (CuAl2) together with inclusions in stolperite of a new nanometric, still unknown Al-Cu phase with a likely nominal Cu3Al2 stoichiometry. At the interface between the alloy assemblage and the surrounding silicate, there is a thin layer (200 nm) of almost pure MgAl2O4 spinel along with well-defined and almost perfectly spherical metallic droplets, predominantly iron in composition. The study yields additional evidence that Al-Cu alloys, the likely precursors to quasicrystals in Khatyrka, occur naturally. Moreover, it implies the existence of multiple pathways leading to the association in reduced form of these two elements, one highly lithophile and the other strongly chalcophile.  相似文献   
173.
River islands are defined as discrete areas of woodland vegetation surrounded by either water‐filled channels or exposed gravel. They exhibit some stability and are not submerged during bank‐full flows. The aim of the study is to analyze the dynamics of established, building, and pioneer islands in a 30‐km‐long reach of the gravel‐bed Piave River, which has suffered from intense and multiple human impacts. Plan‐form changes of river features since 1960 were analyzed using aerial photographs, and a LiDAR was used to derive the maximum, minimum and mean elevation of island surfaces, and maximum and mean height of their vegetation. The results suggest that established islands lie at a higher elevation than building and pioneer islands, and have a thicker layer of fine sediments deposited on their surface after big floods. After the exceptional flood in 1966 (RI > 200 years) there was a moderate increase in island numbers and extension, followed by a further increase from 1991, due to a succession of flood events in 1993 and 2002 with RI > 10 years, as well as a change in the human management relating to the control of gravel‐mining activities. The narrowing trend (1960–1999) of the morphological plan form certainly enhanced the chance of islands becoming established and this explains the reduction of the active channel, the increase in established islands and reduction of pioneer islands.  相似文献   
174.
Experiments have been performed to determine the effect of deformation on degassing of bubble-bearing melts. Cylindrical specimens of phonolitic composition, initial water content of 1.5 wt.% and 2 vol.% bubbles, have been deformed in simple-shear (torsional configuration) in an internally heated Paterson-type pressure vessel at temperatures of 798–848 K, 100–180 MPa confining pressure and different final strains. Micro-structural analyses of the samples before and after deformation have been performed in two and three dimensions using optical microscopy, a nanotomography machine and synchrotron tomography. The water content of the glasses before and after deformation has been measured using Fourier Transform Infrared Spectroscopy (FTIR). In samples strained up to a total of γ ∼ 2 the bubbles record accurately the total strain, whereas at higher strains (γ ∼ 10) the bubbles become very flattened and elongate in the direction of shear. The residual water content of the glasses remains constant up to a strain of γ ∼ 2 and then decreases to about 0.2 wt.% at γ ∼ 10. Results show that strain enhances bubble coalescence and degassing even at low bubble volume-fractions. Noticeably, deformation produced a strongly water under-saturated melt. This suggests that degassing may occur at great depths in the volcanic conduit and may force the magma to become super-cooled early during ascent to the Earth’s surface potentially contributing to the genesis of obsidian.  相似文献   
175.
The variability and scales of the sea surface structure of the northern Ionian Sea from January 1993 to December 2007 were studied by means of altimeter remotely-sensed weekly Sea Level Anomaly (SLA) objective maps. Variability in the sea surface structure was addressed by means of empirical orthogonal function (EOF) analysis and, assuming an exponential correlation model, scales of the SLA field were quantified as e-folding distances of the SLA autocorrelation function. The variability in the sea surface structure, described by the first three EOFs, which cumulatively explain 60.3% of the data set variance, is characterized by a large-scale structure with variability on a time scale of ∼10-13 years and, on shorter scales, an eddy system with variability on an annual scale. The variability in the large-scale structure describes an overturning of the SLA field, which took place in 1997, and determines a reversal of the geostrophic upper-layer circulation. As the large-scale circulation transition takes place, time-dependent spectral analysis of EOF coefficients shows a redistribution of the spectral energy from inter-annual to semi-annual and monthly components. Spatial scales display variability on an annual and inter-annual time scale. On the annual time scale, variability in spatial scales is characterized by longer values in summer-fall and shorter in winter-spring. Inter-annual variability in spatial scales is demonstrated by a remarkable drop in the values during fall in the period 1998-2000. We propose an explanation of the variability in horizontal scales in terms of the redistribution of water masses and related modifications of the vertical structure of the water column associated with different regimes of the basin-scale circulation.  相似文献   
176.
A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca18.858 Na0.028 Ba0.004 K0.006 Sr0.0050.098)19.000 (Al8.813 Ti0.037 Mg2.954 Mn0.008 Fe0.1142+ Fe1.3753+ Cr0.008 B0.202)13.511 Si18.000(O0.261 F0.940 OH7.799)9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si2p, Al2p, Mg1s, and Ca2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si–O bonds at the surface. The presence of eight- and nine-coordinated Ca cations is suggested by a large XPS feature resulting from the merging of Ca2p3/2 and Ca2p1/2 peaks at 348.45 and 352.05 eV, respectively.  相似文献   
177.
The results of integral pumping tests (IPTs) performed in the city of Fabriano, Italy, are presented. The IPT methodology was developed by the European Union project INCORE, as a tool for groundwater investigation and source localization in contaminated areas. This methodology consists of a multiple-well pumping test in which the wells are positioned along a control plane downstream of suspected contaminant source zones and perpendicular to the mean groundwater flow direction. During the pumping, concentration time series of target contaminants are measured. In Fabriano, two control planes were realized to identify a chlorinated aliphatic hydrocarbon plume, to estimate the mass fluxes and draw up a ranked list of the main contamination sources. A numerical flow model was implemented to support the IPT design and to interpret the results. This study revealed low-level trichloroethylene contamination (concentration below 8 μg/l), tetrachloroethylene contamination (mean concentration up to 500 μg/l) and a mass flow rate of about 300 g/day. Through the application of the IPT method, the mean contaminant concentrations, the spatial distribution of concentration values along the control planes, and the total contaminant mass flow rates were evaluated, and the investigation area was reduced for further and deeper investigation activities.  相似文献   
178.
Variable-density groundwater models require extensive computational resources, particularly for simulations representing short-term hydrologic variability such as tidal fluctuations. Saltwater-intrusion models usually neglect tidal fluctuations and this may introduce errors in simulated concentrations. The effects of tides on simulated concentrations in a coastal aquifer were assessed. Three analyses are reported: in the first, simulations with and without tides were compared for three different dispersivity values. Tides do not significantly affect the transfer of a hypothetical contaminant into the ocean; however, the concentration difference between tidal and non-tidal simulations could be as much as 15%. In the second analysis, the dispersivity value for the model without tides was increased in a zone near the ocean boundary. By slightly increasing dispersivity in this zone, the maximum concentration difference between the simulations with and without tides was reduced to as low as 7%. In the last analysis, an apparent dispersivity value was calculated for each model cell using the simulated velocity variations from the model with tides. Use of apparent dispersivity values in models with a constant ocean boundary seems to provide a reasonable approach for approximating tidal effects in simulations where explicit representation of tidal fluctuations is not feasible.  相似文献   
179.
The Multi-scale Soil Information System (MEUSIS) can be a suitable framework for building a nested system of soil data that could facilitate interoperability through a common coordinate reference system, a unique grid coding database, a set of detailed and standardized metadata, and an open exchangeable format. In the context of INSPIRE Directive, MEUSIS may be implemented as a system facilitating the update of existing soil information and accelerating the harmonization of various soil information systems. In environmental data like the soil one, it is common to generalize accurate data obtained at the field to coarser scales using either the pedotransfer rules or knowledge of experts or even some statistical solutions which combine single values of spatially distributed data. The most common statistical process for generalization is averaging the values within the study area. In this paper, we do not present a simple averaging of numerical values without any further processed information. The upscaling process is accompanied with significant statistical analysis in order to demonstrate the method suitability. The coarser resolution nested grids cells (10??? 10?km) represent broad regions where the calculated soil property (e.g., organic carbon) can be accurately upscaled. Multi-scaled approaches are urgently required to integrate different disciplines (such as Statistics) and provide a meta-model platform to improve current mechanistic modeling frameworks, request new collected data, and identify critical research questions. Past papers have described in detail the upscaling methodology while our present approach is to demonstrate an important application of this methodology accompanied with statistical evidence.  相似文献   
180.
Climate Dynamics - Coarse resolution global climate models (GCMs) cannot resolve fine-scale drivers of regional climate, which is the scale where climate adaptation decisions are made. Regional...  相似文献   
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