A Century of Solar Ca <Emphasis Type="SmallCaps">ii</Emphasis> Measurements and Their Implication for Solar UV Driving of Climate

Spectroheliograms and disk-integrated flux monitoring in the strong resonance line of Ca ii (K line) provide the longest record of chromospheric magnetic plages. We compare recent reductions of the Ca ii K spectroheliograms obtained since 1907 at the Kodaikanal, Mt. Wilson, and US National Solar Observatories. Certain differences between the individual plage indices appear to be caused mainly by differences in the spectral passbands used. Our main finding is that the indices show remarkably consistent behavior on the multidecadal time scales of greatest interest to global warming studies. The reconstruction of solar ultraviolet flux variation from these indices differs significantly from the 20th-century global temperature record. This difference is consistent with other findings that, although solar UV irradiance variation may affect climate through influence on precipitation and storm tracks, its significance in global temperature remains elusive.     

Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

Experiments on Surface Waves Interacting with Flexible Aquatic Vegetation

Surface wave interaction with aquatic vegetation appears to play a key role in coastal hydro-morpho-dynamics. As an example, the presence of a dense meadow at intermediate water depth is usually associated with a stable and resilient shore. Wave-meadow interactions are investigated here by means of physical modelling, with a focus on wave height distribution and hydrodynamics. The central part of a wave flume is covered by flexible artificial seagrass, composed of polyethylene leaves. This vegetation is tested in both near emergent and submerged conditions. The wave height reduction is evaluated by means of a drag coefficient defined from linear wave theory, which contains all the unknowns of the adopted methodology. The behaviour of such a coefficient is investigated as a function of a wave related Reynolds number. The influence of the flexibility of the leaves is also considered, together with a wave frequency parameter. The results show a complex behaviour with three different trends for near rigid, intermediate or highly flexible leaves. Amplitudes of the orbital velocities are investigated and show a fairly good match with the linear wave theory. On the contrary, the mean velocity along the water column appears to be modified by the seagrass for submerged leaves.     

Coanda effect in coastal flows

In the present paper some numerical simulations and experiments were carried out to study jet-wall interaction in shallow waters. Namely, modifications of the hydrodynamic field concerning the interaction of river run-off with a shallow coastal water body, due to the presence of marine structures, were investigated. Stratification effects due to salinity and temperature were neglected, and the interest was focused on barotropic features (Coanda effect). The numerical analysis was carried out by means of shallow water equations, numerically solved by finite difference, and the present method was validated by means of a typical simple-shaped test case. The experiments were carried out in a shallow water tank, flow visualizations were performed, and the velocity field was obtained by PIV. The main features of jet-wall interaction flow were investigated in simple-shaped geometries, and applications were shown for two practical cases: Pescara channel harbour (Adriatic Sea, Italy) and the proposed design of Latina harbour (Tyrrhenian Sea, Italy).     

Erosion-driven uplift of the modern Central Alps

We present a compilation of data of modern tectono-geomorphic processes in the Central European Alps which suggest that observed rock uplift is a response to climate-driven denudation. This interpretation is predominantly based on the recent quantification of basin-averaged Late Holocene denudation rates that are so similar to the pattern and rates of rock uplift rates as determined by geodetic leveling. Furthermore, a GPS data-based synthesis of Adriatic microplate kinematics suggests that the Central Alps are currently not in a state of active convergence. Finally, we illustrate that the Central Alps have acted as a closed system for Holocene redistribution of sediment in which the peri-Alpine lakes have operated as a sink for the erosional products of the inner Central Alps.While various hypotheses have been put forward to explain Central Alpine rock uplift (e.g. lithospheric forcing by convergence, mantle processes, or ice melting) we show with an elastic model of lithospheric deformation, that the correlation between erosion and rock uplift rates reflects a positive feedback between denudation and the associated isostatic response to unloading. Thus, erosion does not passively respond to advection of crustal material as might be the case in actively converging orogens. Rather, we suggest that the geomorphic response of the Alpine topography to glacial and fluvial erosion and the resulting disequilibrium for modern channelized and associated hillslope processes explains much of the pattern of modern denudation and hence rock uplift. Therefore, in a non-convergent orogen such as the Central European Alps, the observed vertical rock uplift is primarily a consequence of passive unloading due to erosion.     

Long-term growth and metropolitan spatial structures: an analysis of factors influencing urban patch size under different economic cycles

Urban forms are increasingly reflective of socio-economic change in metropolitan regions. The present study illustrates an original approach to identify latent mechanisms of urban growth through the analysis of metropolitan spatial structures and their proximate drivers of change. Urban transformations are evaluated here using built-up patches as the elementary analysis unit and background socio-economic attributes at four stages of the “city life cycle” (urbanization, suburbanization, dis-urbanization, re-urbanization). Regression models based on 13 indicators assessing urban patch area and shape, nearest neighbour urban patch area and shape, elevation, distance from 5 urban centres, 2 road infrastructures and sea coastline, were run with the aim to investigate direction and intensity of metropolitan growth in post-war Athens (1948–2012), a southern European city shifting from a compact mono-centric form towards discontinuous urban structures. Mono-centric configurations were characterized by linear dependence of urban patch size from the distance to central cities. Shifts toward scattered urban forms were associated with changes in the multivariate relationship between urban patch size and territorial drivers, pointing out the increased complexity of dispersed metropolitan structures. Our approach integrates economic and ecological visions of urban landscapes and contributes to understanding long-term mechanisms of metropolitan growth under dynamic spatial equilibriums. Investigating the multiple relationships between form and functions at the base of socio-economic transformations are relevant issues when identifying and profiling urbanization cycles.     

Detection of Miocene saucer‐shaped sills (offshore Senegal) via integrated interpretation of seismic,magnetic and gravity data

The Atlantic margin offshore Senegal has been explored by seismic reflection and GRAV‐MAG surveys. High‐amplitude, laterally transgressive seismic reflectors are found to coincide with gravimetric and magnetic highs. Once seismic data are integrated with potential fields modelling, these reflectors can be safely interpreted as saucer‐shaped igneous sills, up to some hundreds of metres thick, some km wide. The occurrence of hydrothermal vent complexes and forced folds in the stratigraphic sequence above the sills constrain the intrusion age to the Miocene. Field observations and in‐situ magnetic susceptibility measurements of Oligocene–Miocene and Quaternary igneous rocks emplaced in coastal Senegal support this interpretation.     

Latent Exurban Development: City Expansion Along the Rural-To-Urban Gradient in Growing and Declining Regions of Southern Europe

This paper quantifies the extent of exurban development in Mediterranean Europe. The assessment was carried out by studying changes in the urban-to-rural population density gradient between the years 1950 and 2010. Three of the six urban regions in this study have experienced population growth and moderate urban concentration, while two regions appear to be shifting toward population decline and urban de-concentration after having experienced compact expansion. A phase of recent re-urbanization has been observed in one region. Altogether, these findings indicate a common path of urban expansion among representative Mediterranean regions between 1950 and 1980 while, in the following period, the cities experienced distinct development phases. From this study, we conclude that exurban development is mainly the product of a shift from compact and dense to semi-compact and intermediate-density settlements. [Key words: semi-dense urban growth, density-distance curve, Mediterranean Europe].