Pliensbachian magnetostratigraphy: new data from Paris Basin (France)

Sampling of an industrial drill string from the northeastern Paris Basin (Montcornet, France) provides early Jurassic magnetostratigraphic data coupled with biochronological control. About 375 paleomagnetic samples were obtained from a 145 m thick series of Pliensbachian rocks. A composite demagnetization thermal up to 300°C and an alternating field up to 80 mT were used to separate the magnetic components. A low unblocking temperature component (<250°C) with an inclination of about 64° is interpreted as a present-day field overprint. The characteristic remanent component with both normal and reversed antipodal directions was isolated between 5 and 50 mT. Twenty-nine polarity intervals were recognized. Correlation of these new results from the Paris Basin with data from the Breggia Gorge section (Ticino, southern Alps, Switzerland), which is generally considered as the reference section for Pliensbachian magnetostratigraphy, reveals almost identical patterns of magnetic polarity reversals. However, the correlation implies significant paleontological age discrepancies. Revised age assignments of biostratigraphic data of Breggia as well as an objective evaluation of the uncertainties on zonal boundaries in both Breggia and Moncornet resolve the initial discrepancies between magnetostratigraphic correlations and biostratigraphic ages. Hence, the sequence of magnetic reversals is significantly strengthened and the age calibration is notably improved for the Pliensbachian, a stage for which sections combining adequate magnetic signal and biostratigraphic constraints are still very few.     

Yields of suspended sediment and dissolved solids from the Andean basins of Ecuador

Abstract

Water discharge and suspended and dissolved sediment data from three rivers (Napo, Pastaza and Santiago) in the Ecuadorian Amazon basin and a river in the Pacific basin (Esmeraldas) over a 9-year period, are presented. This data set allows us to present: (a) the chemical weathering rates; (b) the erosion rates, calculated from the suspended sediment from the Andean basin; (c) the spatio-temporal variability of the two regions; and (d) the relationship between this variability and the precipitation, topography, lithology and seismic activity of the area. The dissolved solids load from the Esmeraldas basin was 2 × 10⁶ t year^-1, whereas for the Napo, Pastaza and Santiago basins, it was 4, 2 and 3 × 10⁶ t year^-1, respectively. For stations in the Andean piedmont of Ecuador, the relationship between surface sediment and the total sediment concentration was found to be close to one. This is due to minimal stratification of the suspended sediment in the vertical profile, which is attributed to turbulence and high vertical water speeds. However, during the dry season, when the water speed decreases, sediment stratification appears, but this effect can be neglected in the sediment flux calculations due to low concentration rates. The suspended sediment load in the Pacific basin was 6 × 10⁶ t year^-1, and the total for the three Amazon basins was 47 × 10⁶ t year^-1. The difference between these contributions of the suspended sediment load is likely due to the tectonic uplift and the seismic and volcanic dynamics that occur on the Amazon side.

Editor Z.W. Kundzewicz

Citation Armijos, E., Laraque, A., Barba, S., Bourrel, L., Ceron, C., Lagane, C., Magat, P., Moquet, J.-S., Pombosa, R., Sondag, F., Vauchel, P., Vera, A., and Guyot, J.L., 2013. Yields of suspended sediment and dissolved solids from the Andean basins of Ecuador. Hydrological Sciences Journal, 58 (7), 1478–1494.     

Web-based analytical tools for the exploration of spatial data

This paper deals with the extension of internet-based geographic information systems with functionality for exploratory spatial data analysis (esda). The specific focus is on methods to identify and visualize outliers in maps for rates or proportions. Three sets of methods are included: extreme value maps, smoothed rate maps and the Moran scatterplot. The implementation is carried out by means of a collection of Java classes to extend the Geotools open source mapping software toolkit. The web based spatial analysis tools are illustrated with applications to the study of homicide rates and cancer rates in U.S. counties.This research was supported in part by a number of grants from the US National Science Foundation: NSF Grant SBR-9410612, BCS-9978058, to the Center for Spatially Integrated Social Science (csiss), and a grant from the National Consortium on Violence Research (ncovr is supported under grant SBR-9513040 from the National Science Foundation). In addition, support was provided by grant RO1 CA 95949-01 from the National Cancer Institute. Special thanks to Dr. Eugene J. Lengerich of the Pennsylvania State Cancer Institute for providing the data on colon cancer diagnoses.     

Soil-gas radon anomalies in three study areas of Central-Northern Calabria (Southern Italy)

Soil-gas radon concentrations and exhalation rates have generally been observed to be anomalously high along active faults in many parts of the world. The soil-gas method is based on the principle that faults and fractures in rocks are highly permeable pathways along which gases can migrate upward from deep crust and mantle to soil cover, retaining their source signatures. The present study summarizes the influence of fault zones on anomalous radon concentrations in soil by integrated geophysical and geo-structural analyses in three study areas of Central-Northern Calabria (Southern Italy). Soil-gas radon surveys have been carried out by means of an alpha scintillation counting system, at 12,509 locations between 2002 and 2004. A geostatistical approach has been used to estimate the spatial distribution of soil radon concentrations. Relations among soil-gas distribution and geo-structural features have been evaluated by ordinary multi-Gaussian kriging. Highest soil radon concentrations (ca. 90 kBq m^?3) have been measured in the Rossanese sector. In the three study areas, no appreciable differences can be noticed among lithotypes, with the highest concentration values (ca. 89 kBq m^?3) measured in alluvial deposit and in clay. Measurements of soil-gas radon reveal anomalies clearly connected to the tectonic structures. Increased signals are linearly distributed along regional WNW–ESE trending shear zones, with main pathways of concentration also recognizable along the E–W fault system in the Rossanese sector, the N–S fault system in the Crati Graben and the Catanzaro Trough, and the NE–SW fault system in the Catanzaro Trough. The distribution of epicentres of historical earthquakes occurred between 1184 and 2001 confirms the recent activity of the same fault systems. Soil-gas radon concentrations generally increase, as expected, with decreasing distance to the faults.     

Self-diffusion of water and its dependence on temperature and ionic strength in highly compacted montmorillonite, illite and kaolinite

The effect of temperature and ionic strength on the diffusion of HTO parallel to the direction of compaction through 5 highly compacted clay minerals (bulk dry density, ρ_b,d = 1.90 ± 0.05 Mg/m³), namely montmorillonite (Na- and Ca-form), illite (Na- and Ca-form), and kaolinite, was studied. The diffusion experiments were carried out at temperatures between 0 °C and 60 °C and at ionic strengths of 0.01 M and 1 M NaCl for the Na-form clays and kaolinite, and of 0.005 M and 0.5 M CaCl₂ for the Ca-form. The ionic strength had an insignificant influence on the values of the effective diffusion coefficient (variation by less than 10%) for the clays under study at this degree of compaction. The effective diffusion coefficients followed the order Na-montmorillonite < Ca-montmorillonite < Ca-illite < Na-illite  kaolinite. It is thought that the differences between Na- and Ca-montmorillonite originate from the larger size particles, and thus the lower tortuosity of the latter; whereas the differences between Na- and Ca-illite are related to the different degree of solvation of the Na and Ca cations. The activation energies were successfully calculated using the Arrhenius law. Swelling clays (Na- and Ca-montmorillonite) had slightly larger activation energy values (20 kJ/mol) compared to bulk water (17 kJ/mol); Ca-illite (16 kJ/mol), Na-illite (13 kJ/mol) and kaolinite (14.4 kJ/mol) lower values than that of bulk water. The low activation energies of the last three clays may be related to weaker H-bonds between water and the clay surfaces compared to those in bulk water.     

Recovery of Bennu’s orientation for the OSIRIS-REx mission: implications for the spin state accuracy and geolocation errors

The goal of the OSIRIS-REx mission is to return a sample of asteroid material from near-Earth asteroid (101955) Bennu. The role of the navigation and flight dynamics team is critical for the spacecraft to execute a precisely planned sampling maneuver over a specifically selected landing site. In particular, the orientation of Bennu needs to be recovered with good accuracy during orbital operations to contribute as small an error as possible to the landing error budget. Although Bennu is well characterized from Earth-based radar observations, its orientation dynamics are not sufficiently known to exclude the presence of a small wobble. To better understand this contingency and evaluate how well the orientation can be recovered in the presence of a large 1\(^{\circ }\) wobble, we conduct a comprehensive simulation with the NASA GSFC GEODYN orbit determination and geodetic parameter estimation software. We describe the dynamic orientation modeling implemented in GEODYN in support of OSIRIS-REx operations and show how both altimetry and imagery data can be used as either undifferenced (landmark, direct altimetry) or differenced (image crossover, altimetry crossover) measurements. We find that these two different types of data contribute differently to the recovery of instrument pointing or planetary orientation. When upweighted, the absolute measurements help reduce the geolocation errors, despite poorer astrometric (inertial) performance. We find that with no wobble present, all the geolocation requirements are met. While the presence of a large wobble is detrimental, the recovery is still reliable thanks to the combined use of altimetry and imagery data.     

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

Microvertebrates from the Rhaetian basal bone bed of Saltford,near Bath,SW England

The famous Rhaetian bone bed (Late Triassic, 205 Ma) is well known because it marks a major switch in depositional environment from terrestrial red beds to fully marine conditions throughout the UK and much of Europe. The bone bed is generally cemented and less than 10 cm thick. However, we report here an unusual case from Saltford, near Bath, S.W. England where the bone bed is unconsolidated and up to nearly 1 m thick. The exposure of the basal beds of the Westbury Formation, Penarth Group includes a bone bed containing a diverse Rhaetian marine microvertebrate fauna dominated by sharks, actinopterygian fishes and reptiles. Despite the unusual sedimentary character of the bone bed, we find similar proportions of taxa as in other basal Rhaetian bone beds (55–59 % Lissodus teeth, 13–16 % Rhomphaiodon teeth, 12–14 % Severnichthys teeth, 6–9% Gyrolepis teeth, 3–4% undetermined sharks’ teeth, 1–3% undetermined bony fish teeth, and < 1% of each of Hybodus, Parascylloides, and Sargodon), the only differences being in the proportions of Rhomphaiodon teeth, which can represent 30–40 % of specimens elsewhere. This suggests that taphonomic bias of varying Rhaetian bone beds may be comparable despite different sedimentary settings, and that the proportions of taxa say something about their original proportions in the ecosystem.     

Populus nigra L. establishment and fluvial landform construction: biogeomorphic dynamics within a channelized river

Populations of the riparian pioneer species Populus nigra L. which establish on alluvial bars within river channels modulate sediment dynamics and fluvial landforms. Dense cohorts of P. nigra have colonized gravel point bars along the channelized River Garonne, France, during the last 20 years and have enhanced the vertical, lateral and longitudinal development of the bars. For this period, the geomorphic characteristics of two wooded point bars on this laterally stable river are closely linked to the spatial distribution and intensity of establishment and resistance of different cohorts of P. nigra. Furthermore, P. nigra colonization dynamics were controlled by engineer effects of this same species. This relationship is illustrated by a significant correlation between key geomorphic and biological variables measured in situ and characterized with a set of four aerial photographs taken between 2000 and 2010. The development of wooded point bars, which are discrete biogeomorphic units, over the studied period, appear to result from a specific biogeomorphic positive feedback of matter aggregation and vegetation establishment related to sediment trapping and stabilization by pioneer engineer plants. We propose a conceptual model of biogeomorphic unit construction for channelized, lateral stable rivers. We consider the resultant biogeomorphic units as functional from an ecological point of view because P. nigra enhances at the cohort scale (i) its own inherent capacity to resist hydrogeomorphic disturbances, and (ii) its resilience capacity as a result of successful colonization, especially downstream of mature poplar stands. Copyright © 2016 John Wiley & Sons, Ltd.     

SN 1994W: an interacting supernova or two interacting shells?

We present a multi-epoch quantitative spectroscopic analysis of the Type IIn supernova (Type IIn SN) 1994W, an event interpreted by Chugai et al. as stemming from the interaction between the ejecta of a SN and a  0.4 M_⊙  circumstellar shell ejected 1.5 yr before core collapse. During the brightening phase, our models suggest that the source of optical radiation is not unique, perhaps associated with an inner optically thick cold dense shell and outer optically thin shocked material. During the fading phase, our models support a single source of radiation, an hydrogen-rich optically thick layer with a near-constant temperature of ∼7000 K that recedes from a radius of  4.3 × 10¹⁵  at a peak to  2.3 × 10¹⁵ cm  40 d later. We reproduce the hybrid narrow-core broad-wing line profile shapes of SN 1994W at all times, invoking an optically thick photosphere exclusively (i.e. without any external optically thick shell). In SN 1994W, slow expansion makes scattering with thermal electrons a key escape mechanism for photons trapped in optically thick line cores, and allows the resulting broad incoherent electron-scattering wings to be seen around narrow-line cores. In SNe with larger expansion velocities, the thermal broadening due to incoherent scattering is masked by the broad profile and the dominant frequency redshift occasioned by bulk motions. Given the absence of broad lines at all times and the very low ⁵⁶Ni yields, we speculate whether SN 1994W could have resulted from an interaction between two ejected shells without core collapse. The high conversion efficiency of kinetic to thermal energy may not require a SN-like energy budget for SN1994W.