A Comparative Study of the Use of Organoclay‐Based Formulations and Organic Amendment to Reduce the Leaching of the Herbicide MCPA in Soil

MCPA (4‐chloro‐2‐methylphenoxyacetic acid) is an acidic herbicide widely used on olive crops in Spain. Due to its anionic form at natural soil pH, there is high risk of leaching and groundwater contamination by the use of this herbicide. The aim of this work was to study the effects of organoclay‐based formulations of MCPA and olive oil waste amendment on MCPA leaching in a sandy loam soil. For this purpose, batch adsorption and column leaching studies were performed. The organoclays used to prepare the clay‐based formulations of MCPA were obtained by treating Wyoming montmorillonite (SWy‐2) and Arizona montmorillonite (SAz‐1) with an amount of hexadecyltrimethylammonium (HDTMA) cation equal to 100% of the CEC of the montmorillonites. The organic residue used in this study was a solid waste from olive oil production (olive oil waste, OOW). The soil was amended with the organic residue at the rate of 10% (w/w). Batch release and column leaching studies indicated that organoclay‐based formulations of MCPA reduced the release rate and the leaching of the herbicide as compared to the use of a conventional formulation containing the herbicide in an immediately available form. The increase in soil organic matter of the soil upon amendment with the organic residue also resulted in greater adsorption and reduced leaching of MCPA in the soil. Accordingly, both the use of organoclay‐based formulations and the amendment of soil with OOW are proposed as efficient strategies to reduce extensive leaching losses associated with the application of MCPA in high‐risk scenarios, such as Mediterranean olive groves.     

Impact of gently dipping discontinuities on basement aquifer recharge: An example from Ploemeur (Brittany,France)

Classically, geological surveys of water resources in hard-rock aquifers are made from aerial photographs or geophysical techniques that basically permit to detect vertical features. On the other hand, aquifers only linked to vertical structures are very limited in space and offer in most cases very poor water resources. In the present case, we do show that an outstanding aquifer in Brittany is linked to a geological context associated with low-angle faults possibly directly connected with vertical feeders. In particular, we show through a high-resolution gravimetric survey that the highly fractured contact between granite and micaschists, which constitutes the main path for groundwater flow, is a gently dipping structure. Combined gravimetric, magnetic and geological data allowed us to establish the overall aquifer geometry by running a three-dimensional forward model. In addition, details about the shape of the contact have been obtained using an iterative scheme based on the method of Oldenburg (1974). The gravimetric model confirms the presence of sub-vertical faults that may constitute important drains for the aquifer recharge. Thus, the geological context associated with exceptional water resources for this crystalline aquifer is characterized by a sub-horizontal to gently dipping contact between granite and micaschists. Only such a geological context can allow sufficient recharge to provide the main water supply for a town of 18,000 inhabitants at an average rate of about a billion of cubic meter per year since 1991. Thus, instead of looking for possible vertical structures like in classical hard-rock hydrogeology, it appears much more efficient to detect sub-horizontal permeable fractures and faults for providing consistent water resources.     

Biochip for astrobiological applications: Investigation of low energy protons effects on antibody performances

Antibody-based micro-arrays instruments are very promising tools for the search for biomarkers in planetary exploration missions. Since such instruments have never been used in this context, it is important to test their resistance to space constraints. In particular, cosmic particles might be deleterious. In the present study, we have investigated the effect of low energy protons (2 MeV) on antibody performances with fluences levels much greater than expected for a typical mission to Mars. We show that these particles do not alter significantly the antibody recognition capability for both free (in solution) and grafted (covalently bound to the support) freeze–dried antibodies. Details of the freeze–dried drying process used to optimize antibody performances during our experiments are also presented.     

MODFLOW procedure to simulate axisymmetric flow in radially heterogeneous and layered aquifer systems

A procedure is outlined to simulate axisymmetric groundwater flow in radially heterogeneous and layered aquifer systems using the unmodified version of MODFLOW. The procedure is straightforward, as it only requires correction of some of the input parameters. In contrast to other MODFLOW procedures to simulate axisymmetric flow, no restrictions are imposed on the type of flow, the discretization of radial distance, or the parameter values. Hence, the method can deal with both confined and unconfined flow, wellbore storage, and axisymmetric aquifer inhomogeneities including effects of finite-thickness skin and gravel pack. Several test cases are presented, which compare the calculated results with existing analytical solutions, the analytic element solver TTim, and the axisymmetric, finite-difference model MAxSym. It is concluded that the MODFLOW procedure is capable of simulating accurately axisymmetric flow in radially heterogeneous multi-aquifer systems.     

Analyses of precipitation,temperature and evapotranspiration in a French Mediterranean region in the context of climate change

This study is focused on the western part of the French Mediterranean area, namely the Pyrénées-Orientales and Aude administrative departments. The water resources (surface and groundwater) in the region are sensitive to climate change. The study addresses the question of whether any trend in the annual and monthly series of temperature, rainfall and potential evapotranspiration (PET) already appears at the scale of this region. Two data sources have been used: (a) direct local measurements using the meteorological network; and (b) spatially interpolated data from the French weather service model SAFRAN for the period 1970–2006. The non-parametric Mann–Kendall test was applied to identify significant trends at the local scale and, because of the natural spatial variability of the Mediterranean climate, regional interpretation was also performed. The trends observed in the 13 catchments of interest are consistent with those observed at a larger scale. An increase in annual mean temperature and annual PET was observed throughout the study area, whereas annual precipitation has not exhibited any trend. The monthly scale has revealed strong seasonal variability in trend. The trend for an increase in monthly PET has been observed mainly in the spring, and has not been seen in the coastal areas. A trend for an increase in monthly temperature has been observed in June and in the spring throughout the entire area. Monthly rainfall has been found to decrease in June and increase in November throughout the area. The significant trends observed in rainfall and temperature seem to be consistent between the different data sources.     

Isotopic constraints on the Si-biogeochemical cycle of the Antarctic Zone in the Kerguelen area (KEOPS)

Estimation of the silicon (Si) mass balance in the ocean from direct measurements (Si uptake-dissolution rates …) is plagued by the strong temporal and spatial variability of the surface ocean as well as methodological artifacts. Tracers with different sensitivities toward physical and biological processes would be of great complementary use. Silicon isotopic composition is a promising proxy to improve constraints on the Si-biogeochemical cycle, since it integrates over longer timescales in comparison with direct measurements and since the isotopic balance allows to resolve the processes involved, i.e. uptake, dissolution, mixing. Si-isotopic signatures of seawater Si(OH)₄ and biogenic silica (bSiO₂) were investigated in late summer 2005 during the KEOPS experiment, focusing on two contrasting biogeochemical areas in the Antarctic Zone: a natural iron-fertilized area above the Kerguelen Plateau (< 500 m water depth) and the High Nutrient Low Chlorophyll area (HNLC) east of the plateau (> 1000 m water depth). For the HNLC area the Si-isotopic constraint identified Upper Circumpolar Deep Water as being the ultimate Si-source. The latter supplies summer mixed layer with 4.0 ± 0.7 mol Si m^? 2 yr^? 1. This supply must be equivalent to the net annual bSiO₂ production and exceeds the seasonal depletion as estimated from a simple mixed layer mass balance (2.5 ± 0.2 mol Si m^? 2 yr^? 1). This discrepancy reveals that some 1.5 ± 0.7 mol Si m^? 2 yr^? 1 must be supplied to the mixed layer during the stratification period. For the fertilized plateau bloom area, a low apparent mixed layer isotopic fractionation value (?³⁰Si) probably reflects (1) a significant impact of bSiO₂ dissolution, enriching the bSiO₂ pool in heavy isotope; and/or (2) a high Si uptake over supply ratio in mixed layer at the beginning of the bloom, following an initial closed system operating mode, which, however, becomes supplied toward the end of the bloom (low Si uptake over supply ratio) with isotopically light Si(OH)₄ from below when the surface Si(OH)₄ pool is significantly depleted. We estimated a net integrated bSiO₂ production of 10.5 ± 1.4 mol Si m^? 2 yr^? 1 in the AASW above the plateau, which includes a significant contribution of bSiO₂ production below the euphotic layer. However, advection which could be significant for this area has not been taken into account in the latter estimation based on a 1D approach of the plateau system. Finally, combining the KEOPS Si-isotopic data with those from previous studies, we refined the average Si-isotopic fractionation factor to ? 1.2 ± 0.2‰ for the Antarctic Circumpolar Current.     

The Temperature and Ionization of T-Tauri Micro-Jets

The effects of phenomenological heating functions on the flow thermodynamics of cold T-Tauri disk winds are examined. Turbulent dissipation (mechanical) heating and a warm disk corona are invoked to heat the wind. The temperature and ionization evolution are solved for along the flow. The results allow the construction of synthetic observations; emission maps, forbidden line ratios, line fluxes and line profiles; and successfully reproduce a number of observed trends. Mechanical heating produces line ratios and fluxes that fit very well with observations. Invoking a warm disk corona successfully reproduces forbidden line profile low velocity components.     

Hydrological flowpaths and nitrate removal rates within a riparian floodplain along a fourth‐order stream in Brittany (France)

Three main reservoirs were identified that contribute to the shallow subsurface flow regime of a valley drained by a fourth‐order stream in Brittany (western France). (i) An upland flow that supplied a wetland area, mainly during the high‐water period. It has high N‐NO₃^? and average Cl^? concentrations. (ii) A deep confined aquifer characterized by low nitrate and low chloride concentrations that supplied the floodplain via flow upwelling. (iii) An unconfined aquifer under the riparian zone with high Cl^? and low N‐NO₃^? concentrations where biological processes removed groundwater nitrate. This aquifer collected the upland flow and supplied a relict channel that controlled drainage from the whole riparian zone. Patterns of N‐NO₃^? and Cl^? concentrations along riparian transects, together with calculated high nitrate removal, indicate that removal occurred mainly at the hillslope–riparian zone interface (i.e. first few metres of wetland), whereas dilution occurred in lower parts of the transects, especially during low‐water periods and at the beginning of recharge periods. Stream flow was modelled as a mixture of water from the three reservoirs. An estimation of these contributions revealed that the deep aquifer contribution to stream flow averaged 37% throughout the study period, while the contribution of the unconfined reservoir below the riparian zone and hillslope flow was more variable (from ca 6 to 85%) relative to rainfall events and the level of the riparian water table. At the entire riparian zone scale, NO₃^? removal (probably from denitrification) appeared most effective in winter, despite higher estimated upland NO₃^? fluxes entering the riparian zone during this period. Copyright © 2003 John Wiley & Sons, Ltd.     

Effect of climate change and increased atmospheric CO2 on hydrological and nitrogen cycling in an intensive agricultural headwater catchment in western France

Climate change and increased atmospheric CO₂ concentration can impact hydrological and nitrogen cycling at the catchment scale. The objective of this study is to assess these impacts in an intensive agricultural headwater catchment in western France. A calibrated and validated agro-hydrological model was driven by output of the climate model ARPEGE under the A1B emission scenario over 30-year simulation periods. Our study indicated that with climate warming and increased atmospheric CO₂, the main trends in water balance were a decrease in annual actual evapotranspiration (AET), a decrease in annual discharge and wetland extent, and a decrease in spring and summer of groundwater recharge and soil-water content. Not considering the effects of increased atmospheric CO₂ in the agro-hydrological model led to overestimating discharge decrease and underestimating AET decrease and wetland extent. Climate change could influence N cycling by increasing soil N mineralisation, increasing soil denitrification in wetlands and upstream areas, and decreasing NO₃–N load to streams. Since wetlands appear to be sensitive to climate change, improving modelling to better predict their responses is an important issue, especially to help plan sustainable management of these vulnerable areas.     

GPS measurements of ground deformation induced by water level variations into a granitic aquifer (French Brittany)

We used two semi‐permanent GPS receivers with differential configuration to measure the hydrological subsidence of an aquifer used for water supply, located on a fractured granitic area. The time series of the vertical deformation measurements of the ground surface show a variation of 2 cm between winter and summer. We investigate the relationship between this vertical deformation and hydraulic head variations. We show that this kind of GPS survey allows characterizing part of the hydrological properties of such a heterogeneous aquifer. This is thus a new approach of time continuous monitoring of the deformation related to hydrogeological processes.