A case study of the internal structures of gossans and weathering processes in the Iberian Pyrite Belt using magnetic fabrics and paleomagnetic dating

In the Rio Tinto district of the Iberian Pryrite Belt of South Spain, the weathering of massive sulfide bodies form iron caps, i.e., true gossans and their subsequent alteration and re-sedimentation has resulted in iron terraces, i.e., displaced gossans. To study the stucture and evolution of both types of gossans, magnetic investigations have been carried out with two foci: (1) the characterisation and spatial distribution of magnetic fabrics in different mineralised settings, including massive sulfides, gossans, and terraces, and (2) paleomagnetic dating. Hematite has been identified as the suceptibility carrier in all sites and magnetic fabric investigation of four gossans reveals a vertical variation from top to bottom, with: (1) a horizontal foliation refered to as “mature” fabric in the uppermost part of the primary gossans, (2) highly inclined or vertical foliation interpreted as “immature” fabric between the uppermost and lowermost parts, and (3) a vertical foliation interpreted to be inherited from Hercynian deformation in the lowermost part of the profiles. In terraces, a horizontal foliation dominates and is interpreted to be a “sedimentary” fabric. Rock magnetic studies of gossan samples have identified goethite as the magnetic remanence carrier for the low-temperature component, showing either a single direction close to the present Earth field (PEF) direction or random directions. Maghemite, hematite, and occasionally magnetite are the remanence carriers for the stable high-temperature component that is characterized by non PEF directions with both normal and reversed magnetic polarities. No reliable conclusion can be yet be drawn on the timing of terrace magnetization due to the small number of samples. In gossans, the polarity is reversed in the upper part and normal in the lower part. This vertical distribution with a negative reversal test suggests remanence formation during two distinct periods. Remanence in the upper parts of the gossans is older than in the lower parts, indicating that the alteration proceeded from top to bottom of the profiles. In the upper part, the older age and the horizontal “mature” fabric is interpreted to be a high maturation stage of massive sulfides’ alteration. In the lower part, the age is younger and the inherited “imature” vertical Hercynian fabric indicates a weak maturation stage. These two distinct periods may reflect changes of paleoclimate, erosion, and/or tectonic motion.     

Measuring Tourist’s Water Footprint in a Mountain Destination of Northwest Yunnan, China

Monitoring and minimizing tourist’s water consumption is essential for the sustainable development of mountain destinations in the world. However, available data and a generally accepted protocol on such measurement are still limited. This study uses water footprint accounting to quantify tourist’s water demand in the Liming valley, a World Heritage site and a rapidly growing tourism destination in Northwest Yunnan, China. Both the water for direct and indirect use is taken into account based on the consump...     

Contribution of climatic and anthropogenic effects to the hydric deficit of peatlands

The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay‐rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two‐year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 1·10^?7 to 3·10^?9 m.s^?1) and does not form a hydraulic barrier. Moreover, the vertical hydraulic gradients are downward between the peat and the sand aquifer, leading to high flows of groundwater through the clay layer (20–48% of the precipitation). The observed hydric deficit of the peatland results from a combination of dry climatic conditions during the study period and groundwater extraction. The climatic effect is mainly expressed through drying out of the peatland, while the anthropogenic effect leads to an enhancement of the climatic effect on a global scale, and a modification of fluxes at a local scale. The drying out of the peatland can lead to its mineralisation, which thus gives rise to environmental impacts. The protection of such wetlands in the context of climate change should take account of anthropogenic pressures by considering the wetland‐aquifer interaction. Copyright © 2011 John Wiley & Sons, Ltd.     

Building Temporal Topology in a GIS Database to Study the Land‐Use Changes in a Rural‐Urban Environment

This article addresses the issue of linking temporal and spatial information into a GIS database structure to investigate the land‐use changes in a rural‐urban region over a thirty‐five‐year period. More specifically, it describes the application of a programming package developed to build temporal topology in an historical land‐use GIS database to efficiently perform spatiotemporal queries. The program was created within the MapInfo environment using MapBasic language. Different types of information, such as the rate of change, the relationship between the change of land use and zoning regulations, and land‐use succession were extracted from the database. A user‐friendly interface was also developed to easily address spatiotemporal queries to the database. This approach represents a flexible and performing tool for scientists and planners who need to efficiently capture essential spatiotemporal information required for geographical inquiry and decision‐making.     

Correction of inertial oscillations by assimilation of HF radar data in a model of the Ligurian Sea

This article aims at analyzing if high-frequency radar observations of surface currents allow to improve model forecasts in the Ligurian Sea, where inertial oscillations are a dominant feature. An ensemble of ROMS models covering the Ligurian Sea, and nested in the Mediterranean Forecasting System, is coupled with two WERA high-frequency radars. A sensitivity study allows to determine optimal parameters for the ensemble filter. By assimilating observations in a single point, the obtained correction shows that the forecast error covariance matrix represents the inertial oscillations, as well as large- and meso-scale processes. Furthermore, it is shown that the velocity observations can correct the phase and amplitude of the inertial oscillations. Observations are shown to have a strong effect during approximately half a day, which confirms the importance of using a high temporal observation frequency. In general, data assimilation of HF radar observations leads to a skill score of about 30% for the forecasts of surface velocity.     

First record of Branchinella spinosa (Milne-Edwards) (Crustacea: Branchiopodacolon; Anostraca) from Greece

As the result of a first screening of temporary inland water habitats,Branchinella spinosa is here recorded for the first time in Greece. This finding extends the circum-Mediterranean part of its vast distribution. The species was collected from a shallow astatic coastal salt-marsh that is mainly fed by rainwater, where it coexists but rarely co-occurs withArtemia parthenogenetica. Branchinella spinosa is only the fourth anostracan species currently known from Greece. The poor knowledge of anostracan richness and abundance is mainly due to limited sampling efforts in this area. As temporary aquatic habitats are threatened by several anthropogenic activities, especially agriculture and land clearing for urbanisation and tourism, there is an urgent necessity for further monitoring and protection of these precious habitats.     

‘Paleoenvironmental study of modern charcoal making activity on forest soils in the Northern Vosges Mountains (Bitche,France): A multidisciplinary study of two remaining charcoal platforms and associated soils sequences’

This multidisciplinary study aims to decipher the impact of ancient charcoal production on past and present-day soils in the northern Vosges Mountains. Soil observations in the field and laboratory were complemented by charcoal and phytolith studies on large thin sections, molecular analyses of organic pollutants, and phytolith analysis on bulk samples. The complex technosol platform records an ancient natural soil sequence buried by a human-made platform on which charcoal accumulated. The current upslope soil is an entic Podzol. Palaeoecological data collected in the buried soil are reliable owing to low bioactivity due to soil acidity. Podzolisation predated the platform construction. The presence of ashes induced low soil alkalisation developed in the charcoal hearth remains and appears to have generated the migration of subsequent iron/clay/organic bands throughout the platform sediment and the buried soil. Charcoal studied in thin sections revealed mainly Quercus and Fagus taxa. Phytolith studies suggest that a less dense or degraded forest preceded platform construction, probably due to former woodland coppicing or earlier disorganised wood gathering. The specific distribution of polycyclic aromatic hydrocarbons sorbed on charcoal has persisted in soils throughout centuries, but we have no evidence that charcoal-making activities contributed to diffuse global pollution.     

Cracking risk of partially saturated porous media—Part I: Microporoelasticity model

Drying of deformable porous media results in their shrinkage, and it may cause cracking provided that shrinkage deformations are hindered by kinematic constraints. This is the motivation to develop a thermodynamics‐based microporoelasticity model for the assessment of cracking risk in partially saturated porous geomaterials. The study refers to 3D representative volume elements of porous media, including a two‐scale double‐porosity material with a pore network comprising (at the mesoscale) 3D mesocracks in the form of oblate spheroids, and (at the microscale) spherical micropores of different sizes. Surface tensions prevailing in all interfaces between solid, liquid, and gaseous matters are taken into account. To establish a thermodynamics‐based crack propagation criterion for a two‐scale double‐porosity material, the potential energy of the solid is derived, accounting—in particular—for mesocrack geometry changes (main original contribution) and for effective micropore pressures, which depend (due to surface tensions) on the pore radius. Differentiating the potential energy with respect to crack density parameter yields the thermodynamical driving force for crack propagation, which is shown to be governed by an effective macrostrain. It is found that drying‐related stresses in partially saturated mesocracks reduce the cracking risk. The drying‐related effective underpressures in spherical micropores, in turn, result in a tensile eigenstress of the matrix in which the mesocracks are embedded. This way, micropores increase the mesocracking risk. Model application to the assessment of cracking risk during drying of argillite is the topic of the companion paper (Part II). Copyright © 2009 John Wiley & Sons, Ltd.     

Structural changes of humic acids from sinking organic matter and surface sediments investigated by advanced solid-state NMR: Insights into sources, preservation and molecularly uncharacterized components

Knowledge of the structural changes that particulate organic matter (POM) undergoes in natural systems is essential for determining its reactivity and fate. In the present study, we used advanced solid-state NMR techniques to investigate the chemical structures of sinking particulate matter collected at different depths as well as humic acids (HAs) extracted from these samples and underlying sediments from the Saguenay Fjord and the St. Lawrence Lower Estuary (Canada). Compared to bulk POM, HAs contain more non-polar alkyls, aromatics, and aromatic C-O, but less carbohydrates (or carbohydrate-like structures). In the two locations studied, the C and N contents of the samples (POM and HAs) decreased with depth and after deposition onto sediments, leaving N-poor but O-enriched HAs and suggesting the involvement of partial oxidation reactions during POM microbial degradation. Advanced NMR techniques revealed that, compared to the water-column HAs, sedimentary HAs contained more protonated aromatics, non-protonated aromatics, aromatic C-O, carbohydrates (excluding anomerics), anomerics, OC_q, O-C_q-O, OCH, and OCH₃ groups, but less non-polar alkyls, NCH, and mobile CH₂ groups. These results are consistent with the relatively high reactivity of lipids and proteins or peptides. In contrast, carbohydrate-like structures were selectively preserved and appeared to be involved in substitution and copolymerization reactions. Some of these trends support the selective degradation (or selective preservation) theory. The results provide insights into mechanisms that likely contribute to the preservation of POM and the formation of molecules that escape characterization by traditional methods. Despite the depletion of non-polar alkyls with depth in HAs, a significant portion of their general structure survived and can be assigned to a model phospholipid. In addition, little changes in the connectivities of different functional groups were observed. Substituted and copolymerized carbohydrates and fused-ring aromatics detected in the present study likely represented an important part of molecularly uncharacterized components (MUC).