Long-chain alkenones and U37′ variability along a south–north transect in the Western Pacific Ocean

In this paper, we present 50 surface water samples collected during the IMAGES III cruise (June–July 1997) along a transect from New Zealand to the China Sea (42°S–178°E, 21°N–120°E) covering a temperature range from 13.3 to 30.4 °C. A very worthwhile aspect of this study is a coupling of both biomarker (alkenone) and coccolithophorid counting. We show that the U₃₇^k′–temperature relationship is very similar to the Prahl et al. [Geochim. Cosmochim. Acta 52 (1988) 2203] culture calibration and to the global core top calibration of Müller et al. [Geochim. Cosmochim. Acta 62 (1998) 1757]. However, in the warmest surface waters of the Western Pacific ocean (>26.4 °C) where Gephyrocapsa oceanica is likely the most widespread species, the associated U₃₇^k′ has a constant value of 1.0. The consequence is that above this temperature threshold, U₃₇^k′ cannot be used as an accurate paleothermometer.     

A case study of the internal structures of gossans and weathering processes in the Iberian Pyrite Belt using magnetic fabrics and paleomagnetic dating

In the Rio Tinto district of the Iberian Pryrite Belt of South Spain, the weathering of massive sulfide bodies form iron caps, i.e., true gossans and their subsequent alteration and re-sedimentation has resulted in iron terraces, i.e., displaced gossans. To study the stucture and evolution of both types of gossans, magnetic investigations have been carried out with two foci: (1) the characterisation and spatial distribution of magnetic fabrics in different mineralised settings, including massive sulfides, gossans, and terraces, and (2) paleomagnetic dating. Hematite has been identified as the suceptibility carrier in all sites and magnetic fabric investigation of four gossans reveals a vertical variation from top to bottom, with: (1) a horizontal foliation refered to as “mature” fabric in the uppermost part of the primary gossans, (2) highly inclined or vertical foliation interpreted as “immature” fabric between the uppermost and lowermost parts, and (3) a vertical foliation interpreted to be inherited from Hercynian deformation in the lowermost part of the profiles. In terraces, a horizontal foliation dominates and is interpreted to be a “sedimentary” fabric. Rock magnetic studies of gossan samples have identified goethite as the magnetic remanence carrier for the low-temperature component, showing either a single direction close to the present Earth field (PEF) direction or random directions. Maghemite, hematite, and occasionally magnetite are the remanence carriers for the stable high-temperature component that is characterized by non PEF directions with both normal and reversed magnetic polarities. No reliable conclusion can be yet be drawn on the timing of terrace magnetization due to the small number of samples. In gossans, the polarity is reversed in the upper part and normal in the lower part. This vertical distribution with a negative reversal test suggests remanence formation during two distinct periods. Remanence in the upper parts of the gossans is older than in the lower parts, indicating that the alteration proceeded from top to bottom of the profiles. In the upper part, the older age and the horizontal “mature” fabric is interpreted to be a high maturation stage of massive sulfides’ alteration. In the lower part, the age is younger and the inherited “imature” vertical Hercynian fabric indicates a weak maturation stage. These two distinct periods may reflect changes of paleoclimate, erosion, and/or tectonic motion.     

Extreme value modelling of daily areal rainfall over Mediterranean catchments in a changing climate

Heavy rainfall events during the fall season are causing extended damages in Mediterranean catchments. A peaks‐over‐threshold model is developed for the extreme daily areal rainfall occurrence and magnitude in fall over six catchments in Southern France. The main driver of the heavy rainfall events observed in this region is the humidity flux (FHUM) from the Mediterranean Sea. Reanalysis data are used to compute the daily FHUM during the period 1958–2008, to be included as a covariate in the model parameters. Results indicate that the introduction of FHUM as a covariate can improve the modelling of extreme areal precipitation. The seasonal average of FHUM can improve the modelling of the seasonal occurrences of heavy rainfall events, whereas daily FHUM values can improve the modelling of the events magnitudes. In addition, an ensemble of simulations produced by five different general circulation models are considered to compute FHUM in future climate with the emission scenario A1B and hence to evaluate the effect of climate change on the heavy rainfall distribution in the selected catchments. This ensemble of climate models allows the evaluation of the uncertainties in climate projections. By comparison to the reference period 1960–1990, all models project an amplification of the mean seasonal FHUM from the Mediterranean Sea for the projection period 2070–2099, on average by +22%. This increase in FHUM leads to an increase in the number of heavy rainfall events, from an average of 2.55 events during the fall season in present climate to 3.57 events projected for the period 2070–2099. However, the projected changes have limited effects on the magnitude of extreme events, with only a 5% increase in the median of the 100‐year quantiles. Copyright © 2011 John Wiley & Sons, Ltd.     

Correction of inertial oscillations by assimilation of HF radar data in a model of the Ligurian Sea

This article aims at analyzing if high-frequency radar observations of surface currents allow to improve model forecasts in the Ligurian Sea, where inertial oscillations are a dominant feature. An ensemble of ROMS models covering the Ligurian Sea, and nested in the Mediterranean Forecasting System, is coupled with two WERA high-frequency radars. A sensitivity study allows to determine optimal parameters for the ensemble filter. By assimilating observations in a single point, the obtained correction shows that the forecast error covariance matrix represents the inertial oscillations, as well as large- and meso-scale processes. Furthermore, it is shown that the velocity observations can correct the phase and amplitude of the inertial oscillations. Observations are shown to have a strong effect during approximately half a day, which confirms the importance of using a high temporal observation frequency. In general, data assimilation of HF radar observations leads to a skill score of about 30% for the forecasts of surface velocity.     

Barium uptake into the shells of the common mussel (Mytilus edulis) and the potential for estuarine paleo-chemistry reconstruction

In this study we test if calcite shells of the common mussel, Mytilus edulis, contain barium in proportion to the water in which they grew. Similar to all bivalves analyzed to date, the [Ba/Ca]_shell profiles are characterized by a relatively flat background [Ba/Ca]_shell, interrupted by sharp [Ba/Ca]_shell peaks. Previous studies have focused on these [Ba/Ca]_shell peaks, but not on the background [Ba/Ca]_shell. We show that in both laboratory and field experiments, there is a direct relationship between the background [Ba/Ca]_shell and [Ba/Ca]_water in M. edulis shells. The laboratory and field data provided background Ba/Ca partition coefficients (D_Ba) of 0.10 ± 0.02 and 0.071 ± 0.001, respectively. This range is slightly higher than the D_Ba previously determined for inorganic calcite, and slightly lower than foraminiferal calcite. These data suggest that M. edulis shells can be used as an indicator of [Ba/Ca]_water, and therefore, fossil or archaeological M. edulis shells could be used to extend knowledge of estuarine dissolved Ba throughputs back in time. Moreover, considering the inverse relationship between [Ba/Ca]_water and salinity, background [Ba/Ca]_shell data could be used as an estuary specific indicator of salinity. The cause of the [Ba/Ca]_shell peaks is more confusing, both the laboratory and field experiments indicate that they cannot be used as a direct proxy of [Ba/Ca]_water or phytoplankton production, but may possibly be caused by barite ingestion.     

An EPR study of native radiation-induced paramagnetic defects in sudoite (di–trioctahedral Al–Mg chlorite) from the alteration halo related to unconformity-type uranium deposits

Natural radiation-induced defects were identified in specimens of sudoite (Al–Mg di-trioctahedral chlorite) related to unconformity-type uranium deposits at the base of the Athabasca Group (Saskatchewan, Canada), using electron paramagnetic resonance (EPR) spectroscopy at X- and Q-band frequencies. X-band spectra indicate the presence of a main native defect, named the A_s-center, whose EPR signal is dominated by an axially distorted spectrum with apparent principal components as follows: g _// = 2,051 and g _⊥ = 2,005, and a secondary defect with apparent component g = 2,025. The study of oriented specimens shows that the main defect has its g _// component perpendicular to the (ab) plane of sudoite. The A_s-center corresponds to an electron hole located on oxygen atoms of the structure and is likely associated with Si, according to the lack of hyperfine structure. The A_s-center in sudoite has EPR parameters similar to the A-center in kaolinite and dickite, and the A_i-center in illite. The saturation behavior of EPR spectra as a function of power demonstrates that native defects of sudoite are different from those known in other clays, such as kaolinite, dickite or smectite, but are similar to those of illite. The isochronal annealing data suggest that the main defect in sudoite is stable to more than 300°C. The corresponding defects characterized in sudoite may have the potential for tracing past radionuclide migration around unconformity-type uranium deposits.     

Building Temporal Topology in a GIS Database to Study the Land‐Use Changes in a Rural‐Urban Environment

This article addresses the issue of linking temporal and spatial information into a GIS database structure to investigate the land‐use changes in a rural‐urban region over a thirty‐five‐year period. More specifically, it describes the application of a programming package developed to build temporal topology in an historical land‐use GIS database to efficiently perform spatiotemporal queries. The program was created within the MapInfo environment using MapBasic language. Different types of information, such as the rate of change, the relationship between the change of land use and zoning regulations, and land‐use succession were extracted from the database. A user‐friendly interface was also developed to easily address spatiotemporal queries to the database. This approach represents a flexible and performing tool for scientists and planners who need to efficiently capture essential spatiotemporal information required for geographical inquiry and decision‐making.     

First record of Branchinella spinosa (Milne-Edwards) (Crustacea: Branchiopodacolon; Anostraca) from Greece

As the result of a first screening of temporary inland water habitats,Branchinella spinosa is here recorded for the first time in Greece. This finding extends the circum-Mediterranean part of its vast distribution. The species was collected from a shallow astatic coastal salt-marsh that is mainly fed by rainwater, where it coexists but rarely co-occurs withArtemia parthenogenetica. Branchinella spinosa is only the fourth anostracan species currently known from Greece. The poor knowledge of anostracan richness and abundance is mainly due to limited sampling efforts in this area. As temporary aquatic habitats are threatened by several anthropogenic activities, especially agriculture and land clearing for urbanisation and tourism, there is an urgent necessity for further monitoring and protection of these precious habitats.     

Deriving TDS values in coarse sediments from long normal and electromagnetic logs

This paper presents an empirical relationship of quantitatively linked electromagnetic (EM) borehole recordings of the total dissolved solids (TDS) in pore water in the Quaternary deposits of the Belgian coastal plain. First, the long normal (LN) logs are linked to EM logs, then the already developed relationships between LN resistivity measurements and the TDS values are rewritten for EM recordings. The main parameter in these equations is the formation factor, which is derived from ground water analyses and LN logs through Archie's law. The EM recording has several advantages compared to the LN logs. The EM analysis allows measuring in PVC-cased wells and is not hindered by the invasion zone around the well. Furthermore, it has a high vertical resolution. LN logs can be measured only once, after drilling a well; EM recordings can be repeated several times in monitoring wells, which allows the gathering of time-dependent data over a complete vertical cross section. Such data could be obtained with LN logs only in wells with screens over the full-depth interval, which causes a hydraulic short circuit. This short circuit can result in a large artificial flow through the well between different levels, resulting in a salinity profile, which is no longer representative for the studied site. Remediation against short circuiting is a reduction of the screened interval, which strongly reduces the gathered information. The application of the derived equations is one of setting up a monitoring network along the Belgian coast to monitor the trend in salinity levels and comparing present salinity levels with older LN recordings to investigate the salinity changes in the last 30 years. Deep wells already present in the Belgiancoastal plain can then be used to monitor both the fresh water head changes and the salt water evolution. The technique has also been used for parameter identification for which real concentration measurements were needed.     

Radar observations of Itokawa in 2004 and improved shape estimation

Abstract— We present June 2004 radar images of asteroid 25143 Itokawa (1998 SF36) that improve upon the longitude‐latitude coverage of images obtained in 2001 by Ostro et al. (2004) and use the 2001–2004 data to refine that paper's constraints on Itokawa's shape. The 2004 images, the first of the asteroid's southern side, look distinctly different from the 2001 images, revealing leading edges that are much more curved and rugged than the nearly convex leading edges seen at northern latitudes in 2001. Itokawa is shaped like a slightly asymmetrical, bent, lumpy ellipsoid with dimensions along the principal axes within 10% of 594 times 320 times 288 m. To illustrate the uncertainty space associated with shape reconstruction from images with suboptimal orientational coverage, we present two alternative three‐dimensional models of the object.