Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

TOGA-COARE IOP期间的海气通量观测结果

在TOGA－COAREIOP期间用涡度相关法对海气热通量进行了船载直接观测．对垂直风速、温度和湿度湍流脉动观测数据的谱分析显示它们在高频区基本满足"－2／3次方律"．对船体简谐震荡影响的讨论从理论上证明该影响在热通量计算中可被忽略．根据以此方法得到的通量求出了中性层结条件下感热和潜热的整体输送系数分别为2．25×10－3和1．26×10－3．对海气边界层特性的分析表明该海域的近海层主要呈中性或弱不稳定层结．海气通量的变化与背景环流形势密切相关,潜热通量主要受海面风场强度的影响,而感热通量变化除了风场的影响外,层结变化也是一个重要因素．用整体输送法计算TOGA－COAREIOP期间以及TOGA期间8个航次的通量结果而得到的Bowen比约为0．1,显示潜热通量是暖池大气的主要热源．     

原油族组分成气的化学动力学模型及其标定

利用等温密封热解实验技术及恒速升温热解实验与PY—GC分析技术的结合,本文分别建立并标定了原油中各族组分,即饱和烃、芳烃、非烃和沥青质成气的化学动力学模型。结果表明,原油中不同族组分成气的过程均可用平行一级反应描述,但不同组分在平均活化能及活化能分布上有明显的差异。各族组分在地史过程中成气的过程可由各自的化学动力学模型来描述。这将使原油成气过程的定量、动态描述成为可能。     

One-dimensional ocean model with three types of vertical velocities: a case study in the South China Sea

In this research, three vertical velocities were included in a one-dimensional (1D) ocean model for a case study of the SouthEast Asian Time-Series Study station in the South China Sea. The vertical velocities consisted three processes, i.e., Ekman pumping (WEK), Eddy pumping (WEP), and the background upwelling (WBK). The quantification of WEK followed the classical Ekman pumping theory. The WEP, whose underlying mechanism was consistent with the baroclinic modes (dominated by the first mode), was quantified by Argo observation and altimetry data. The WBK, related with the background circulation, was estimated from the long-term heat budget balance. The skill assessment indicated that the case with all three processes performed best. The study confirmed the capability of the 1D model with three types of vertical velocities, which can reproduce the general structure and variation of temperature in vertical direction.     

石咀山市地貌与反应谱间的关系

本文在实地调查的基础上,将宁夏石咀山市按地貌单元分为三个区。对每个地貌单元场地土的动力特性进行了试验研究。根据一维地震反应计算模型,计算求得了各个地貌单元的平均反应谱,讨论了不同类型的地貌单元与其对应的反应谱之间的关系,最后给出了相应的设计反应谱。     

相变前的热力学平衡态对铁电液晶排列的影响

本实验选用ZLI-3654型铁电液晶(FLC)以及SE-3140型取向剂制备FLC器件样品,通过改变FLC相变过程中的降温速率以及相变前的热力学平衡态来研究FLC相变前的热力学平衡态对FLC排列的影响,共进行了十组实验.实验后,将FLC器件静态对比度进行比较,得出手性向列相到近晶A相(N^*-SmA)相变前的热力学平衡态对FLC实现均匀排列起着极其重要的作用的结论.实验结果表明:器件的静态对比度可高达620 ∶1, N^*-SmA相变前的热力学平衡态有利于形成高对比     

Recent advances in monsoon studies in China

This review provides a synopsis of the major progress that has been made in monsoon studies in China and to further bridge the gap between the Chinese and international meteorological community. It consists of seven major sections. After the introduction, the second section begins with the global monsoon systems and their seasonal variation, based on some new methods proposed in recent years. Besides, some major intraseasonal features of East Asian monsoon, including the onset of South China Sea summer monsoon are discussed. In the third section, we review the interactions between ENSO and the East Asian monsoon, focusing in particular on the results of Chinese meteorologists that indicate the influence of ENSO on the East Asian summer monsoon(EASM) is obviously different from that on the tropical monsoon. Besides the tropical Pacific,other ocean basins, such as the Indian Ocean and the Atlantic Ocean, are also important to the East Asian monsoon, and this topic is discussed in the fourth section. In the fifth section, we address the role of land surface processes in East Asian monsoon. For example, we describe work that has shown more snow cover in spring on the Tibetan Plateau is followed by a weakened EASM and more summer rainfall in the Yangtze River valleys. The sixth section focuses on the influence of atmospheric circulation in the Southern Hemisphere(SH) on EASM, demonstrating how the signal from the SH is likely to provide new clues for the seasonal forecasting of summer rainfall in China. Finally, in the seventh section, we concentrate on the interdecadal variations of EASM. In particular, we look at a significant interdecadal variation that occurred at the end of the 1970 s, and how our understanding of this feature could affect forecasting ability.     

Perfluoroalkyl and polyfluoroalkyl substances in sediments from South Bohai coastal watersheds,China

This study investigated the concentrations and distribution of Perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sediments of 12 rivers from South Bohai coastal watersheds. The highest concentrations of ΣPFAS (31.920 ng g⁻¹ dw) and PFOA (29.021 ng g⁻¹ dw) were found in sediments from the Xiaoqing River, which was indicative of local point sources in this region. As for other rivers, concentrations of ΣPFAS ranged from 0.218 to 1.583 ng g⁻¹ dw were found in the coastal sediments and from 0.167 to 1.953 ng g⁻¹ dw in the riverine sediments. Predominant PFAS from coastal and riverine areas were PFOA and PFBS, with percentages of 30% and 35%, respectively. Partitioning analysis showed the concentrations of PFNA, PFDA and PFHxS were significantly correlated with organic carbon. The results of a preliminary environmental hazard assessment showed that PFOS posed the highest hazard in the Mi River, while PFOA posed a relative higher hazard in the Xiaoqing River.     

从技术中心主义到人本主义：智慧城市研究进展与展望

随着5G网络、物联网、云计算、大数据分析、地理信息系统等新技术的兴起,探索更具包容性和创新潜力的参与式治理,引导高效的技术研发与运用,实现城市“以地方现实为基础、以社会需求为导向”的智慧化转型,已成为国内外城市地理学的重要与前沿议题。人本主义视角下的智慧城市研究,为地理学者介入这一领域提供了理论工具。不同于技术中心主义将智慧城市视作由数字技术构成的物理空间集合,人本主义强调特定情境下的技术、社会(人文治理)与空间的互动。该视角呼吁对多方行动者参与技术研发、基础设施建设与治理决策的合作互动开展微观研究,以揭示智慧城市的共建过程与地方性驱动机制。论文梳理了国内外人本主义研究的最新进展,认为该视角下的研究仍然沿袭“技术中心”或采用与之对立的“知识中心”立场,而缺少技术—社会互动的视角来理解城市智慧化转型。论文提出未来值得深入探讨的议题,即技术与社会(治理)的共生性、围绕技术研发的社会关系互动复杂性、技术研发与关系互动的语境化分析。探讨以上议题有助于理解智慧城市如何作为一个复杂地域系统,在人与技术的持续互动中发生转型,也可为未来中国相关研究提供理论借鉴。     

上海地面沉降模型研究及存在问题

文章主要对当今国内外地面沉降模型研究进展进行了简要的回顾和总结。针对上海地面沉降现象，就准三维水流－一维耦俣沉降模型中存在的科学问题进行了阐述，并就模型的下一步研究提出了科学的目标。