基于测量机器人的数字化船坞建设方法及应用研究

阐述了基于测量机器人的数字化船坞建设方法,主要分析了数字化船坞建设的关键技术,深入研究了基准控制点选择及基准控制点稳定性观测的方法,并对控制网测量平差及精度进行了评定,最后结合案例给出了建设数字化船坞在建设及应用中的几点意见。     

Synthesis and characterisation of a multifunctional oil-based drilling fluid additive

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.     

长乐-南澳韧性剪切带走滑特征探讨

长乐-南澳韧性剪切带可能是在碰撞造山缝合带基础上发育的,其走滑特性严格受闽台微大陆与闽浙中生代火山弧碰撞过程中碰撞动力学的制约。岩石韧性组构和糜棱岩变形的微构造研究表明,碰撞前期走滑为左行。在早垩世晚期(100-120Ma)的主碰撞期和以伸展作用为主的碰撞后期,该带以右行为主,这种右行走滑一直持续至今。发育韧性剪切带的闽台微大陆(或称平潭-东山带)原始位置可能比现今更靠南,这是属于几百公里的漂移位移而不是剪切位移。     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

对虾养殖围隔生态系细菌的生物量

对5个对虾养殖围隔生态系细菌生物量(以C计,下同)的研究结果表明,浮游细菌总生物量波动在0.09～0．83mg/dm3之间,平均0．37±0．21mg／dm3,占水层颗粒有机碳含量的11．94%;附着细菌生物量在(0．14～3．69)x10－2mg/dm3)之间,平均(0．77±0．58)x10-2mg/dm3,占浮游细菌总生物量的2.08%±1．95%。随着养殖时间的推移,浮游细菌总生物量、附着细菌生物量均有所上升。底泥细菌生物量为(44～132)x(10-6m/m),平均(86±23)x(10-6m/m),占底泥有机碳含量的1．55%。     

中国铁路客运流联结的城市时间可达性

基于中国铁路客户服务中心提供的客运流数据,采集全国地级以上行政单元(未含港澳台数据)间铁路客运运行的最短历时,基于GIS网络分析和空间分析等方法,选取时间可达性和一日交流圈2个指标对城市可达性进行测度和分析。研究发现:①城市时间可达性水平划分为7个级别,在空间上呈现中心-外围式圈层结构,中心区域沿铁路干线和高速铁路线轴向扩展,廊道效应明显,东部、中部地区的城市时间可达性优于西部地区。②城市之间的时间可达性小于2.0 h的城市对在空间上构成了由京广、京沪、京哈、京福、杭深、青太、徐兰、沪汉蓉、沪昆、广昆等高速铁路连接的"五纵五横"带状分布格局。时间可达性小于10.0 h的城市对覆盖了"胡焕庸线"东南部的大部分区域,城市带转为城市网络。③直辖市、省会/首府城市一日交流圈以31个城市为中心,按照时间可达性由小到大呈现轴向扩展,廊道效应明显。基于城市一日交流圈划分了19个城市群和拉萨城市圈,为城市群的划分提供方法借鉴。     

京津冀国家级经开区地位作用评估

从科技引领、产业支撑、经济带动3个维度构建京津冀国家级经开区地位作用的指标评估系统,运用全排列多边形综合图示法,测度2011~2014年京津冀13个国家级经开区的地位作用及演化趋势。研究表明,京津冀各经开区发展不断优化,逐步进入“深度调整、转型升级”的新阶段;各经开区发展各有千秋、各有短板,初步形成“差异化、非均衡化”的发展格局;各经开区发展差距逐渐缩小,初步呈现“全面崛起、协同并进”发展趋势;各经开区发展指数和位序将会不断调整,但总体发展格局不会太大改变。研究发现,京津冀经开区也面临一些突出问题,如资源集约利用不高,产业转型升级缓慢,企业创新动能不足,区域发展差距悬殊。为此,应激活企业创新活力,增强科技引领能力;促进产业集群集约发展,加快经开区转型升级;培育经济增长新动力,发挥区域带动作用。     

一个有大地形影响的初始方程数值予报模式

大地形对大尺度大气运动的动力和热力作用早已为人们所注意。尤其是青藏高原,国内外气象工作者对它的研究工作越来越多。至于对大地形附近的局地天气系统的模拟和予报,则更有必要考虑地形的作用。 目前,国内外大多数模式在解决地形问题时,都采用了σ座标系,因为这样一来,地形面就成为一个座标面,计算很方便。但是,根据一般坐标变换的原理,气压梯度力项变成两大项的余差,在差分计算时,尤其在地形的陡坡附近会出现很大的误差。因此,不得不     

Speciation of gold in hydrosulphide-rich ore-forming fluids: Insights from first-principles molecular dynamics simulations

To shed light on gold speciation in sulfur-containing ore-forming fluids, we perform first principles molecular dynamics (FPMD) simulations to investigate gold-hydrosulphide complexing under representative geological conditions. With this advanced technique, the electronic structures of solutes and solvents are calculated with density functional theory and the thermal motions are sampled with molecular dynamics. The molecular structures, solvated structures and stabilities of possible complexes are characterized in detail and the following insights have been gained. (1) The previously hypothesized species Au(HS)(H₂S)₃ and Au(HS) are found unstable under ore-forming conditions. Au(HS)(H₂S)₃ would dissociate to LAu(HS) (L = H₂S or H₂O) and free H₂S molecules spontaneously. Au(HS) is highly reactive and tends to capture a second ligand to form a double-coordinated complex. (2) In the thin vapor-like phases of low pressures, the stable complexes include Au(HS)(H₂O), Au(HS)(H₂S) and Au(HS)₂⁻ and their relative stability is Au(HS)₂⁻ > Au(HS)(H₂S) > Au(HS)(H₂O). In dense aqueous phases of high pressures, Au(HS)(H₂S) would spontaneously deprotonate to Au(HS)₂⁻ and thus Au(HS)(H₂O) and Au(HS)₂⁻ are the stable forms. All of these complexes can retain to the upper-limit of ore-forming temperatures. (3) The gold ions in the complexes do not favor coordinating more molecules and therefore the solvations happen mainly through H-bonding interactions between the ligands and environmental waters. H-bonds are found in vapor, liquid, and dense supercritical phases, whereas in the thin supercritical phase the hydration is very weak. These results provide quantitative and microscopic basis for understanding the speciation of gold in hydrothermal fluids.