基于SPOT6遥感影像的滩涂湿地入侵种互花米草植株高度的反演研究

本文以SPOT6 高空间分辨率遥感影像为数据源,通过植被覆盖度和地上生物量两个参数进行滩涂湿地入侵种互花米草植株高度的估算研究。结果表明,三沙湾滩涂湿地互花米草植株高度平均值为2.04 m,以1~2 m和2~3 m植株为主要分布高度,分布面积分别为6.83 km2和10.31 km2,占研究区互花米草总面积的33.83%和51.06%,小于1 m和大于3 m的互花米草仅占9.26%和5.84%。估算值与真实值之间的均方根误差为0.204,绝对误差为0.04~0.37 m。该方法是对高空间分辨率光学影像应用研究的重要尝试,其反演方法具有较好的可行性,可较为准确的获取滩涂湿地植株高度信息。     

强潮流作用下桥墩不对称“双肾型”冲刷地貌特征与机理

本文在海图地形资料分析桥轴线附近的海床自然冲刷的基础上,利用多波束测深技术研究大桥主墩附近局部冲刷地形。结果表明,该大桥桥位附近地形冲刷较显著,且大桥主墩位置有持续冲刷的趋势;主墩上、下游群桩最大冲刷深度呈上游最深、中部淤积、下游渐深的不对称形态,最大局部冲刷深度为4 m;桥墩整体冲刷坑形态呈南北“双肾型”;潮流流向与桥墩迎流面存在偏南的入射角,使得各桥墩南侧的最大冲深和冲刷范围均大于北侧。     

Comprehensive analyses of the initiation and landslide-generated wave processes of the 24 June 2015 Hongyanzi landslide at the Three Gorges Reservoir,China

Reservoir landslides pose a great threat to shipping safety, human lives and properties, and the operation of the hydropower station. In this paper, the 24 June 2015 Hongyanzi landslide at the Three Gorges Reservoir is considered as an example to study the initiation mechanism and landslide-generated wave process of a reservoir landslide. The finite difference method and limit equilibrium analysis are used to analyze the deformation and failure characteristics of the Hongyanzi slope. Simulation results show that a large deformation (about 358 mm) happens in the shallow deposits under intermittent rainfall condition, and the slope is in a limit state. At the same time, continuous rapid drawdown of the water level (about ?0.55 m/day during 8–24 June 2015) reduced the support and accelerated the drainage of the water for the bank slope. A coupling effect of intermittent rainfall and rapid drawdown of the water level was the triggering factor of the 24 June Hongyanzi landslide. Landslide-generated wave process was simulated using a fluid–solid coupling method by integrating the general moving object collision model. Simulation results show that the landslide-generated wave is dominated by the impulse wave, which is generated by sliding masses entering the river with high speed. The maximum wave height is about 5.90 m, and the wave would decay gradually as it spreads because of friction and energy dissipation. To prevent reservoir landslides, the speed for the rising or drawdown of the water level should be controlled, and most importantly, rapid drawdown should be avoided.     

Antialgal and antilarval activities of bioactive compounds extracted from the marine dinoflagellate <Emphasis Type="Italic">Amphidinium carterae</Emphasis>

With the global ban on the application of organotin-based marine coatings by the International Maritime Organization, the development of environmentally friendly, low-toxic and nontoxic antifouling compounds for marine industries has become an urgent need. Marine microorganisms have been considered as a potential source of natural antifoulants. In this study, the antifouling potential of marine dinoflagellate Amphidinium carterae, the toxic and red-tide microalgae, was investigated. We performed a series of operations to extract the bioactive substances from Amphidinium carterae and tested their antialgal and antilarval activities. The crude extract of Amphidinium carterae showed significant antialgal activity and the EC₅₀ value against Skeletonema costatum was 55.4 μg mL^?1. After purification, the isolated bioactive substances (the organic extract C) exhibited much higher antialgal and antilarval activities with EC₅₀ of 12.9 μg mL^?1 against Skeletonema costatum and LC₅₀ of 15.1 μg mL^?1 against Amphibalanus amphitrite larvae. Subsequently, IR, Q-TOFMS, and GC-MS were utilized for the structural elucidation of the bioactive compounds, and a series of unsaturated and saturated 16- to 22-carbon fatty acids were detected. The data suggested the bioactive compounds isolated from Amphidinium carterae exhibited a significant inhibiting effect against the diatom Skeletonema costatum and Amphibalanus amphitrite larvae, and could be substitutes for persistent, toxic antifouling compounds.     

Production and Certification of Synthetic Selenium Isotopic Reference Materials

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.     

Degradation of dimethyl sulfoxide through fluidized-bed Fenton process: kinetic analysis

In this study, fluidized-bed Fenton process (FBF) was used to degrade dimethyl sulfoxide (DMSO), one of the most widely used solvents. Oxidation by Fenton’s reagent, Fe⁺² and H₂O₂, is one of the cheapest advanced oxidation processes due to the high availability of the reagents. FBF is a modified approach that reduces the large amount of iron oxide sludge formed in conventional Fenton process. The optimal treatment efficiencies by FBF with 2 h of reaction were 95.22 % of DMSO degradation and 34.38 % of COD removal at the conditions of 5 mM DMSO, 68.97 g/L SiO₂ carrier, pH_initial 3.0, 5 mM Fe²⁺, and 32.5 mM H₂O₂. The kinetic study was also done to investigate the two stages involved in the oxidation. The first stage fitted the zero reaction order with overall initial rate’s apparent rate constant, k ₁, of ?0.099. The second stage fitted the first order of DMSO degradation, with rate constant, k ₂, of ?0.0005.