激发态质子转移分子2-(2'-羟基苯基)苯并噻唑溶液的全光开关效应

研究了激发态质子转移(ESPT)分子2-(2'-羟基苯基)苯并噻唑(HBT)在不同极性溶剂中的光开关行为,探讨了溶剂极性对HBT分子光开光效应的影响.揭示了光开关脉冲信号的形成原因,建立了基于光诱导HBT分子激发态非线性折射效应的皮秒全光开关的理论模型.根据对时间响应函数的理论计算和实验结果分析,确定了光开关脉冲信号下降前沿和上升后沿的形成机理以及影响因素,并提出了增强光开关信号下降前沿的关断深度,提升上升后沿的恢复速度的有效途径和方法.本文工作为制成皮秒量级关断,微秒甚至纳秒量级重新打开的快速全光开关器     

银纳米杆高温熔化断裂弛豫性能的原子级模拟研究

采用分子动力学模拟方法,研究了不同长度银纳米杆在不同温度弛豫过程中的结构演变过程.结果表明:银纳米杆存在一与杆长相关的临界熔断温度,该临界熔断温度随杆长增加而显著降低.当温度大于熔点而小于临界熔断温度时,体系形成一个高度无序的球形团簇,而温度大于临界熔断温度时,体系则熔断成两个球形团簇.并给出了银纳米杆的产生该熔断现象的机理.     

相变前的热力学平衡态对铁电液晶排列的影响

本实验选用ZLI-3654型铁电液晶(FLC)以及SE-3140型取向剂制备FLC器件样品,通过改变FLC相变过程中的降温速率以及相变前的热力学平衡态来研究FLC相变前的热力学平衡态对FLC排列的影响,共进行了十组实验.实验后,将FLC器件静态对比度进行比较,得出手性向列相到近晶A相(N^*-SmA)相变前的热力学平衡态对FLC实现均匀排列起着极其重要的作用的结论.实验结果表明:器件的静态对比度可高达620 ∶1, N^*-SmA相变前的热力学平衡态有利于形成高对比     

退火对B掺杂纳米金刚石薄膜微结构和电化学性能的影响

采用热丝化学气相沉积法制备B掺杂纳米金刚石薄膜,并对薄膜进行真空退火处理,系统研究了不同退火温度对B掺杂纳米金刚石薄膜的微结构和电化学性能的影响.结果表明,当退火温度升高到800 ℃后,薄膜的Raman谱图中由未退火时在1157,1346,1470,1555 cm^-1处的4个峰转变为只有D峰和G峰,说明晶界上的氢大量解吸附量减少;并且D峰和G峰的积分强度比I_D/I_G值变为最小,即sp²相团簇     

折射/谐衍射红外双波段成像光谱仪系统研究

为了获取足够的目标信息,充分利用中波红外和长波红外的光谱信息,建立了谐衍射中、长波红外超光谱成像系统.利用谐衍射元件独特的色散特性,将谐衍射透镜应用于中、长波红外超光谱成像系统中,使系统在中波红外3.7—4.8 μm和长波红外8—12 μm的2个红外大气窗口内获取数百个光谱图像.设计结果表明,中波红外波段,在18对线/mm处光学系统的调制传递函数(MTF)大于0.55;长波红外波段,在13对线/mm处光学系统的MTF大于0.5;光学系统的衍射环绕能,在中波红外波段30 μm半径范围内大于85%,在长波红外     

极性分子型电流变液导电机理研究

极性分子型电流变液是一种新型的电流变材料.其介电颗粒上吸附极性分子,极性分子在颗粒间强局域电场作用下发生取向是产生巨电流变效应的关键.通过对Ca—Ti—O(CTO)体系极性分子型电流变液电流密度的测量发现,其导电行为遵从Poole-Frenkel效应的规律,这是极性分子型电流变液的重要特征之一.而500 ℃处理过的CTO粉体不含极性分子,所配制的电流变液无巨电流变效应,其电流密度随外电场强度近似地呈线性关系,显示出传统电流变液特性.     

Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

Matter-wave interference in an axial triple-well optical dipole trap

This paper proposes a scheme of axial triple-well optical dipole trap by employing a simple optical system composed of a circular cosine grating and a lens. Three optical wells separated averagely by ～37 μm were created when illuminating by a YAG laser with power 1 mW. These wells with average trapping depth ～0.5 μK and volume ～74 μm³ are suitable to trap and manipulate an atomic Bose--Einstein condensation (BEC). Due to a controllable grating implemented by a spatial light modulator, an evolution between a triple-well trap and a single-well one is achievable by adjusting the height of potential barrier between adjacent wells. Based on this novel triple-well potentials, the loading and splitting of BEC, as well as the interference between three freely expanding BECs, are also numerically stimulated within the framework of mean-field treatment. By fitting three cosine functions with three Gaussian envelopes to interference fringe, the information of relative phases among three condensates is extracted.     

Influence of core property on multi-electron process in slow collisions of isocharged sequence ions with neon

Influence of core property on multi-electron process in the collisions of q=6-9 and 11 isocharged sequence ions with Ne is investigated in the keV/u region. The cross-section ratios of double-, triple-, quadruple- and total multi-electron processes to the single electron capture process as well as the partial ratios of different reaction channels to the relevant multi-electron process are measured by using position-sensitive and time-of-flight techniques. The experimental data are compared with the theoretical predictions including the extended classical over-barrier model, the molecular Columbic barrier model and the semi-empirical scaling law. Results show a core effect on multi-electron process of isocharge ions colliding with Neon, which is consistent with the results of Helium we obtained previously.     

Distributions and seasonal variations of dissolved carbohydrates in the Jiaozhou Bay,China

Surface seawater samples were collected in the Jiaozhou Bay, a typical semi-closed basin located at the western part of the Shandong Peninsula, China, during four cruises. Concentrations of monosaccharides (MCHO), polysaccharides (PCHO) and total dissolved carbohydrates (TCHO) were measured with the 2,4,6-tripyridyl-s-triazine spectroscopic method. Concentrations of TCHO varied from 10.8 to 276.1 μM C for all samples and the ratios of TCHO to dissolved organic carbon (DOC) ranged from 1.1 to 67.9% with an average of 10.1%. This result indicated that dissolved carbohydrates were an important constituent of DOC in the surface seawater of the Jiaozhou Bay. In all samples, the concentrations of MCHO ranged from 2.9 to 65.9 μM C, comprising 46.1 ± 16.6% of TCHO on average, while PCHO ranged from 0.3 to 210.2 μM C, comprising 53.9 ± 16.6% of TCHO on average. As a major part of dissolved carbohydrates, the concentrations of PCHO were higher than those of MCHO. MCHO and PCHO accumulated in January and July, with minimum average concentration in April. The seasonal variation in the ratios of TCHO to DOC was related to water temperature, with high values in January and low values in July and October. The concentrations of dissolved carbohydrates displayed a decreasing trend from the coastal to the central areas. Negative correlations between concentrations of TCHO and salinity in July suggested that riverine input around the Jiaozhou Bay had an important effect on the concentrations of dissolved carbohydrates in surface seawater. The pattern of distributions of MCHO and PCHO reported in this study added to the global picture of dissolved carbohydrates distribution.