Temporal variation of228Ra in the near-surface Gulf of Mexico

The Mn-fiber technique for extracting radium from seawater has proved useful for studying the marine geochemistry of²²⁸Ra. In the Gulf of Mexico, this technique was used to measure the surface and near-surface distribution of²²⁶Ra and²²⁸Ra. The observed surface distribution of²²⁸Ra, and particularly the radium activity ratio (228/226) can be explained by known circulation patterns, or, when local surface currents are not well understood, may provide insight into their general characteristics.The radium activity ratio has increased from 0.5 in 1968 to 0.7 in 1973 in the surface Gulf of Mexico. This observed increase cannot be attributed to known anthropogenic or natural source perturbations within the Caribbean Sea-Gulf of Mexico system. Possible causes include a change in the residence time for near-surface water, or variations in the relative dominance of the two sources for water entering the eastern Caribbean; the North Equatorial Current and the Guiana Current.The temporal distribution of²²⁸Ra is unstable and naturally variable over a time period less than or equal to five years in the Gulf of Mexico and by extrapolation, the Caribbean Sea. Therefore, its usefulness in calculations of eddy diffusion coefficients for these regions is greatly diminished.     

A Study of Ozone Laminae Using Diabatic Trajectories, Contour Advection and Photochemical Trajectory Model Simulations.

In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism.     

Dating climatic episodes of the Holocene

Monitoring evidence indicates that the Holocene embraced a sequence of rather discrete climatic episodes. The transitions between these environmental episodes apparently were abrupt and globally synchronous. This paper reports on statistical analyses of radiocarbon dates associated with environmental change and cultural change.Over 800 ¹⁴C dates associated with pollen maxima and minima, sea level maxima and minima, and top and bottom surfaces of peat beds were simultaneously analyzed to identify times of globally synchronous environmental discontinuities.Some 3700 ¹⁴C dates associated with 155 cultural continua of the world were collectively analyzed to identify worldwide synchroneities in appearance and termination of the cultures.Significant globally synchronous discontinuities were identified in each independent analysis. The dates of environmental and cultural discontinuities are rather similar, particularly during the recent half of the Holocene. The fact that the cultural discontinuities mostly follow rather closely those of the paleobotanical record suggests that there has been a distinct climatic impact on the cultural history of man.     

An analysis of Apollo lunar soil samples 12070,889, 12030,187, and 12070,891: Basaltic diversity at the Apollo 12 landing site and implications for classification of small‐sized lunar samples

Lunar mare basalts provide insights into the compositional diversity of the Moon's interior. Basalt fragments from the lunar regolith can potentially sample lava flows from regions of the Moon not previously visited, thus, increasing our understanding of lunar geological evolution. As part of a study of basaltic diversity at the Apollo 12 landing site, detailed petrological and geochemical data are provided here for 13 basaltic chips. In addition to bulk chemistry, we have analyzed the major, minor, and trace element chemistry of mineral phases which highlight differences between basalt groups. Where samples contain olivine, the equilibrium parent melt magnesium number (Mg#; atomic Mg/[Mg + Fe]) can be calculated to estimate parent melt composition. Ilmenite and plagioclase chemistry can also determine differences between basalt groups. We conclude that samples of approximately 1–2 mm in size can be categorized provided that appropriate mineral phases (olivine, plagioclase, and ilmenite) are present. Where samples are fine‐grained (grain size <0.3 mm), a “paired samples t‐test” can provide a statistical comparison between a particular sample and known lunar basalts. Of the fragments analyzed here, three are found to belong to each of the previously identified olivine and ilmenite basalt suites, four to the pigeonite basalt suite, one is an olivine cumulate, and two could not be categorized because of their coarse grain sizes and lack of appropriate mineral phases. Our approach introduces methods that can be used to investigate small sample sizes (i.e., fines) from future sample return missions to investigate lava flow diversity and petrological significance.     

Crustal sulfur is required to form magmatic Ni–Cu sulfide deposits: evidence from chalcophile element signatures of Siberian and Deccan Trap basalts

Process models for ore formation in magmatic Ni–Cu–platinum group element (PGE) sulfide systems require that S saturation is achieved in a mafic–ultramafic magma. Traditional models explain the achievement of S saturation or sulfide saturation either by the addition of crustal S, by the felsification of the magma by crustal contamination, or by mixing between primitive and evolved magmas. Which process matters most is important to industry-oriented exploration models where crustal S sources are believed to be encouraging features of a metallotect. Studies of the Siberian Trap flood basalts at Noril’sk have demonstrated that chalcophile element depletion is linked to assimilation of silica-rich crust, but it is less clear whether this contaminant contained an appreciable amount of S. At Noril’sk, the Ni–Cu–PGE sulfide deposits are associated with subvolcanic intrusions that were emplaced into Permian and Carboniferous sedimentary sequences rich in shales, marlstones, and evaporites. Similar to the Siberian Trap basalts, the Deccan Trap contains a volumetrically important suite of crustally contaminated tholeiitic basalts. We present new PGE data for samples from a stratigraphic sequence of basalts from the southern Deccan province. Two of the formations in this sequence (the Bushe and Poladpur Formations) have geochemical signatures indicative of a wide degree of crustal contamination of a magma type that gave rise to the stratigraphically higher Ambenali Formation (a product of transitional midocean ridge basalt magmatism). There are no known deposits or occurrences of Ni–Cu–PGE sulfides associated with subvolcanic intrusions in the Deccan province. Despite the fact that the Bushe Formation exhibits a stronger crustal contamination signature than the most contaminated Siberian Trap basalt formations, and the Poladpur lavas are also strongly crustally contaminated, the Bushe and Poladpur basalts are undepleted in Ni, Cu, or PGE. This indicates that the contaminated Deccan Trap lavas did not achieve S saturation. This, in turn, places constraints on the potential of the Deccan Trap in southern India to host significant magmatic sulfide deposits. Conversely, this observation also indicates that an S-rich crustal contaminant is required for the genesis of magmatic Ni–Cu–PGE sulfide deposits.     

Observations of photometric profiles of two planetary nebulae

It is noted that the Abel integral of a Gaussian function is a Gaussian function. This special property is used in order to develop an analytic method for studying photometric profile in Planetary Nebulae. Monochromatic observations have been made at the Haute-Provence Observatory using the RCA-CCD (320×512 pixels) mounted at theF/6 Newtonian focus of the 1.2 m telescope. Among the observed nebulae, two of them (NGC 6778 and NGC 7354) are regular enough to test the photometric profile method. The nebular emissivity per volume unit is then obtained for H⁺ and O⁺⁺ ions.     

A search for previously unrecognized metal-poor subdwarfs in the Hipparcos astrometric catalogue

We have identified 317 stars included in the Hipparcos astrometric catalogue that have parallaxes measured to a precision of better than 15 per cent, and the location of which in the ( M _V ,( B − V ) _T ) diagram implies a metallicity comparable to or less than that of the intermediate-abundance globular cluster M5. We have undertaken an extensive literature search to locate Strömgren, Johnson/Cousins and Walraven photometry for over 120 stars. In addition, we present new UBV ( RI )_C photometry of 201 of these candidate halo stars, together with similar data for a further 14 known metal-poor subdwarfs. These observations provide the first extensive data set of R _C I _C photometry of metal-poor, main-sequence stars with well-determined trigonometric parallaxes. Finally, we have obtained intermediate-resolution optical spectroscopy of 175 stars.
47 stars still lack sufficient supplementary observations for population classification; however, we are able to estimate abundances for 270 stars, or over 80 per cent of the sample. The overwhelming majority have near-solar abundance, with their inclusion in the present sample stemming from errors in the colours listed in the Hipparcos catalogue. Only 44 stars show consistent evidence of abundances below [Fe/H]=−1.0 . Nine are additions to the small sample of metal-poor subdwarfs with accurate photometry. We consider briefly the implication of these results for cluster main-sequence fitting.     

Smear fitting: a new image-deconvolution method for interferometric data

A new technique is presented for producing images from interferometric data. The method, 'smear fitting', makes the constraints necessary for interferometric imaging double as a model, with uncertainties, of the sky brightness distribution. It does this by modelling the sky with a set of functions and then convolving each component with its own elliptical Gaussian to account for the uncertainty in its shape and location that arises from noise. This yields much sharper resolution than clean for significantly detected features, without sacrificing any sensitivity. Using appropriate functional forms for the components provides both a scientifically interesting model and imaging constraints that tend to be better than those used by traditional deconvolution methods. This allows it to avoid the most serious problems that limit the imaging quality of those methods. Comparisons of smear fitting to clean and maximum entropy are given, using both real and simulated observations. It is also shown that the famous Rayleigh criterion (resolution = wavelength/baseline) is inappropriate for interferometers as it does not consider the reliability of the measurements.