Sub‐Permil Interlaboratory Consistency for Solution‐Based Boron Isotope Analyses on Marine Carbonates

Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO₂ through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ¹¹B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (a) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ¹¹B; (b) to determine to what degree the chosen analytical approach may affect the resultant δ¹¹B; and (c) to provide well‐constrained consensus δ¹¹B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.     

Taking stock of Climate Change Acts in Europe: living policy processes or symbolic gestures?

Since the UK introduced a Climate Change Act (CCA) in 2008, similar legislation has followed in a number of states, with each having a slightly different take. What unites these examples is that they all represent framework legislation that aims to facilitate climate change mitigation by creating continuous policy processes whereby mechanisms for the reduction of greenhouse gas (GHG) emissions are developed and implemented. This article is concerned with the extent to which they are living policy processes or rather symbolic gestures. We analyse seven European CCAs with regard to GHG emission reduction targets, planning/implementation mechanisms, and feedback/evaluations prescribed by the laws. These three features correspond with three aspects of climate policy integration (CPI): interpretations of CPI as a norm; CPI as a process of governing; CPI as a policy outcome. We show that CCAs address all three aspects of CPI and constitute living policy processes, although to varying extents. However, CCAs are also policy processes in that they are part of a political system, affected by political forces external to the legislation, positively and negatively.

Key policy insights

• CCAs can provide a normative basis for policymaking on climate change at the national level, especially through quantitative emission reduction targets.

• Whilst CCAs can bring some stability and predictability to policymaking on climate change (mainly because legislation is more difficult to amend or remove than policy strategies), they are still vulnerable to political developments.

• Most CCAs lack either short/medium-term (Denmark, Finland, Ireland, Sweden) or long-term (Austria) targets. Given EU Member States’ aim to decarbonise in the next three decades and the Paris Agreement's global goal of pursuing efforts to limit warming to 1.5°C, states need to find ways to guide this process. One approach could be the inclusion of short-term, medium-term and long-term targets in their CCAs.

• Since sanctioning mechanisms are lacking across all the CCAs analysed here, it is not clear what will happen if legally binding targets are not met. Just as it is difficult to imagine speed limits and speed cameras without accompanying penalties, it is hard to imagine how CCAs without sanctions can deliver decarbonization.

     

Catalyzing mitigation ambition under the Paris Agreement: elements for an effective Global Stocktake

The Global Stocktake (GST) takes a central role within the architecture of the Paris Agreement, with many hoping that it will become a catalyst for increased mitigation ambition. This paper outlines four governance functions for an ideal GST: pacemaker, ensurer of accountability, driver of ambition and provider of guidance and signal. The GST can set the pace of progress by stimulating and synchronizing policy processes across governance levels. It can ensure accountability of Parties through transparency and public information sharing. Ambition can be enhanced through benchmarks for action and transformative learning. By reiterating and refining the long term visions, it can echo and amplify the guidance and signal provided by the Paris Agreement. The paper further outlines preconditions for the effective performance of these functions. Process-related conditions include: a public appraisal of inputs; a facilitative format that can develop specific recommendations; high-level endorsement to amplify the message and effectively inform national climate policy agendas; and an appropriate schedule, especially with respect to the transparency framework. Underlying information provided by Parties complemented with other (scientific) sources needs to enable benchmark setting for collective climate action, to allow for transparent assessments of the state of emissions and progress of a low-carbon transformation. The information also needs to be politically relevant and concrete enough to trigger enhancement of ambition. We conclude that meeting these conditions would enable an ideal GST and maximize its catalytic effect.

Key policy insights

• The functional argument developed in this article may inspire a purposeful design of the GST as its modalities and procedures are currently being negotiated.

• The analytical framework provided serves as a benchmark against which to assess the GST's modalities and procedures.

• Gaps and blind spots in the official GST can and should be addressed by processes external to the climate regime in academia and civil society.

     

Genetic stock structure of white steenbras Lithognathus lithognathus (Cuvier, 1829), an overexploited fishery species in South African waters

White steenbras Lithognathus lithognathus (Teleostei: Sparidae) is an overexploited marine fish species endemic to South Africa. Overexploitation in recreational, subsistence and commercial fisheries has resulted in stock collapse and the need for improved management of the species. Adults are thought to undertake large-scale annual spawning migrations, yet studies of their movement indicate low levels of connectivity among coastal regions. To address this, mitochondrial DNA sequencing and genotyping of microsatellite loci in the nuclear genome were conducted to determine the genetic stock structure and level of gene flow in this species. Genetic diversity was high throughout the species’ core distribution, with no evidence of isolation by way of distance or localised spawning. Low, non-significant pairwise fixation indices (F_ST, R_ST and Jost’s D_est) indicated low genetic differentiation and high levels of gene flow. The observed results, and agreement between mitochondrial and microsatellite DNA, confirm that white steenbras exists as a single genetic stock with high levels of gene flow throughout its distribution.     

Defining geo-habitats for groundwater ecosystem assessments: an example from England and Wales (UK)

Groundwater ecosystems comprising micro-organisms and metazoans provide an important contribution to global biodiversity. Their complexity depends on geology, which determines the physical habitat available, and the chemical conditions within it. Despite this, methods of classifying groundwater habitats using geological data are not well established and researchers have called for higher resolution habitat frameworks. A novel habitat typology for England and Wales (UK) is proposed, which distinguishes 11 geological habitats (geo-habitats) on hydrogeological principles and maps their distribution. Hydrogeological and hydrochemical data are used to determine the characteristics of each geo-habitat, and demonstrate their differences. Using these abiotic parameters, a new method to determine abiotic habitat quality is then developed. The geo-habitats had significantly different characteristics, validating the classification system. All geo-habitats were highly heterogeneous, containing both high quality habitat patches that are likely to be suitable for fauna, and areas of low quality that may limit faunal distributions. Karstic and porous habitats generally were higher quality than fractured habitats. Overall, 70% of England and Wales are covered by lower quality fractured habitats, with only 13% covered by higher quality habitats. The main areas of high quality habitats occur in central England as north–south trending belts, possibly facilitating dispersal along this axis. They are separated by low quality geo-habitats that may prevent east-west dispersal of fauna. In south-west England and Wales suitable geo-habitats occur as small isolated patches. Overall, this paper provides a new national-scale typology that is adaptable for studies in other geographic areas.     

Estimation of temporally averaged sediment delivery ratio using aggradational terraces in headwater catchments of the Waipaoa River,North Island,New Zealand

The sediment delivery ratio was estimated for two periods (28 years and eight years) following reforestation of seven tributary catchments (0·33 to 0·49 km²) in the headwaters of the Waipaoa River basin, North Island, New Zealand. In these catchments, gully erosion, which largely resulted from clearance of the natural forest between 1880 and 1920, is the main source of sediment to streams. Reforestation commenced in the early 1960s in an attempt to stabilize hillslopes and reduce sediment supply. Efforts have been partially successful and channels are now degrading, though gully erosion continues to supply sediment at accelerated rates in parts of the catchment. Data from the area indicate that the sediment delivery ratio (SDR) can be estimated as a function of two variables, ψ (the product of catchment area and channel slope) and A _g (the temporally averaged gully area for the period). Sediment input from gullies was determined from a well defined relationship between sediment yield and gully area. Sediment scoured from channels was estimated from dated terrace remnants and the current channel bed. Terrace remnants represent aggradation during major floods. This technique provides estimates of SDR averaged over periods between large magnitude terrace‐forming events and with the present channel bed. The technique averages out short‐term variability in sediment flux. Comparison of gully area and sediment transport between two periods (1960–1988 and 1988–1996) indicates that the annual rate of sediment yield from gullies for the later period has decreased by 77 per cent, sediment scouring in channels has increased by 124 per cent, and sediment delivered from catchments has decreased by 78 per cent. However, average SDR for the tributaries was found to be not significantly different between these periods. This may reflect the small number of catchments examined. It is also due to the fact that the volume of sediment scoured from channels was very small relative to that produced by gullies. According to the equation for SDR determined for the Waipaoa headwaters, SDR increases with increasing catchment area in the case where A _g and channel slope are fixed. This is because the amount of sediment produced from a channel by scouring increases with increasing catchment area. However, this relationship does not hold for the main stem of the study catchments, because sediment delivered from its tributaries still continues to accumulate in the channel. Higher order channels are, in effect, at a different stage in the aggradation/degradation cycle and it will take some time until a main channel reflects the effects of reforestation and its bed adjusts to net degradation. Results demonstrate significant differences among even low order catchments, and such differences will need to be taken into consideration when using SDR to estimate sediment yields. Copyright © 2001 John Wiley & Sons, Ltd.     

The morphology of craters on Mercury: Results from MESSENGER flybys

Topographic data measured from the Mercury Laser Altimeter (MLA) and the Mercury Dual Imaging System (MDIS) aboard the MESSENGER spacecraft were used for investigations of the relationship between depth and diameter for impact craters on Mercury. Results using data from the MESSENGER flybys of the innermost planet indicate that most of the craters measured with MLA are shallower than those previously measured by using Mariner 10 images. MDIS images of these same MLA-measured craters show that they have been modified. The use of shadow measurement techniques, which were found to be accurate relative to the MLA results, indicate that both small bowl-shaped and large complex craters that are fresh possess depth-to-diameter ratios that are in good agreement with those measured from Mariner 10 images. The preliminary data also show that the depths of modified craters are shallower relative to fresh ones, and might provide quantitative estimates of crater in-filling by subsequent volcanic or impact processes. The diameter that defines the transition from simple to complex craters on Mercury based on MESSENGER data is consistent with that reported from Mariner 10 data.     

Biogeochemical and ecological functioning of the low-salinity water lenses in the region of the Rhone River freshwater influence,NW Mediterranean Sea

A quasi-synoptic survey of a eulerian small grid was carried out twice during mid-spring 2002 in the Gulf of Lions, NW Mediterranean Sea. Analysis of hydrological core parameters reveal for the first time, in the region of freshwater influence (ROFI) of the Rhone River, the presence of low-salinity water (LSW) lenses. The present work details the biogeochemical and ecological functioning of the two LSW lenses from a combined analysis of nutrients and organic matter content, taxonomic assemblages of phytoplankton, primary productivity measurements and nitrogen regeneration fluxes. During the first survey, the lens observed is only detached in part from the Rhone River plume and is considered as a juvenile lens. In contrast, the second lens is totally detached from the plume forming a confined 3D structure with a large vertical development and is considered as having a more advanced maturity. A second survey, 4 days later, provided the opportunity to propose a complete sequence of ecological functioning of the LSW lenses, from their formation to a late stage of maturity just before dispersion. Nitrate contents and dissolved organic matter remain in high concentrations during the juvenile stages while the little available phosphate is rapidly exhausted. In such, an unbalanced-nutrient environment picoplankton appear to out-compete bacterioplankton for phosphate and other resources such as ammonium. In turn, the dominance of such prokaryotic assemblages could have involved the rapid development of microzooplankton. The sudden increase in phosphate observed in a more advanced stage of lens maturity is attributed to intense P-regeneration driven by the large abundance of microzooplankton. This top-down control does not seem to enable the prokaryotic assemblages to bloom again but the high concentrations of phosphate and nitrate favour the development of larger phytoplankton. These autotrophic communities rapidly exhaust nutrients and then decline in the confined ecosystem of the LSW lens that subsequently evolves towards oligotrophic conditions. In the observed last stage, small-sized phytoplankton again dominates the microbial assemblages and the trophic regime is mainly based on regenerated production. The long lifetime of the LSW lens compared to that of the Rhone River plume enables a deep transformation of the initial characteristics of the Rhone River freshwaters both in terms of nutrients balance and microbial food webs, especially through trophic cascading effects. Hence, we show that the LSW lenses have the potential to transfer nutrients and organic matter offshore but the nature (inorganic vs. organic) of the dominant compound exported will depend on the maturity of the lens at the time of its dispersion.     

The role of innovation in advancing understanding of hydrological processes

Innovation and understanding hydrological processes are intimately linked. Existing research has demonstrated the role of technological, societal, and political drivers in shaping and delivering new understandings in hydrological processes. In this paper we pose three research questions to explore how innovation can further our understanding of hydrological processes, if working towards the sustainable development goals (SDGs) provides a helpful focus, and whether specific mechanisms can be used to facilitate innovation and research into hydrological processes. First, we examine key aspects of innovation and explore innovation in the context of water security. We then present a series of innovation projects to determine their effectiveness in delivering innovation in managing hydrological processes, but also their contribution to scientific understanding. Our research suggests that product and process innovation were more closely related to increasing scientific understanding of hydrological processes than other forms of innovation. The NE Water Hub demonstrated that the design of the innovation ecosystem was crucial to its success and provides a model to integrate innovation and research more widely to further scientific understanding and deliver behaviour change to address the SDGs.     

EUREC<Superscript>4</Superscript>A: A Field Campaign to Elucidate the Couplings Between Clouds,Convection and Circulation

Trade-wind cumuli constitute the cloud type with the highest frequency of occurrence on Earth, and it has been shown that their sensitivity to changing environmental conditions will critically influence the magnitude and pace of future global warming. Research over the last decade has pointed out the importance of the interplay between clouds, convection and circulation in controling this sensitivity. Numerical models represent this interplay in diverse ways, which translates into different responses of trade-cumuli to climate perturbations. Climate models predict that the area covered by shallow cumuli at cloud base is very sensitive to changes in environmental conditions, while process models suggest the opposite. To understand and resolve this contradiction, we propose to organize a field campaign aimed at quantifying the physical properties of trade-cumuli (e.g., cloud fraction and water content) as a function of the large-scale environment. Beyond a better understanding of clouds-circulation coupling processes, the campaign will provide a reference data set that may be used as a benchmark for advancing the modelling and the satellite remote sensing of clouds and circulation. It will also be an opportunity for complementary investigations such as evaluating model convective parameterizations or studying the role of ocean mesoscale eddies in air–sea interactions and convective organization.