A C25 highly branched isoprenoid (HBI) monoene hydrocarbon, designated IP25, has been proposed previously to originate from diatoms living in Arctic sea ice, while the presence of IP25 in sediments has been suggested to be a proxy for the occurrence of former Arctic sea ice. Here, we show that the 13C isotopic composition of IP25 in sea ice, in sediment trap material collected under sea ice, and in high latitude northern sediments, is distinctive (isotopically ‘heavy’) and distinguishable from that of organic matter of planktonic or terrigenous origin. Mean δ13C values for IP25 were − 22.3 ± 0.4‰ (sea ice), − 19.6 ± 1.1‰ (sediment traps) and − 19.3 ± 2.3‰ (sediments). These measurements, therefore, support further the proposed use of IP25 as an Arctic sea ice proxy. 相似文献
Abstract Models of a convectively driven hydromagnetic dynamo are constructed using a truncated modal expansion. The resulting nonlinear partial differential equations are integrated numerically. The results confirm that rotation is a necessary condition for effective dynamo action, and suggest that equipartition of kinetic and magnetic energies is qualitatively valid, and that toroidal field energies can be much larger than poloidal. 相似文献
This study contributes to identifying and spatializing the different types of nitrate sources by combining hydrogeochemical and isotopic data with principal component analysis (PCA) and t-distributed stochastic neighbor embedding (t-SNE) multicriteria statistical methods. The methodology is applied to the strategic Mons Basin chalk aquifer (Belgium). The results are based on a whole dataset containing 72 water samples with analyses of the hydrogeochemical parameters (temperature, pH, electrical conductivity (EC), redox potential, dissolved O2), alkalinity, total organic carbon (TOC), silica (SiO2), major and minor ions (NO3–, NH4+, Ca2+, dissolved Fe and Mn, K+, Mg2+, Na+, Sr2+, Cl–, F–, SO4–, B) and multiple stable isotope ratios (δ11B, δ15N–NO3–, δ18O–NO3–). Compared to classical PCA, the recently developed t-SNE method, which considers nonlinear relationships between variables and preserves local-scale similarities in a low-dimensional space, showed much better performance in discriminating different groups of samples and related zones in the aquifer. t-SNE results combined with isotope ratios highlighted four zones in the aquifer (grouped as A–D) and the presence of denitrification fronts. Group A presents a manure signature (δ15N–NO3– – mean (μ) +12.78‰, standard deviation (σ) 6.48‰; δ11B – μ 29.96‰, σ 6.91‰). Group B exhibits both manure and inorganic fertilizer signatures (δ15N–NO3– – μ 6.27‰, σ 2.55‰; δ11B – μ 15.86‰, σ 9.69‰). Group C shows a contamination by sewage (δ15N–NO3– – μ 12.67‰, σ 5.60‰; δ11B – μ 9.97‰, σ 7.08‰). Group D presents a mixed signature (δ15N–NO3– – μ 9.25‰, σ 2.94‰; δ11B – μ 20.00‰, σ 6.70‰).
Mathematical Geosciences - Machine-learning-based proxy models are often used to replace many of the flow simulations required in optimizations of subsurface flow processes. Because the optimizer... 相似文献
Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin, China. The insufficient understanding of their sedimentary processes, depositional patterns, and controlling factors restricts efficient exploration and development. Coarse-grained subaqueous fans in the Yong′an area, Dongying Depression, are investigated in this study. These fans include nearshore subaqueous fans, and sublacustrine fans, and their sedimentary processes, depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology. Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence. Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction. While the topography was gentle, sublacustrine fans did not develop. During the late weak tectonic activity stage, late sublacustrine fans developed with multiple stages superimposed. Frequent fault activity and related earthquakes steepened the basin margin, and the boundary fault slopes were 25.9°–34°. During the early–middle deposition stage, hyperpycnal flows triggered by outburst floods developed. During the late deposition stage, with weak tectonic activity, seasonal floods triggered hyperpycnal flows, and hybrid event beds developed distally. 相似文献
33 large-diameter wells embedded in 2-m thick, 63-m deep diaphragm walls were constructed to reduce both the uplift pressures and the groundwater inflow during the excavations. As the actual thickness of the pumped aquifer is unknown, the installed wells are regarded as partial penetration wells. Single-well and multi-well pumping tests were conducted in the deep gravel formation of Taipei Basin to derive the hydraulic parameters and to investigate the drawdown characteristics at both the construction and remote sites. However, the tidal effect on the drawdown of both the pumping well and nearby observation wells was found significant. Additionally, wellbore storage, skin, and leakage need to be taken into account for deriving the hydraulic parameters. Hence, a method to remove these five factors influencing the drawdown curve is developed, which takes advantage from the late-time characteristics of drawdown data and the early-time behavior of drawdown. Some currently available semi-log graphic techniques are therefore proven applicable for parameter determination. Validity of the proposed method is verified by the good agreement between the calculated and the measured drawdown of both the pumping well and observation well. 相似文献