Estimation of PM20 emissions by wind erosion: main sources of uncertainties

The physics of the two processes (saltation and sandblasting) leading to fine mineral dust emissions by wind erosion in arid or semi-arid areas has been detailed and modeled. The combination of these two models has led to a physically explicit Dust Production Model (DPM). In this work, sensitivity tests are performed with the DPM to determine the nature of the main soil parameters that control dust emissions by sandblasting. It is found that the soil roughness length and the dry size distribution of the soil aggregates constituting the loose wind erodible fraction of the topsoil have the greatest influence on the soil potential for mineral dust production. Contrary to what is often assumed, soil texture is not a relevant parameter.In the light of these new findings, results of vertical flux measurements performed over a wide variety of sources in Niger and the US south west (14 soils) have been reanalyzed. Results show (1) that for the tested soils the DPM, and hence sandblasting, explain all dust emissions, and (2) that 13 of the 14 soils that had been selected a priori for their high potential for dust emissions contained a fine soil-aggregate component. This is consistent with the sensitivity tests indicating that the presence of such a component could enhance dust emissions by one order of magnitude. Finally, it can be concluded that most of the apparent scatter in the experimental results was in large part due to an inappropriate choice of soil parameters to interpret them.     

Conventional and modern seismic investigations for rock quality determination at a dam site—a case history1

Refraction seismics and modern tomographic surveys were employed at the Platanovrissi dam site on the Nestos river in northern Greece in an effort to investigate the dynamic elastic properties and rockmass condition of gneiss-schist outcropping in the area under investigation. Six seismic refraction traverses were run on the ground surface, inside the exploratory tunnels and between tunnels and the ground surface. The results provided information about the low-velocity surface layer parameters and the stress relief zones on the walls of all the tunnels in which seismic tomography tests were performed. Ultrasonic tests, conducted both in situ and in the laboratory, enabled the determination of the ratio Vp/Vs and the Poisson's ratio calculation. From the tomography data analysis and the geological interpretation of the results, three main velocity zones, ranging between 3500 and 4000, 3000 and 3500 and less than 3000m/s, were detected in each tunnel. High-velocity zones were found to be compatible with the hard rockmass of gneiss-schist material, while moderate velocities are closely related to jointed and fractured zones. Finally, low-velocity zones were well correlated with weathered gneiss-schist material.     

ASSESSMENT OF A SIMPLE METHOD FOR THE DETERMINATION OF NB AND TA AT THE SUB-μG/G LEVEL IN SILICATE ROCKS BY ICP-MS

We report Nb and Ta data for 15 international silicate rock standards, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) measurement following decomposition with HF-HNOs-HCI.⁹⁵ Moand¹⁸⁵Re were used as internal standards, and calibration lines were constructed with artificial solutions. Typical relative standard deviations are better than 10% above 0.2 μg/g, and detection limits for Nb and Ta are 40 and 0.8 ng/g, respectively. The results are generally in good agreement with published data. Moreover, this study points out the Nb-Ta heterogeneity of some standard reference materials on the 100 mg scale.     

TOMS measurement of the sulfur dioxide emitted during the 1985 Nevado del Ruiz eruptions

The eruptions of Nevado del Ruiz in 1985 were unusually rich in sulfur dioxide. These eruptions were observed with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which can quantitatively map volcanic sulfur dioxide plumes on a global scale. A small eruption, originally believed to be of phreatic origin, took place on September 11, 1985. However, substantial amounts of sulfur dioxide from this eruption were detected with TOMS on the following day. The total mass of SO₂, approximately 9 ± 3 × 10⁴ metric tons, was deposited in two clouds, one in the upper troposphere, the other possibly at 15 km near the stratosphere.The devastating November 13 eruptions were first observed with TOMS at 1150 EST on November 14. Large amounts of sulfur dioxide were found in an arc extending 1100 km from south of Ruiz northeastward to the Gulf of Venezuela and as an isolated cloud centered at 7°N on the Colombia-Venezuela border. On November 15 the plume extended over 2700 km from the Pacific Ocean off the Colombia coast to Barbados, while the isolated mass was located over the Brazil-Guyana border, approximately 1600 km due east of the volcano. Based on wind data from Panama, most of the sulfur dioxide was located at 10–16 km in the troposphere and a small amount was quite likely deposited in the stratosphere at an altitude above 24 km.The total mass of sulfur dioxide in the eruption clouds was approximately 6.6 ± 1.9 × 10⁵ metric tons on November 14. When combined with quiescent sulfur dioxide emissions during this period, the ratio of sulfur dioxide to erupted magma from Ruiz was an order of magnitude greater than in the 1982 eruption of El Chichon or the 1980 eruption of Mount St. Helens.     

Physical processes controlling bacterial distribution and variability in the upper St. Lawrence estuary

The vertical structure of the water column and the spatial distribution and semidiurnal variability of bacteria were investigated at six stations in the upper St. Lawrence estuary. The σ₁ profiles indicate that the upper St. Lawrence is a partially mixed estuary. Stratification results from buoyancy input from the freshwater outflow of the St. Lawrence River, and its variability is controlled by tidal and, to a lesser extent, wind mixing. Calculations show that tidal mixing largely exceeds mixing caused by wind. Free and attached bacteria presented different patterns of spatial distribution and temporal variability. Free bacteria exhibited highest mean concentrations at the freshwater station (3.5–4.4 10⁶ml^?1) and lowest concentrations at the downstream stations (0.3–0.5 10⁶ml^?1); their numbers declined exponentially relative to salinity. Attached bacteria had highest mean concentrations (3.2–5.5 10⁶ml^?1) at salinities between 0.5 and 5 and were virtually absent at downseam stations (<0.05 10⁶ml^?1). The importance of semidiurnal variability was demonstrated Over the idal cycle, variability of attached bacteria was always greater than that of free bacteria. The analysis of causal models between salinity and free and attached bacteria, showed that the two types of bacteria are uncoupled and that both types have a strong relationship with salimity. Physical processes are thus important controlling factors of the distribution and variability of bacteria. Results suggest that large-scale processes, such as freshwater outflow and residual circulation, largely control free bacteria, whereas short-term and more local processes (e.g., sediment resuspension caused by wind) may also be important in the control of attached bacteria.     

Low-temperature, polysulfide reactions of conjugated ene carbonyls: A reaction model for the geologic origin of S-heterocycles

The theoretical basis for a type of reaction of sulfur-acceptor carbon molecules with donor catenated forms of sulfur is presented. The reactions between conjugated ene carbonyls as sulfur-acceptors and polysulfide as a sulfur donor are described. The scope of this reaction is broadened by demonstrating that the room-temperature action of polysulfide on dienones produces thiophenes. Evidence is given for the structure of 2-benzoyl-5-phenylthiophene, resulting from 1,5-diphenyl-2,4-pentadien-1-one, and 2-acetyl-5-phenylthiophene, resulting from 6-phenyl-3,5-hexadien-2-one. Evidence is also presented for the structure of 2,4-dibenzoyl-3,5-diphenylthiolane, the product resulting from the action of polysulfide on the mixture of benzaldehyde and acetophenone. The same thiolane is shown to result as the minor thiolane component when chalcone reacts with polysulfide in 80% water/20% ethanol. The major component is a known rearranged thiolane identified by its physical properties. The reactiol of chalcone and polysulfide in ethanol at 0 or 25°C results in thiolane formation as evidenced by the isolation of 2,4-dibenzoyl-3,5-diphenylthiolane. However, the reaction of the same two compounds in boiling methanol (65°C) results in a competitive hydrogenation of chalcone giving dihydrochalcone in addition to the formation of thiolane. The demonstration of the low-temperature reaction of polysulfide with conjugated ene carbonyls in the present work adds an additional pathway for possible formation of S-heterocycles in the geosphere.     

Results from an aeromagnetic investigation of the nares strait region

An analysis of published and recently collected aeromagnetics in the Naires Strait region shows that short wavelength, moderate amplitude magnitic anomalies are coincident with previously mapped Precambrian Shield rocks under southeast Ellesmere Island. Similar magnetic anomalies are also observed in northwestern Greenland across Nares Strait. On Greenland the characteristic magnetic anomalies persist about 105 km beyond and northeast of the exposed Precambrian outcrops. This suggests that the Greenland Pre-Cambrian Shield structures previously shown as only occuring as far north as Inglefield Land actually extend at least 100 km further north. Correlation of the magnetic anomalies with mapped geological units suggest a 105+−10 km left lateral displacement in the boundary between the Lower Paleozoic and Precambrain terrains across Nares Strait. This, we interpret, is due to the relative motion between Greenland and Ellesmere Island during the evolution of the Labrador Sea and Baffin Bay in the Early to Mid Tertiary.     

On the theory of the well-mixed layer containing a zero-order jump

Within the framework of a mixed layer (ML) containing a zero-order jump, the concept of ML is generalized for the case of horizontal non-homogeneity on the assumption that not only potential temperature, but also the wind does not change with height. It turns out that the components of the vertical turbulent stresses are quadratic functions of height.For such a well-mixed layer (WML), bounded below by uneven terrain with an adjacent surface layer, and above — by a stably stratified quasigeostrophic baroclinic atmosphere, a consistent system of equations with all terms independent of height, is obtained. This can be considered as a meteorological generalization of the known shallow-water equations.As an example of the use of these equations, an analytical solution of the large-scale one-dimensional steady-state problem concerning the development of the WML in a stable stratified barotropic air mass moving over a heated horizontal surface has been found.     

Evaluation of microbiologically induced corrosion in an estuary

A dockside experiment was designed at the mouth of the Pascagoula River in Pascagoula, Mississippi, to evaluate corrosion in welded Cu/Ni piping systems. Localized corrosion was shown to be due to the following sequence of events: (1) metal segregation during welding processes, (2) settlemnt of sulfide-producing bacteria in welds, (3) disruption of surface films by turbulence, and (4) formation of adjacent cathodic and anodic areas.