A sample changer for automated seawater nutrient analysis systems

An automatic sample changer based upon a commercially available 20-port rotary valve has been developed for use in automated seawater nutrient analyses. All parts exposed to seawater are of stainless steel, Teflon®, or Kel-F®. The sampler has proven to be rugged and efficient in both shore and shipboard laboratories.     

POST-FIRE DEVELOPMENT OF CANOPY STRUCTURE IN A MEDITERRANEAN SHRUB,QUERCUS COCCIFERAL.

The canopy structure, including density, the apportionment of biomass in basal stem and branch diameter classes and foliage, and leaf characteristics, was examined for a dense Quercus coccifera garrigue in southern France at 3,9, and 33 years since the last fire. Indications of changing canopy structure were considered in relation to succession, regeneration strategies, water relations, and flammability. Other shrub species and herbs are most abundant at 3 and 33 years following fire, but at 9 years Q. coccifera is especially dominant. At 9 years the density of stems in the middle range of diameter classes is greatest, overall biomass reaches its peak, and leaf area index is highest. The canopy closes quickly, but by 33 years evidence for self-thinning, slowed but continuing basal sprouting, and declining leaf area and biomass is found; senescence may be beginning, but it is not an important factor in the first 33 years of canopy development. The continuity of the below-ground biomass in this and similar vegetation probably plays an important role in determining the optimum tactics for ramets through cyclic successions. Renewed competition in later years in a more open canopy of Q. coccifera, as indicated by the data, probably would be limited by recurrent fire. [Key words: biomass, canopy, density, mediterranean, physiognomy.]     

Controls on Quaternary coastal evolution of the east-northeastern coast of Brazil: roles of sea-level history, trade winds and climate

East-northeastern Brazil has a wave-dominated, micro- to meso-tidal coast, lying entirely within the southern Atlantic trade wind belt. Integration of geologic mapping, radiocarbon dating and vibracoring data shows that the Quaternary coastal evolution of this area was controlled by three major factors: (1) sea-level history; (2) trade winds; and (3) climate change.

Sea-level history. Along the east-northeastern coast of Brazil, relative sea level has fallen approximately 5 m during the last 5000 y. Correlation of this sea-level history with the evolution of beach-ridge, lagoonal and coastal plain deposits shows that: (1) sea-level rise favours the formation of barrier island—lagoonal systems and the construction of intralagoonal deltas; (2) sea-level lowering is not conductive to barrier island formation. Rather, lagoons and bays become emergent and beach-ridge plains rapidly prograde.

Trade winds. Sediment dispersal systems along the coastal zone of east-northeastern Brazil have been highly persistent since Pleistocene time, as deduced from beach-ridge orientation. This persistence results from the fact that sediment dispersal in wave-dominated settings is ultimately controlled by atmospheric circulation which, for the east-northeastern coast of Brazil is associated with the South Atlantic high-pressure cell. The remarkable stability of this cell through time, has allowed the accumulation of extensive beach-ridge plains at the longshore drift sinks located along the coast.

Climate change. Effects of Quaternary climate changes on coastal sedimentation are twofold. Climate changes may affect rainfall patterns, thus exerting an important control on coastal dune development. Along the coast of northeastern Brazil, active coastal dunes are only present in those areas in which at least four consecutive dry months occur during the year. Mapping of these areas has shown that dune development during the Holocene has been episodic, these episodes being probably controlled by variations in rainfall patterns associated with climate changes. Secondly, despite its overall stability, the position of the high-pressure cell has experienced small shifts in position during the Holocene in response to climate changes. Changes in wind direction associated with these shifts have induced modifications in the coastal dispersion system, which are recorded in the strandplains as small truncations in the beach-ridge alignments.

These results have important implications in understanding accumulation of ancient sandstone shoreline sequences.     

Additional Analytical Data for Gabbro, GOG-1

Additional data for gabbro, GOG-1, were determined by instrumental-neutron-activation analysis, atomic-absorption spectrometry, and semi-quantitative spectrographic analysis. F ratios calculated in the analysis of variance for 26 sets of data for elements determined by the three methods were not significant, and hence the elements are distributed homogeneously among the bottles. The agreement between our data and the averages previously published ranges from very good to poor. More analytical data are necessary to establish reliable estimates of the concentrations of elements in GOG-1 and in two other gabbros so that three gabbros may be available to geochemists for use as standards.     

Current state and trends in Canadian Arctic marine ecosystems: II. Heterotrophic food web, pelagic-benthic coupling, and biodiversity

As part of the Canadian contribution to the International Polar Year (IPY), several major international research programs have focused on offshore arctic marine ecosystems. The general goal of these projects was to improve our understanding of how the response of arctic marine ecosystems to climate warming will alter food web structure and ecosystem services provided to Northerners. At least four key findings from these projects relating to arctic heterotrophic food web, pelagic-benthic coupling and biodiversity have emerged: (1) Contrary to a long-standing paradigm of dormant ecosystems during the long arctic winter, major food web components showed relatively high level of winter activity, well before the spring release of ice algae and subsequent phytoplankton bloom. Such phenological plasticity among key secondary producers like zooplankton may thus narrow the risks of extreme mismatch between primary production and secondary production in an increasingly variable arctic environment. (2) Tight pelagic-benthic coupling and consequent recycling of nutrients at the seafloor characterize specific regions of the Canadian Arctic, such as the North Water polynya and Lancaster Sound. The latter constitute hot spots of benthic ecosystem functioning compared to regions where zooplankton-mediated processes weaken the pelagic-benthic coupling. (3) In contrast with another widely shared assumption of lower biodiversity, arctic marine biodiversity is comparable to that reported off Atlantic and Pacific coasts of Canada, albeit threatened by the potential colonization of subarctic species. (4) The rapid decrease of summer sea-ice cover allows increasing numbers of killer whales to use the Canadian High Arctic as a hunting ground. The stronger presence of this species, bound to become a new apex predator of arctic seas, will likely affect populations of endemic arctic marine mammals such as the narwhal, bowhead, and beluga whales.     

Temporal relationship between Holocene human occupation and vegetation change along the northwestern margin of the Central African rainforest

This paper discusses the relationship between patterns of human settlements and environmental change during the Holocene along the northwestern margins of the equatorial rain forest of central Africa. Palaeoenvironmental data from high-resolution sediment cores from lacustrine deposits, plant macro-remains from forest soils, and archaeological data are harnessed to discuss the differential impact of climate and/or humans on the central African rain forest. It is shown that climate change impacted the rain forest well before the widespread expansion of human settlements all over the study area.     

Impacts of hydrous manganese oxide on the retention and lability of dissolved organic matter

Minerals constitute a primary ecosystem control on organic C decomposition in soils, and therefore on greenhouse gas fluxes to the atmosphere. Secondary minerals, in particular, Fe and Al (oxyhydr)oxides—collectively referred to as “oxides” hereafter—are prominent protectors of organic C against microbial decomposition through sorption and complexation reactions. However, the impacts of Mn oxides on organic C retention and lability in soils are poorly understood. Here we show that hydrous Mn oxide (HMO), a poorly crystalline δ-MnO₂, has a greater maximum sorption capacity for dissolved organic matter (DOM) derived from a deciduous forest composite O_i, O_e, and O_a horizon leachate (“O horizon leachate” hereafter) than does goethite under acidic (pH 5) conditions. Nonetheless, goethite has a stronger sorption capacity for DOM at low initial C:(Mn or Fe) molar ratios compared to HMO, probably due to ligand exchange with carboxylate groups as revealed by attenuated total reflectance-Fourier transform infrared spectroscopy. X-ray photoelectron spectroscopy and scanning transmission X-ray microscopy–near-edge X-ray absorption fine structure spectroscopy coupled with Mn mass balance calculations reveal that DOM sorption onto HMO induces partial Mn reductive dissolution and Mn reduction of the residual HMO. X-ray photoelectron spectroscopy further shows increasing Mn(II) concentrations are correlated with increasing oxidized C (C=O) content (r = 0.78, P < 0.0006) on the DOM–HMO complexes. We posit that DOM is the more probable reductant of HMO, as Mn(II)-induced HMO dissolution does not alter the Mn speciation of the residual HMO at pH 5. At a lower C loading (2 × 10² μg C m^?2), DOM desorption—assessed by 0.1 M NaH₂PO₄ extraction—is lower for HMO than for goethite, whereas the extent of desorption is the same at a higher C loading (4 × 10² μg C m^?2). No significant differences are observed in the impacts of HMO and goethite on the biodegradability of the DOM remaining in solution after DOM sorption reaches steady state. Overall, HMO shows a relatively strong capacity to sorb DOM and resist phosphate-induced desorption, but DOM–HMO complexes may be more vulnerable to reductive dissolution than DOM–goethite complexes.