Les Facies de Transgression du Trias sur la Bordure Nord-est du Massif Central Français

Résumé La transgression triasique est suivie d'Est en Ouest sur la bordure du Massif Central français. Les formations sont de plus en plus récentes vers l'Ouest, indépendamment de leur faciès. Les limites du Buntsandstein et du Trias supérieur semblent locales et d'origine tectonique, tandis que la limite du Ladinien supérieur parait plus générale et correspond à la période où le caractère marin de la transgression sur les massifs hercyniens était le plus franc.Le début de la transgression aniso-ladinienne est daté pour l'Anisien par des empreintes de Reptiles et pour les faciès les plus marins du Ladinien par des Foraminifères et des pollens. A cette période, des microfaunes mésogéennes de mer ouverte apparaissent sur les bordures.Dans les faciès de transgression réduits, le Trias est constitué de grès fins silteux à pseudomorphoses de sel gemme et empreintes de Reptiles, étalés par une mer pelliculaire sur une surface plate. Le socle sous-jacent a fourni peu de matériel clastique et les courants sont orientés du Nord au Sud. Les évaporites sont plus concentrées sur la bordure que plus au large, ce qui implique une certaine aridité pendant toute la période de la transgression.Les faciès de bordure les plus avancés sur le socle sont formés d'une dolomie paralique supratidale déposée dans des lagunes évaporitiques. Sur les massifs hercyniens, des fractures et des failles ouvertes ont permis des circulations auxquelles sont liés des remplissages carbonates et des minéralisations.

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Conditions of the triassic transgression are analysed from East to West across the eastern border of the Central Massif. Formations directly overlying the basement get younger and younger westwards, without relation with the environment. Buntsandstein and upper Triassic boundaries appear to be syntectonic local limits. The upper Ladininian boundary seems to be more general and connected with the main period of the marine environment for the transgression on the variscan basement rocks. The anisoladinian transgression beginns during the anisian age as indicated by fooprints, while ladinian age is supported by mesogean foraminifera and palynology during the climax of the transgression, in an open sea environment.Silty fine sandstones with footprints and salt casts constitute the triassic transgression facies on the flattened border of the Central Massif. The underlying basement supplied only a little arenaceous material and the currents are oriented from Nord to South. Evaporites are more concentrated at the boundary of the transgression than towards the basin, what means aridity.Paralic supratidal dolomite constitutes the most external deposits at the transgression limit, in a syntectonic environment. Dolomite infillings and ore deposits are connected with water circulations along faults and fractures.

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Zusammenfassung Die Triastransgressionsschichten werden von Osten nach Westen am Nordrand des französischen Zentralmassivs beschrieben. Die auf dem Grundgebirge auflagernden Basisschichten werden, unabhängig von ihrer Faziesausbildung, nach Westen stets jünger. Die Begrenzungen der Ablagerungen des Buntsandsteins und der oberen Trias werden nur lokal, wahrscheinlich in Abhängigkeit von synsedimentären, tektonischen Strukturen angetroffen. Die Beckenausdehnung am Top des oberen Ladiniums ist dagegen zusammenhängend zu erkennen. Sie entspricht den eindeutigeren marinen Transgressionsverhältnissen auf dem variskischen Sockel.Die einsetzende Transgression des Aniso-Ladiniums wird durch Reptilienfährten als anisisch und die stärker marinen Ablagerungen durch Foraminiferen und Pollen als ladinisch datiert. In diesem Zeitabschnitt dringen offenmarine, mesogäische Mikrofossilien bis zum Beckenrand vor.Die geringmächtigen Transgressionsablagerungen bestehen aus siltigen Feinsanden mit Steinsalzpseudomorphosen und Reptilienfährten. Diese Sande wurden von einem sehr seichten Meer auf dem stark eingeebneten Grundgebirge verteilt. Das Grundgebirge hat nur sehr wenige klastische Abtragungsprodukte geliefert. Die Strömungen waren von Norden nach Süden ausgerichtet. Evaporite treten stärker in den randlichen Gebieten als zum offenen Becken hin auf. Dies zeigt auf eine ausgeprägte Aridität während der gesamten Transgressionszeit hin.Die am weitesten zum Festland hin vorgeschobenen Transgressionssedimente bestehen aus paralischen, subpratidalen Dolomiten, die sich in evaporitischen Lagunen bildeten. Die in den offenen Spalten und Verwerfungen des Grundgebirges zirkulierenden Lösungen führten zu Dolomitausfällungen und zu schichtgebundenen Vererzungen.

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Lead-210 and pollen geochronologies on Lake Superior sediments

Rates of sedimentation in two Lake Superior deposits were determined by both ragweed pollen and ²¹⁰Pb geochronologies. The former yields an average rate over the time since the first appearance of enhanced concentrations of the pollen as a consequence of human settlement. Sedimentation rates derived on these two bases can be brought into accord if the first appearance of ragweed pollen in the sediments was around 1830 and if the sedimentation rates have been uniform over the past century.     

Chemistry of alkali extraction of brown coals—I. Kinetics, characterisation and implications to coalification

Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state ¹³C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils.     

Les deformations plio-quaternaires de l'afrique du Nord

Résumé L'Afrique du Nord franÇaise et notamment sa bordure littorale ont subi d'importantes déformations plio-quaternaires; l'auteur en précise les phases et les caractéristiques tectoniques.Les zones de plissement de cet âge doivent Être séparées des déformations à grand rayon de courbure. Les phénomènes géophysiques (tremblements de terre, isostasie) en relation avec ces déformations sont passés en revue. L'auteur place ces phénomènes à l'échelle de temps et d'espace dans l'évolution d'ensemble de l'Afrique du Nord, et discute le problème de la flexure continentale.     

Modelling weathering processes at the catchment scale: The WITCH numerical model

A numerical model of chemical weathering in soil horizons and underlying bedrock (WITCH) has been coupled to a numerical model of water and carbon cycles in forest ecosystems (ASPECTS) to simulate the concentration of major species within the soil horizons and the stream of the Strengbach granitic watershed, located in the Vosges Mountains (France). For the first time, simulations of solute concentrations in soil layers and in the catchment river have been performed on a seasonal basis. The model is able to reproduce the concentrations of most major species within the soil horizons, as well as catching the first-order seasonal fluctuations of aqueous calcium, magnesium and silica concentrations. However, the WITCH model underestimates concentrations of Mg²⁺ and silica at the spring of the catchment stream, and significantly underestimates Ca²⁺ concentration. The deficit in calculated calcium can be compensated for by dissolution of trace apatite disseminated in the bedrock. However, the resulting increased Ca²⁺ release yields important smectite precipitation in the deepest model layer (in contact with the bedrock) and subsequent removal of large amount of silica and magnesium from solution. In contrast, the model accurately accounts for the concentrations of major species (Ca, Mg and silica) measured in the catchment stream when precipitation of clay minerals is not allowed. The model underestimation of Mg²⁺ and H₄SiO₄ concentrations when precipitation of well crystallized smectites is allowed strongly suggests that precipitation of well crystallized clay minerals is overestimated and that more soluble poorly crystallized and amorphous materials may be forming. In agreement with observations on other watersheds draining granitic rocks, this study indicates that highly soluble trace calcic phases control the aqueous calcium budget in the Strengbach watershed.     

Numerical Calculation of Equivalent Cell Permeability Tensors for General Quadrilateral Control Volumes

A new method for upscaling fine scale permeability fields to general quadrilateral-shaped coarse cells is presented. The procedure, referred to as the conforming scale up method, applies a triangle-based finite element technique, capable of accurately resolving both the coarse cell geometry and the subgrid heterogeneity, to the solution of the local fine scale problem. An appropriate averaging of this solution provides the equivalent permeability tensor for the coarse scale quadrilateral cell. The general level of accuracy of the technique is demonstrated through application to a number of flow problems. The real strength of the conforming scale up method is demonstrated when the method is applied in conjunction with a flow-based gridding technique. In this case, the approach is shown to provide results that are significantly more accurate than those obtained using standard techniques.     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).