Oxygen isotopes in single micrometer-sized quartz grains: tracing the source of Saharan dust over long-distance atmospheric transport

Oxygen isotope compositions were measured by ion microprobe in individual micrometer-sized quartz grains extracted from one aerosol sample collected on the Cape Verde Islands and from four surface samples (three soils and one sediment) representing potential source regions of aerosols in Western and Central Africa (Morocco, Algeria, Niger, and Chad). A large range of δ¹⁸O values, from +6.2‰ to +39.3‰ is present within the aerosol quartz grains. The different size fractions of the quartz grains from the surface samples overlap nearly entirely this range but show significant differences in their δ¹⁸O distributions for the different size fractions of the grains (i.e., different modes, different proportions of grains with low or high δ¹⁸O, ...). These differences in δ¹⁸O distributions can be related to different geological formations (i.e., mantle-derived magmatic rocks, crustal magmatic rocks, or sedimentary rocks) outcropping in each region, thus giving a fingerprint of the source region. Quartz grains with unusually high δ¹⁸O values between +30‰ and +40‰ were attributed to lacustrine cherts formed in evaporitic environments (Chad basin).The existence of distinct δ¹⁸O distributions for the surface samples, which reflect regional geology but indicate some transport of the grains, enables the characterization of mixing processes during dust emission in the atmosphere. Particles are mixed at a regional scale in the dust reservoir, but injection of fine particles into the high troposphere occurs as a discrete and localized event with no mixing during the subsequent long-range transport by the easterlies. The comparison of the δ¹⁸O distribution of the quartz from the aerosol sample with the equivalent size fractions in surface samples shows that the Niger area is the more probable source region for the aerosol although the Moroccan source cannot be excluded. This method gives a valuable tool to trace the source region of dust into the atmosphere or into sediment samples, allowing the reconstruction of air mass circulations.     

土壤中稀土元素地球化学研究进展

综述了土壤中稀土元素含量、稀土赋存形态、稀土生物有效性、稀土在土壤环境中的分布规律、迁移方式及其影响因子。讨论了稀土微肥应用中应注意的问题以及由此带来的环境效应，并探讨了建立具有普遍适用性的稀土生物有效性方法学的途径等。     

Formation, subduction, and exhumation of Penninic oceanic crust in the Eastern Alps: time constraints from Ar/Ar geochronology

New ⁴⁰Ar/³⁹Ar geochronology places time constraints on several stages of the evolution of the Penninic realm in the Eastern Alps. A 186±2 Ma age for seafloor hydrothermal metamorphic biotite from the Reckner Ophiolite Complex of the Pennine–Austroalpine transition suggests that Penninic ocean spreading occurred in the Eastern Alps as early as the Toarcian (late Early Jurassic). A 57±3 Ma amphibole from the Penninic subduction–accretion Rechnitz Complex dates high-pressure metamorphism and records a snapshot in the evolution of the Penninic accretionary wedge. High-pressure amphibole, phengite, and phengite+paragonite mixtures from the Penninic Eclogite Zone of the Tauern Window document exhumation through ≤15 kbar and >500 °C at 42 Ma to 10 kbar and 400 °C at 39 Ma. The Tauern Eclogite Zone pressure–temperature path shows isothermal decompression at mantle depths and rapid cooling in the crust, suggesting rapid exhumation. Assuming exhumation rates slower or equal to high-pressure–ultrahigh-pressure terrains in the Western Alps, Tauern Eclogite Zone peak pressures were reached not long before our high-pressure amphibole age, probably at ≤45 Ma, in accordance with dates from the Western Alps. A late-stage thermal overprint, common to the entire Penninic thrust system, occurred within the Tauern Eclogite Zone rocks at 35 Ma. The high-pressure peak and switch from burial to exhumation of the Tauern Eclogite Zone is likely to date slab breakoff in the Alpine orogen. This is in contrast to the long-lasting and foreland-propagating Franciscan-style subduction–accretion processes that are recorded in the Rechnitz Complex.     

Investigation of the pyrolytic liberation of molecular nitrogen from Palaeozoic sedimentary rocks

Open-system non-isothermal pyrolysis up to 1,200°C in combination with elemental analysis was used to study the thermal liberation of molecular nitrogen (N₂) from sedimentary rocks and kerogen concentrates of Palaeozoic age from the Central European Basin system and an Eocene shale (Liaohe Basin, China) with a high content (36%) of ammonium feldspar (buddingtonite). The N/C_org (atomic) ratios of the kerogen concentrates ranged from 0.005 to 0.014, which represents the range commonly observed for coals. Bulk N/C_org ratios of the Palaeozoic shales extended from 0.035 to 0.108, indicating the presence of significant amounts of inorganic nitrogen. Namurian A and A-B (CnA; CnA-B) samples typically exhibited the earliest onset of N₂ generation with intense, characteristic peaks around 600°C. N₂ liberation from the buddingtonite-rich sample occurred at higher temperatures, with a broad peak around 700°C. Pyrograms of the kerogen concentrates showed no or strongly reduced N₂ generation in the 500–700°C range. On-line isotope-specific analysis of the pyrolytically liberated N₂ on one sample revealed a variability of ∼10‰ in the δ¹⁵N values and a steady increase in δ¹⁵N with temperature during the main phase of N₂ generation.     

Assessment of river habitat in Brandenburg, Germany

A habitat assessment of 1,707 km of rivers in the Federal State of Brandenburg, Germany, was undertaken using the desk-based ‘overview method’. This method includes the analysis of different sources such as topographic and thematic maps, reports, remote sensing data, and interviews with authorities. It compares actual habitat conditions with natural conditions, and assesses the human disturbances using a seven-step scale. Results show, that in Brandenburg more than 50% of surveyed river units are heavily (class 5) to totally disturbed (class 7) and only slightly more than 20% are undisturbed (class 1) to little disturbed (class 2). Main human disturbances are canalization, bank stabilizations, flood control, migration barriers, and agricultural and urban development in the floodplain. All survey data and maps are embedded in a geographical information system (GIS) that not only allows future analysis and use in river restoration management by experts, but also serves as information for the public. The river habitat map of Brandenburg is part of the river habitat map of the entire Germany.     

Rainwater composition over a rural area with special emphasis on the size distribution of insoluble particulate matter

The rainwater composition in the vicinity of Mainz, FRG, has been investigated with special emphasis on insoluble constituents. The number size distribution was determined in the range from 0.1 m up to 100 m radius. For particles with r>0.5 m radius the shape of the size distribution of insoluble particles in rain follows the shape of the average urban and rural aerosol. In this particular size range no major size selective removal processes could be seen. For r<0.5 m the number size distribution tends to flatten compared to the average aerosol. This might be the indication of a size selective removal process (Greenfield Gap).     

Influence of Site and Source Dependent Ground Motion Scenarios on the Seismic Safety of Long-span Bridges in Cologne, Germany

An overlap in frequency between the 1D resonance frequency of sediments and the vibrational frequencies of long-span bridges might lead to a strongly increased structural response of the latter. Interference of surface waves caused by reflections at dipping interfaces may introduce additional unfavourable amplifications. Therefore, the vulnerability of two bridges crossing the Rhine River in Cologne, Germany, was assessed using ground motion scenarios computed for four profiles crossing the Lower Rhine Embayment. Due to their vibrational frequencies being in the vicinity of resonant peaks in the response spectra, the Severinsbridge showed critical loading and the bridge Cologne-Deutz even exhibited grave failure according to the dynamic FE-simulations.     

Semantic enrichment of octree structured point clouds for multi‐story 3D pathfinding

3D indoor navigation in multi‐story buildings and under changing environments is still difficult to perform. 3D models of buildings are commonly not available or outdated. 3D point clouds turned out to be a very practical way to capture 3D interior spaces and provide a notion of an empty space. Therefore, pathfinding in point clouds is rapidly emerging. However, processing of raw point clouds can be very expensive, as these are semantically poor and unstructured data. In this article we present an innovative octree‐based approach for processing of 3D indoor point clouds for the purpose of multi‐story pathfinding. We semantically identify the construction elements, which are of importance for the indoor navigation of humans (i.e., floors, walls, stairs, and obstacles), and use these to delineate the available navigable space. To illustrate the usability of this approach, we applied it to real‐world data sets and computed paths considering user constraints. The structuring of the point cloud into an octree approximation improves the point cloud processing and provides a structure for the empty space of the point cloud. It is also helpful to compute paths sufficiently accurate in their consideration of the spatial complexity. The entire process is automatic and able to deal with a large number of multi‐story indoor environments.