Trace elements in world steam coal and their behaviour in Dutch coal-fired power stations: A review

Trace elements associated with the combustion of coal have received more attention recently, as can be seen from the increasing demands laid down in legislation and permits.Knowledge of the trace element content of coal is essential. Coal used in the Netherlands is imported from all over the world. As a consequence, Dutch power stations are designed to burn a wide range of bituminous coals. The largest share nowadays originates from South Africa, Colombia, and Indonesia, with these three countries accounting for more than 85% of the coal fired in the Netherlands in recent years. The coals, as imported in the Netherlands, have been monitored for their (trace) element content. At present the database contains results of own analyses of about 170 coals, originating from 14 different countries. An important uncertainty was the question of how homogeneous the imported lots are. It appears that the lots as imported from overseas are fairly homogeneous.The behaviour and fate of trace elements in coal-fired power stations has been studied in more than 40 mass balance studies since 1977. More than 50 test series have been completed during co-combustion of biomass and waste materials (up to 40% on mass base) since 1993. It has therefore been possible to establish a relationship between (trace) elements in the fuel and the ash, as well as with emissions into the atmosphere.     

Interpretation of combined infrared,submillimeter, and millimeter thermal flux data obtained during the Rosetta fly-by of Asteroid (21) Lutetia

The European Space Agency’s Rosetta spacecraft is the first Solar System mission to include instrumentation capable of measuring planetary thermal fluxes at both near-IR (VIRTIS) and submillimeter–millimeter (smm–mm, MIRO) wavelengths. Its primary mission is a 1 year reconnaissance of Comet 67P/Churyumov–Gerasimenko beginning in 2014. During a 2010 close fly-by of Asteroid 21 Lutetia, the VIRTIS and MIRO instruments provided complementary data that have been analyzed to produce a consistent model of Lutetia’s surface layer thermal and electrical properties, including a physical model of self-heating. VIRTIS dayside measurements provided highly resolved 1 K accuracy surface temperatures that required a low thermal inertia, I < 30 J/(K m² s^0.5). MIRO smm and mm measurements of polar night thermal fluxes produced constraints on Lutetia’s subsurface thermal properties to depths comparable to the seasonal thermal wave, yielding a model of I < 20 J/(K m² s^0.5) in the upper few centimeters, increasing with depth in a manner very similar to that of Earth’s Moon. Subsequent MIRO-based model predictions of the dayside surface temperatures reveal negative offsets of ～5–30 K from the higher VIRTIS-measurements. By adding surface roughness in the form of 50% fractional coverage of hemispherical mini-craters to the MIRO-based thermal model, sufficient self-heating is produced to largely remove the offsets relative to the VIRTIS measurements and also reproduce the thermal limb brightening features (relative to a smooth surface model) seen by VIRTIS. The Lutetia physical property constraints provided by the VIRTIS and MIRO data sets demonstrate the unique diagnostic capabilities of combined infrared and submillimeter/millimeter thermal flux measurements.     

Analysis of one-dimensional models for exchange flows under strong stratification

Ocean Dynamics - One-dimensional models of exchange flows driven by horizontal density gradients are well known for performing poorly in situations with weak turbulent mixing. The main issue with...     

The unusual and large drawdown response of buried-valley aquifers to pumping

The buried-valley aquifers that are common in the glacial deposits of the northern hemisphere are a typical case of the strip aquifers that occur in many parts of the world. Pumping from a narrow strip aquifer leads to much greater drawdown and much more distant drawdown effects then would occur in a sheet aquifer with a similar transmissivity and storage coefficient. Widely used theories for radial flow to wells, such as the Theis equation, are not appropriate for narrow strip aquifers. Previously published theory for flow to wells in semiconfined strip aquifers is reviewed and a practical format of the type curves for pumping-test analysis is described. The drawdown response of strip aquifers to pumping tests is distinctive, especially for observation wells near the pumped well. A case study is presented, based on extensive pumping test experience for the Estevan Valley Aquifer in southern Saskatchewan, Canada. Evaluation of groundwater resources in such buried-valley aquifers needs to take into account the unusually large drawdowns in response to pumping.     

Reconstruction of MODIS total suspended matter time series maps by DINEOF and validation with autonomous platform data

In situ measurements of total suspended matter (TSM) over the period 2003–2006, collected with two autonomous platforms from the Centre for Environment, Fisheries and Aquatic Sciences (Cefas) measuring the optical backscatter (OBS) in the southern North Sea, are used to assess the accuracy of TSM time series extracted from satellite data. Since there are gaps in the remote sensing (RS) data, due mainly to cloud cover, the Data Interpolating Empirical Orthogonal Functions (DINEOF) is used to fill in the TSM time series and build a continuous daily “recoloured” dataset. The RS datasets consist of TSM maps derived from MODIS imagery using the bio-optical model of Nechad et al. (Rem Sens Environ 114: 854–866, 2010). In this study, the DINEOF time series are compared to the in situ OBS measured in moderately to very turbid waters respectively in West Gabbard and Warp Anchorage, in the southern North Sea. The discrepancies between instantaneous RS, DINEOF-filled RS data and Cefas data are analysed in terms of TSM algorithm uncertainties, space–time variability and DINEOF reconstruction uncertainty.     

Hydrogeological processes in seasonally frozen northern latitudes: understanding, gaps and challenges

The groundwater regime in seasonally frozen regions of the world exhibits distinct behavior. This paper presents an overview of flow and associated heat and solute transport processes in the subsurface, from the soil/vadose zone, through groundwater recharge to groundwater discharge processes in these areas. Theoretical developments, field studies and model development are considered. An illustrative conceptual model of the system is presented. From a groundwater perspective, the dominant effect is the extent of hydraulic isolation between the water above and that below the near-surface frozen zone. The spatial and temporal occurrences of this isolation are seasonally variable and may also be modified under a future changing climate. A good qualitative conceptual understanding of the system has been developed over numerous decades of study. A major gap is the inability to effectively monitor processes in the field, particularly unfrozen water content during freezing conditions. Modeling of field-scale behavior represents a major challenge, even while physically based models continue to improve. It is suggested that progress can be made by combining well-designed field experiments with modeling studies. A major motivation for improving quantification of these processes derives from the need to better predict the impacts of a future changing climate.     

Quantifying sediment storage in a high alpine valley (Turtmanntal,Switzerland)

The determination of sediment storage is a critical parameter in sediment budget analyses. But, in many sediment budget studies the quantification of magnitude and time‐scale of sediment storage is still the weakest part and often relies on crude estimations only, especially in large drainage basins (>100 km²). We present a new approach to storage quantification in a meso‐scale alpine catchment of the Swiss Alps (Turtmann Valley, 110 km²). The quantification of depositional volumes was performed by combining geophysical surveys and geographic information system (GIS) modelling techniques. Mean thickness values of each landform type calculated from these data was used to estimate the sediment volume in the hanging valleys and the trough slopes. Sediment volume of the remaining subsystems was determined by modelling an assumed parabolic bedrock surface using digital elevation model (DEM) data. A total sediment volume of 781·3×10⁶–1005·7×10⁶ m³ is deposited in the Turtmann Valley. Over 60% of this volume is stored in the 13 hanging valleys. Moraine landforms contain over 60% of the deposits in the hanging valleys followed by sediment stored on slopes (20%) and rock glaciers (15%). For the first time, a detailed quantification of different storage types was achieved in a catchment of this size. Sediment volumes have been used to calculate mean denudation rates for the different processes ranging from 0·1 to 2·6 mm/a based on a time span of 10 ka. As the quantification approach includes a number of assumptions and various sources of error the values given represent the order of magnitude of sediment storage that has to be expected in a catchment of this size. Copyright © 2009 John Wiley & Sons, Ltd.     

Foraminiferal depth palaeoecology of Late Pliocene shelf sequences and systems tracts, Wanganui Basin, New Zealand

High-resolution foraminiferal census of benthic taxa was undertaken on 113 closely spaced samples drawn from the Late Pliocene (ca. 2.6−1.7 Ma) cyclothemic marine strata of the Rangitikei Group, eastern Wanganui Basin, New Zealand. These strata comprise a ca. 1 km thick progradational stack of twenty, sixth-order, depositional sequences that accumulated in shelf and shoreline palaeoenvironments. The sequences are correlated with δ¹⁸O Stages 100−58, and each 41 ka glaciallinterglacial stage couplet is represented by an individual sequence comprising transgressive (TST), highstand (HST), and regressive (RST) systems tracts.

Statistical analysis of the census data identifies thirteen foraminiferal associations within the cyclothemic strata, that are grouped into seven depth- and lithology-related biofacies spanning the entire range of marginal marine to outer shelf palaeoenvironments. Foraminiferal palaeobathymetric analysis of the Rangitikei Group sequences reveals cyclical changes in water-depth of ca. 100–200 m amplitude with frequencies corresponding to the 41 ka obliquity orbital rhythm. Water-depth changes of this magnitude are consistent with a glacio-eustatic origin for the cyclothems, which correspond to an interval of Earth's history when successive continental glaciations of the Northern Hemisphere are known to have occurred. Furthermore the derived water-depth changes are also consistent with lithofacies and sequence stratigraphic inferences regarding palaeodepth of the sequences.

Individual sequences display a clear deepening-upward trend from shoreline to mid-shelf water-depths within TSTs. The level of resolution provided by the microfaunal analysis was insufficient to resolve the precise position of the maximum flooding surface (MFS) and its relationship to the downlap surface (DLS). However, the turn around from rising to falling relative sea level (maximum water-depth) corresponds to a < 5 m interval of section spanning the top of TSTs and lower portions of HST's. A progressive shoaling trend to shoreline and marginal marine environments is indicated for the overlying RSTs.

The amplitudes of water-depth changes for asymmetrical sequences, Rangitikei_nt motif (nondepositional transgression) (100–200 m), are somewhat greater than glacio-eustatic sea-level changes derived from the deep-sea δ¹⁸O record (50–100 m). This implies a significant subsidence contribution to relative sea-level changes. Notwithstanding the effect of subsidence and sedimentation on relative sea level, fluctuations in glacio-eustatic sea level are regarded as the primary factor controlling relative sea-level changes recorded in the Late Pliocene Wanganui Basin succession. Foraminifer-derived palaeobathymetric cycles within sequences display the same frequency, relative magnitude and symmetry as their correlative cycles on the δ¹⁸O sea-level curve.     

The abundance ratio C/O in the atmospheres of 343 carbon stars

The abundance ratio C/O in the atmospheres of 343 carbon stars in the Orion galactic arm is detected. Method of data reduction and errors of results are discussed.     

FACILITATING REGIONAL SUSTAINABLE DEVELOPMENT THROUGH INTEGRATED MULTI-OBJECTIVE UTILIZATION, MANAGEMENT OF WATER RESOURCES IN THE LANCANG-MEKONG RIVER BASIN

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