The tectonic regime along the Andes: Present‐day and Mesozoic regimes

The analyses of the main parameters controlling the present Chile‐type and Marianas‐type tectonic settings developed along the eastern Pacific region show four different tectonic regimes: (1) a nearly neutral regime in the Oregon subduction zone; (2) major extensional regimes as the Nicaragua subduction zone developed in continental crust; (3) a Marianas setting in the Sandwich subduction zone with ocean floored back‐arc basin with a unique west‐dipping subduction zone and (4) the classic and dominant Chile‐type under compression. The magmatic, structural and sedimentary behaviours of these four settings are discussed to understand the past tectonic regimes in the Mesozoic Andes based on their present geological and tectonic characteristics. The evaluation of the different parameters that governed the past and present tectonic regimes indicates that absolute motion of the upper plate relative to the hotspot frame and the consequent trench roll‐back velocity are the first order parameters that control the deformation. Locally, the influences of the trench fill, linked to the dominant climate in the forearc, and the age of the subducted oceanic crust, have secondary roles. Ridge collisions of seismic and seismic oceanic ridges as well as fracture zone collisions have also a local outcome, and may produce an increase in coupling that reinforces compressional deformation. Local strain variations in the past and present Andes are not related with changes in the relative convergence rate, which is less important than the absolute motion relative to the Pacific hotspot frame, or changes in the thermal state of the upper plate. Changes in the slab dip, mainly those linked to steepening subduction zones, produce significant variations in the thermal state, that are important to generate extreme deformation in the foreland. Copyright © 2009 John Wiley & Sons, Ltd.     

Quantification and modeling of foot trail surface erosion in a dry sub‐tropical setting

Anthropogenic disturbance often increases surface erosion and this may have potential detrimental effects on downstream aquatic resources. Foot trails are often overlooked as they represent only a small fragment of the landscape, yet they can be important sources of sediment, particularly in pristine areas. The trail network above East End Bay on the island of St Croix in the US Virgin Islands is the sole anthropogenic source of terrestrial sediment in the area. Concern over the potential for trail erosion to stress nearshore coral reefs of the East End Marine Park led to trail reconstruction and restoration efforts. The objectives of this study were to: (1) quantify trail erosion rates; (2) identify key factors controlling erosion rates; (3) develop an empirical trail erosion model. Sediment production was measured from 12 trail segments with sediment traps from November 2009 to October 2011. Annual trail erosion rates ranged from 0.6 to 81 Mg ha^?1 yr^?1. The lower values were from abandoned trails with a dense vegetation cover, while the highest rates were associated with devegetated trails immediately following construction or restoration. Trail erosion was a function of rainfall, slope, and vegetation cover density raised to the negative 1.7th power. Annual trail erosion rates were one‐ to three‐orders of magnitude higher than measured surface erosion rates on undisturbed hillslopes. The absence of rills or gullies suggests that traditional parametric or repeated transect monitoring commonly used to assess trail erosion may greatly underestimate actual sediment production rates. The new empirical trail erosion model serves as a tool to assess the effects of trail construction and restoration activities in the generation of sediment from small catchments in East End Bay and in other similar settings. Copyright © 2014 John Wiley & Sons, Ltd.     

Enhancement of the benthic communities around an isolated island in the Antarctic Ocean

Insular marine biotas are often richer in faunal diversity than those from the open sea in the same geographical region. The existence of particular island effects were tested under polar conditions by comparing infaunal benthic assemblages on Peter I Island with those of similar latitudes in the open ocean at the Bellingshausen Sea and also from the coast of the Antarctic Peninsula. Sampling was carried out aboard the R/V Hespérides during the expedition named BENTART-2003 from 24 January to 3 March 2003. Benthic samples were collected at 18 stations ranging from 90 to 2 044 m depth, using an USNEL-type box corer (BC) dredge. Representatives of 32 higher taxa of invertebrates were found. Univariate and multivariate analyses revealed various patterns in the data. First, significant differences in polychaete abundance were detected between the stations located in the open sea and the remaining sites (island plus mainland sites). Bivalve abundances were also distinct between island and mainland sampling sites. Sediment columns taken from the island seafloor exhibited the highest rate of bioturbation by the infauna. These findings confirm the model that islands develop distinct assemblages characterized by the enhancement of the benthic communities even in cold waters. Several abiotic factors were measured simultaneously at the seafloor and along the water column to investigate faunal distribution patterns. Significant correlations were found between the benthic assemblages and a combination of two environmental variables: "island effect" (measured as a categorical variable) and the redox state of sediments. Richer and more complex benthic assemblages were found in Peter I Island’s sea bottom, whereas the more depauperate bottoms remained in the open sea.     

Fluid circulation and structural discontinuities inside Misti volcano (Peru) inferred from self-potential measurements

One of the seven potentially active andesite stratovolcanoes in southern Peru, Misti (5822 m), located 17 km northeast and 3.5 km above Arequipa, represents a major threat to the population (900,000 inhabitants). Our recent geophysical and geochemical research comprises an extensive self-potential (SP) data set, an audio–magnetotelluric (AMT) profile across the volcano and CO₂ concentrations in the soil along a radial profile. The SP survey is the first of its kind in providing a complete mapping of a large andesitic stratovolcano 20 km in diameter. The SP mapping enables us to analyze the SP signature associated with a subduction-related active volcano.The general SP pattern of Misti is similar to that of most volcanoes with a hydrogeologic zone in the lower flanks and a hydrothermal zone in the upper central area. A quasi-systematic relationship exists between SP and elevation. Zones with constant SP/altitude gradients (Ce) are observed in both hydrogeologic (negative Ce) and hydrothermal (positive Ce) zones. Transition zones between the different Ce zones, which form a concentric pattern around the summit, have been interpreted in terms of lateral heterogeneities in the lithology. The highest amplitudes of SP anomalies seem to coincide with highly resistive zones. The hydrothermal system 6 km in diameter, which extends over an area much larger than the summit caldera, may be constrained by an older, concealed collapse caldera. A sealed zone has apparently developed through alteration in the hydrothermal system, blocking the migration of CO₂ upward. Significant CO₂ emanations are thus observed on the lower flanks but are absent above the hydrothermal zone.     

Rill length and plot‐scale effects on the hydrogeomorphologic response of gravelly roadbeds

Although unpaved roads are well‐recognized as important sources of Hortonian overland flow and sediment in forested areas, their role in agriculturally‐active rural settings still lacks adequate documentation. In this study, we assessed the effect of micro‐catchment size, slope, and ground cover on runoff and sediment generation from graveled roadbeds servicing a rural area in southern Brazil. Fifteen replications based on 30‐min‐long simulated rainfall experiments were performed at constant rainfall intensities of 22–58 mm h^?1 on roadbeds with varying characteristics including ~3–7 m² micro‐catchment areas, 2–11° slopes, 2–9.7‐m‐long shallow rill features, and 30–100% gravel cover. The contributions of micro‐catchment size and rill length were the most important physical characteristics affecting runoff response and sediment production; both the size of the micro‐catchment and the length of the rills were inversely related to sediment loss and this contradicts most of the rill erosion literature. The effect of micro‐catchment size on runoff and sediment response suggests a potentially problematic spatial‐scale subjectivity of experimental plot results. The inverse relationship between rill length and sediment generation is interpreted here as related to the predominance of coarse fragments within rills, the inability of the shallow flows generated during the simulations to erode this sediment, and their role as zones of net sediment storage. Copyright © 2015 John Wiley & Sons, Ltd.     

Runoff and suspended sediment yields from an unpaved road segment,St John,US Virgin Islands

Unpaved roads are believed to be the primary source of terrigenous sediments being delivered to marine ecosystems around the island of St John in the eastern Caribbean. The objectives of this study were to: (1) measure runoff and suspended sediment yields from a road segment; (2) develop and test two event‐based runoff and sediment prediction models; and (3) compare the predicted sediment yields against measured values from an empirical road erosion model and from a sediment trap. The runoff models use the Green–Ampt infiltration equation to predict excess precipitation and then use either an empirically derived unit hydrograph or a kinematic wave to generate runoff hydrographs. Precipitation, runoff, and suspended sediment data were collected from a 230 m long, mostly unpaved road segment over an 8‐month period. Only 3–5 mm of rainfall was sufficient to initiate runoff from the road surface. Both models simulated similar hydrographs. Model performance was poor for storms with less than 1 cm of rainfall, but improved for larger events. The largest source of error was the inability to predict initial infiltration rates. The two runoff models were coupled with empirical sediment rating curves, and the predicted sediment yields were approximately 0·11 kg per square meter of road surface per centimetre of precipitation. The sediment trap data indicated a road erosion rate of 0·27 kg m^?2 cm^?1. The difference in sediment production between these two methods can be attributed to the fact that the suspended sediment samples were predominantly sand and silt, whereas the sediment trap yielded mostly sand and gravel. The combination of these data sets yields a road surface erosion rate of 0·31 kg m^?2 cm^?1, or approximately 36 kg m^?2 year^?1. This is four orders of magnitude higher than the measured erosion rate from undisturbed hillslopes. The results confirm the importance of unpaved roads in altering runoff and erosion rates in a tropical setting, provide insights into the controlling processes, and provide guidance for predicting runoff and sediment yields at the road‐segment scale. Copyright © 2006 John Wiley & Sons, Ltd.     

The Hesperides basin: a continental‐scale upper Palaeozoic to Triassic basin in southern Gondwana

The late Palaeozoic to Triassic sedimentary record of the central Argentinean offshore was analysed through the integration of data from exploratory wells and 2D seismic lines. Our interpretations were combined with existing ones in Argentina, Uruguay, Brazil and South Africa for their analysis in the late Palaeozoic south‐western Gondwana context. The mapped upper Palaeozoic‐Lower Triassic stratigraphic record offshore Argentina bears a thickness of +7000 m south of the Colorado basin and encompasses the time span between Pennsylvanian and Lower Triassic; this means that it triples that of the Sierras de la Ventana of Argentina and involves a far larger time span. On the basis of seismic stratigraphic interpretations in localities near the coast, we interpret that a strong denudation process removed a great portion of the stratigraphic record in the Sierras de la Ventana, the surrounding plains and the Tandilia system of Buenos Aires. The seismic stratigraphic configuration of the late Palaeozoic succession shows continuous and parallel reflections in a wide sediment wedge extending for more than 1000 km between the Gondwanides orogen core to the south and offshore Uruguay to the north. Two salient aspects of this sedimentary wedge are that no flexural depocentre was observed at the Ventania fold belt front, and that deformation in the orogenic front is post‐Lower Triassic. The original westwards extent of the basin is interpreted to have encompassed the whole of Buenos Aires province in continuity with the Chacoparaná basin; to the east continuity and a straightforward correlation with the Karoo basin was interpreted. The name of Hespérides Basin is proposed herein to refer to a Pennsylvanian to Lower Triassic basin mainly controlled by dynamic subsidence that encompasses and exceeds the area of the Sauce Grande and Colorado basins and the Claromecó fore‐deep in Argentina. The Hespérides basin is interpreted to have been in lateral continuity with the Kalahari, Karoo and Chacoparaná basins of Africa and South America forming a +3 000 000 sq. km depocentre.     

Understanding the dynamics and contamination of an urban aquifer system using groundwater age (14C, 3H,CFCs) and chemistry

The quality of the groundwater supplying drinking water to the Guadalajara metropolitan area has deteriorated due to both endogenic and exogenic processes. Previous studies of this complex neotectonic volcanic environment suggest that the sources of contamination here are underground fluids derived from an active volcanic center and surface wastewater derived from regional land‐use intensification. This study uses isotopic, gaseous, and chemical signatures to more comprehensively characterize this groundwater flow and its contamination paths. Groundwater is mainly recharged at the La Primavera Caldera to the west and is discharged into the Santiago River to the east. The exception to this trend is the Toluquilla area, where groundwater most likely represents rainfall originating from outside the basin limits. Evaporation affects groundwater in these areas, especially waters that have been affected by recycling below urban areas in the Atejamac area and by intensive agricultural activity in the Toluquilla area. Additionally, we present evidence that groundwater flow through alluvial sediments and tuffs in deeper wells mixes with a lower aquifer unit in basaltic‐andesitic rocks, which are in contact with hydrothermal fluids. Groundwater ages range from postbomb in the western and northwestern regions of the study area (i.e., the Atemajac aquifer unit) to Late Pleistocene in the southern and southeastern regions (i.e., the Toluquilla aquifer unit). Recently recharged water records little mixing and is located mostly in or near the La Primavera volcanic system. As groundwater undergoes gravitational flow towards discharge areas, it mixes with older water components. Chloride and sodium concentrations above natural background levels are primarily related to volcanic activity, nitrate is associated with human activities, and sulfate originates from both anthropogenic sources and water–rock interactions. Nitrate originating from land‐use activities (such as sewers, septic tanks, landfills, and agricultural fields) that is introduced into the deeper part of the groundwater system is expected to travel with the groundwater to the discharge areas because oxidizing conditions will prevent microbial reduction. See Supplementary Information.     

Metal contents in Porites corals: Anthropogenic input of river run-off into a coral reef from an urbanized area, Okinawa

In order to monitor pollutants from urban areas to coral reefs, metal contents in Porites coral samples collected from the Hija River mouth and at nearby sites from the estuary were analyzed. The corals were cleaned by oxidative and reductive treatments to effectively eliminate detritus and organic materials. Metal-to-calcium (Me/Ca) ratios in the samples were determined by ICP-MS. Filtered samples of river water were also measured similarly for metal concentrations. The extent of anthropogenic contribution by riverine input was assessed by comparing the Me/Ca values in corals to those of Rukan-sho, an unpolluted coral reef. High riverine inputs of Mn, Cd, Zn and Ag were observed from Me/Ca values in the coral samples. Manganese in the coral samples showed strong dependence on salinity, varying inversely to the distance from terrestrial sources. Considering a lead background of 25.0 nmol/mol measured in the Rukan-sho corals, Pb/Ca in corals of the Hija River estuary that are two and three times higher may indicate lead enrichment in the river mouth. Because Pb is only moderately high in the Hija River water compared to its concentration in surface seawater, lead may have accumulated in the estuarine water and sediments, resulting in an elevated concentration of lead available for coral uptake.