Exploring the effects of urban and agricultural land use on surface water chemistry,across a regional watershed,using multivariate statistics

In this paper, the influence of anthropogenic activity on surface water chemistry is investigated. Base flow samples from dominant land use streams in the Muskegon River Watershed, Michigan, USA, were analyzed for nutrients, major ions, and trace elements. Principal component and hierarchical cluster analysis were used to investigate the processes controlling the effects of land use on the biogeochemistry of streams in this Watershed. Biogeochemical fingerprints of land use were developed based on the results of the cluster analysis. Spider diagrams which referenced the natural environment aided the identification of the individual contributions of urban and agricultural land uses to surface water chemistry. The biogeochemical fingerprints quantified support previous findings (Urb: Na, K, Cl/Ag: Ca, Mg) and produced new insights into the effects of land use on the behavior of nutrients (Ag: N and Urb: N, P) and trace elements (Urb: V, Cr, Co, Cu, Se, Rb, Mo, Sr, Cd, Pb and Ba/Ag: U and As). The higher correlations of urban than agricultural land uses with nutrients, specifically P, were not expected and may reflect the effects of fertilization and wastewater or the season the samples were taken. More study in different geologic and urban settings is needed to help refine these fingerprints, but it is becoming apparent that despite obscuring factors, land use produces consistent, quantifiable associations between biogeochemical analytes.     

钻孔灌注桩桩底沉渣压浆处理研究与应用

对桩底沉渣产生的原因、沉渣对灌注桩承载能力的影响以及沉渣的处理作了简要分析,讨论了灌注桩桩底压浆工艺的作用机理。重点结合实际工程介绍了该技术,经检测表明,灌注桩桩底压浆技术的使用有效地处理了沉渣,提高了桩的承载能力。     

High Precision Time Domain Forward Modeling for Crosshole Electromagnetic Tomography

To improve the resolution of crosshole electromagnetic tomography, high precision of forward modeling is necessary. A pseudo-spectral time domain (PSTD) forward modeling was used to simulate electromagnetic wave propagation between two boreholes. The PSTD algorithm is based on the finite difference time domain (FDTD) method and uses the fast Fourier transform (FFT) algorithm for spatial derivatives in Maxwell's equations. Besides having the strongpoint of the FDTD method, the calculation precision of the PSTD algorithm is higher than that of the FDTD method under the same calculation condition. The forward modeling using the PSTD method will play an important role in enhancing the resolution of crosshole electromagnetic tomography.     

Establishing the time of initial human occupation of Liang Bua, western Flores, Indonesia

Liang Bua, a limestone cave in western Flores, has an archaeological and faunal sequence known to span the last 95 ka and is the type-site for a small-bodied hominid species, Homo floresiensis. This paper describes the geomorphic history of this significant site, and presents numerical ages for key events as determined by thermoluminescence dating of sediments (using a dual-aliquot regenerative-dose protocol) and uranium-series dating of flowstones. Our age estimates indicate that Liang Bua existed as a subterranean chamber by 400 ka ago. It was subsequently exposed by the incision of the Wae Racang River, which invaded the cave around 190 ka and deposited an upward-fining sequence of water-rolled boulders and cobbles. The latter conglomerate was partially reworked around 130 ka ago and was capped by flowstones at 100 ka. The conglomerate also contains stone artefacts, which implies that the occupation of the surrounding area is at least as old as the time of emplacement of the conglomerate. After 190 ka, a complex sequence of erosion and deposition led to the accumulation of at least 11 m of sediment in the front chamber of the cave, which proved suitable for hominid occupation. Such geochronological and geomorphological information is extremely valuable for interpreting the archaeological record at Liang Bua and its wider significance.     

不同标度震级关系和台基影响问题探讨

利用近年中国数字地震台网观测报告中的中国及邻区地震目录资料,取能够同时计算面波震级MS和近震震级ML的地震,拟合出2种震级之间的关系,发现与过去使用30余年的换算公式存在系统差别。考虑现代化地震数字观测系统有动态范围大、频带宽、台站多、覆盖区域广、测定精度高的特点,由此拟合的关系应当更可靠。考虑不同误差因素统计面波震级MS和近震震级ML的关系表明,2种震级之间换算和不换算的差别并不大,因此建议MS和ML震级之间不换算为宜。分析地震台站的场地响应发现:一些基岩台的放大因子在1附近,场地响应不随频率变化;处于沉积土层的台站,放大因子在低频段大于1,高频段小于1;还有一些台站在某个频段范围大于1,或者小于1。另外,沉积土层台站的单台震级和台网平均震级差也随周期增大,呈现由负到正的增长趋势。看来并不存在固定的台站校正系数,因此不能把台站校正作为提高震级测定精度的方法。     

京津冀地区地下流体数字化观测数据完整率及其地震前兆监测有效性的调查与分析

在北京、天津、河北二市一省部分地区抽样调查了13口井水位、11口井水温、5口井气氡、2口井气汞、2口井氦气数字化观测现状,统计分析了其数据完整率及观测断记次数与数据缺失量;在调查观测数据断记及其原因的基础上,进一步统计分析了数据缺失的主要原因,分析了连续完整的数据系列在地震前兆监测中的有效性。研究结果表明,除了氦气之外,水位、水温、气氡与气汞4大主要测项的运行,总体上是正常的;但多数井多数测项存在断记与数据缺失的问题,其主要原因是仪器故障与运行不正常,其次是停电、通信线路故障与雷击,此外还存在原因不明的断记与缺数的问题;以井统计,约有1/2的水位与水温观测井可在地震中期与短临前兆中发挥作用,而气氡、气汞等化学量观测只在地震短临前兆监测中,约有一半的井有可能发挥一定效能。     

Seismic identification of channel sandbodies in the Fuyang oil layer in North Songliao Basin, China

The Fuyang oil-layer in North Songliao Basin is characterized by thin interbedded sands and shales, strong lateral variation, strong reservoir heterogeniety, and so on. The thickness of individual sand layers is generally 3 - 5 m. Identifying the channel sand-bodies of the Fuyang oil layer using seismic techniques is very difficult due to the low seismic resolution. Taking the GTZ area as an example, we discuss the genetic characteristics of the channel sand-bodies and point out the real difficulty in using seismic techniques to predict the channel sand-bodies. Two methods for the identification of channels are presented： frequency spectrum imaging and pre-stack azimuthal anisotropy. Identifying the channel sand-bodies in Fuyu oil-layer using the two seismic methods results in a success rate up to 80% compared with well data.     

Collision leading to multiple-stage large-scale extrusion in the Qinling orogen: Insights from the Mianlue suture

The geologic framework of the Phanerozoic Qinling–Dabie orogen was built up through two major suturing events of three blocks. From north to south these include the North China craton (including the north Qinling block), the Qinling–Dabie microblock, and the South China craton (including the Bikou block), separated by the Shangdan and Mianlue sutures. The Mianlue suture zone contains evidence for Mesozoic extrusion tectonics in the form of major strike–slip border faults surrounding basement blocks, a Late Paleozoic ophiolite and a ca. 240–200 Ma thrust belt that reformed by 200–150 Ma thrusts during A-type (intracontinental) subduction. The regional map pattern shows that the blocks are surrounded by complexly deformed Devonian to Early Triassic metasandstones and metapelites, forming a regional-scale block-in-matrix mélange fabric. Five distinct tectonic units have been recognized in the belt: (1) basement blocks including two types of Precambrian basement, crystalline and transitional; (2) continental margin slices including Early Paleozoic strata, and Late Paleozoic fluviodeltaic sedimentary rocks, proximal and distal fan clastics, reflecting the development of a north-facing rift margin on the edge of the South China plate; (3) out of sequence oceanic crustal slices including strongly deformed postrift, deep-water sedimentary rocks, sheeted dikes, basalts, and mafic–ultramafic cumulates of a Late Paleozoic ophiolite suite, developing independent of the rift margin in a separate basin; (4) out-of-sequence island-arc slices; (5) accretionary wedge slices. All the tectonic units were deformed during three geometrically distinct deformation episodes (D₁, D₂ and D₃ during 240–200 Ma). Units 2–4 involved southward thrusting and vertical then southward extrusion of about 20 km of horizontal displacement above the autochthonous basement during the D₁ episode. Thrust slices 20 km south of the Mianlue suture are related to this vertical extrusion due to the same rock assemblages, ages and kinematics. The D₂ and D₃ episodes folded all the units in a thick-skinned style about east–west (D₂) and west–northwest (D₃) axes in the Mianlue suture zone. An early foreland propagating sequence of accretion of Late Paleozoic rocks deposited above the Yangtze craton is not involved in D₁ deformation but is temporally equivalent to the D₂ and D₃ deformation in the Mianlue suture. Two stages of strike–slip faulting mainly occurred at the end of D₂ and D₃, respectively. During D₂ deformation, the Bikou block was obliquely indented to the ESE into the Mianlue suture, rather than being thrust over the Mianlue suture from the north as a part of the Qinling–Dabie microblock. During D₃ deformation, however, the Bikou block was bounded by the south boundary fault of the Mianlue suture, and the Yangpingguan fault on the south. These faults are coeval strike–slip faults, but of opposite senses, and accommodated minor southwestward extrusion of the Bikou block into Songpan–Ganze orogen. The other basement blocks north of the Mianlue suture were extruded eastward by about 20 km of lateral displacement, based on the offset of the Wudang dome, during the D₃ episode due to the northeastward indentation of the Hannan complex of the South China craton. Post-D₃ emplacement of granite, cutting across the strike–slip faults such as the Mianlue suture, provides a minimum age of 200 Ma for D₃ deformation. Therefore, based on insights from the evolution of the Mianlue suture, the D₂ and D₃ episodes in the Mianlue suture and its neighbors are not responsible for and associated with the two-stage extrusion of the Dabie UHP-HP terranes from the Foping dome to the present erosional surface (more than 350 km).     

山西西山煤田7号煤层成因类型研究

煤的成因类型通过煤的有机显微组成、矿物成分等来体现。从微观研究的角度出发，以各子样的显微煤岩组分统计值、镜惰比（V/I）、骨基比（F／M）、矿物质含量为依据，对西山煤田屯兰煤矿7号煤进行成因类型划分，分为4类6型，即Ⅰ-①、Ⅲ-①、Ⅲ-②、Ⅳ-①、Ⅳ-②、Ⅴ-①。自下而上对煤层划分了23个成因分层。7煤层以Ⅳ类成因类型为主，沉积了覆水森林沼泽环境。     

Geology and Metallogenesis of the Sawayaerdun Gold Deposit in the Southwestern Tianshan Mountains, Xinjiang, China

The Sawayaerdun gold deposit, located in Wuqia County, Southwest Tianshan, China, occurs in Upper Silurian and Lower Devonian low‐grade metamorphic carbonaceous turbidites. The orebodies are controlled by a series of NE‐NNE‐trending, brittle–ductile shear zones. Twenty‐four gold mineralized zones have been recognized in the Sawayaerdun ore deposit. Among these, the up to 4‐km‐long and 200‐m wide No. IV mineralized zone is economically the most important. The average gold grade is 1–6 g/t. Gold reserves of the Sawayaerdun deposit have been identified at approximately 37 tonnes and an inferred resource of 123 tonnes. Hydrothermal alteration is characterized by silicification, pyritization, arsenopyritization, sericitization, carbonatization and chloritization. On the basis of field evidence and petrographic analysis, five stages of vein emplacement and hydrothermal mineralization can be distinguished: stage 1, early quartz stage, characterized by the occurrence of quartz veins; stage 2, arsenopyrite–pyrite–quartz stage, characterized by the formation of auriferous quartz veinlets and stockworks; stage 3, polymetallic sulfide quartz stage, characterized by the presence of auriferous polymetallic sulfide quartz veinlets and stockworks; stage 4, antimony–quartz stage, characterized by the formation of stibnite–jamesonite quartz veins; and stage 5, quartz–carbonate vein stage. Stages 2 and 3 represent the main gold mineralization, with stage 4 representing a major antimony mineralization episode in the Sawayaerdun deposit. Two types of fluid inclusion, namely H₂O–NaCl and H₂O–CO₂–NaCl types, have been recognized in quartz and calcite. Aqueous inclusions show a wide range of homogenization temperatures from 125 to 340°C, and can be correlated with the mineralization stage during which the inclusions formed. Similarly, salinities and densities of these fluids range for each stage of mineralization from 2.57 to 22 equivalent wt% NaCl and 0.76 to 1.05 g/cm³, respectively. The ore‐forming fluids thus are representative of a medium‐ to low‐temperature, low‐ to medium‐salinity H₂O–NaCl–CO₂–CH₄–N₂ system. The δ³⁴S_CDT values of sulfides associated with mineralization fall into a narrow range of ?3.0 to +2.6‰ with a mean of +0.1‰. The δ¹³C_PDB values of dolomite and siderite from the Sawayaerdun gold deposit range from ?5.4 to ?0.6‰, possibly reflecting derivation of the carbonate carbon from a mixed magmatic/sedimentary source. Changes in physico‐chemical conditions and composition of the hydrothermal fluids, water–rock exchange and immiscibility of hydrothermal fluids are inferred to have played important roles in the ore‐forming process of the Sawayaerdun gold–antimony deposit.