The role of liquid immiscibility in the genesis of carbonatites — An experimental study

The two-liquid field between alkali-carbonate liquids and phonolite or nephelinite magmas from the Oldoinyo Lengai volcano has been determined between 0.7 and 7.6 kb and 900°–1,250° C. The miscibility gap expands with increase in and decrease in temperature. Concomitantly there is a rotation of tie-lines so that the carbonate liquids become richer in CaO. The element distribution between the melts indicates that a carbonate liquid equivalent in composition to Oldoinyo Lengai natrocarbonatite lava would have separated from a phonolitic rather than a nephelinitic magma. CO₂-saturated nephelinites coexist with carbonate liquids much richer in CaO than the Lengai carbonatites, but even so these liquids have high alkali concentrations. If the sövites of hypabyssal and plutonic ijolite-carbonatite complexes originated by liquid immiscibility, then large quantities of alkalis have been lost, as is suggested by fenitization and related phenomena. The miscibility gap closes away from Na₂O-rich compositions, so that the tendency to exsolve a carbonatite melt is greater in salic than in mafic silicate magmas. The two-liquid field does not approach kimberlitic compositions over the range of pressures studied, suggesting that the globular textures observed in many kimberlite sills and dykes may be the result of processes other than liquid immiscibility at crustal pressures.     

Geology of the dry creek site; a stratified early man site in Interior Alaska

The Dry Creek archeologic site contains a stratified record of late Pleistocene human occupation in central Alaska. Four archeologic components occur within a sequence of multiple loess and sand layers which together form a 2-m cap above weathered glacial outwash. The two oldest components appear to be of late Pleistocene age and occur with the bones of extinct game animals. Geologic mapping, stratigraphic correlations, radiocarbon dating, and sediment analyses indicate that the basal loess units formed part of a widespread blanket that was associated with an arctic steppe environment and with stream aggradation during waning phases of the last major glaciation of the Alaska Range. These basal loess beds contain artifacts for which radiocarbon dates and typologic correlations suggest a time range of perhaps 12,000–9000 yr ago. A long subsequent episode of cultural sterility was associated with waning loess deposition and development of a cryoturbated tundra soil above shallow permafrost. Sand deposition from local source areas predominated during the middle and late Holocene, and buried Subarctic Brown Soils indicate that a forest fringe developed on bluff-edge sand sheets along Dry Creek. The youngest archeologic component, which is associated with the deepest forest soil, indicates intermittent human occupation of the site between about 4700 and 3400 ¹⁴C yr BP.     

A Nd isotope investigation of sediments related to crustal development in the British Isles

The times of original fractionation of the Sm and Nd component of clastic sediments from a mantle source (≡ crustal residence age) have been estimated from Sm-Nd model ages calculated relative to a depleted mantle evolution. In this way the provenance and evolution of selected Precambrian and Phanerozoic sediments and metasediments from the British Isles have been examined. Whereas some Archaean and early Proterozoic sediments have Sm-Nd model ages that are close to their stratigraphic age, the Phanerozoic sediments analysed have model ages as much as 2.0 Ga in excess of their stratigraphic age.A more detailed study of Lower Palaeozoic sediments deposited on the northern margin of the Iapetus Ocean provides evidence for a marked change of provenance in the Ordovician after the deposition of the Dalradian Supergroup. A component with comparatively high¹⁴³Nd/¹⁴⁴Nd and Sm/Nd ratio (presumably basaltic) is present in the sediments throughout the accretionary prism. Crustal residence age estimates average about 1.5 Ga for both these Lower Palaeozoic sediments, and modern pelagic clays, and collectively fail to provide any evidence for significant continental growth during the Phanerozoic.     

Benthonic foraminiferal faunal and isotopic data for the postglacial evolution of the Champlain Sea

Benthonic foraminiferal faunal and isotopic data from Champlain Sea sediments (approximately 12,500 to 10,000 yr B.P. in age) in two piston cores from Lake Champlain provide a detailed, apparently continuous record of the evolution of the Champlain Sea. Cassidulina reniforme and Islandiella helenae are the dominant benthonic foraminifera during the initial phase of the Champlain Sea, and are replaced by Elphidium excavatum forma clavatum and Protelphidium orbiculare as the dominant species during the remainder of the sea's history. The oxygen-isotopic data show a gradual decrease in δ¹⁸O between approximately 12,500 and 10,900 yr B.P., followed by a more rapid decrease during the interval 10,900 to 10,000 yr B.P. The δ¹³C data have a similar trend as δ¹⁸O, with generally decreasing values up the section. The isotopic and faunal data suggest that nearly marine conditions were present in the initial plase of the Champlain Sea, followed by gradually decreasing salinities and increasing temperatures as the sea evolved. The beginning of the rapid isotopic decrease at approximately 10,900 yr B.P. marks the onset of the largest environmental change in the history of the Champlain Sea, probably reflecting a major pulse of meltwater from the Laurentide Ice Sheet.     

The inner city: In search of the problem

This paper explores the theoretical content of the inner-city debate in Britain and seeks to examine the extent to which the ‘problem’ is either new or primarily economic. It is argued that the inner-city issue, while subject to specific political and ideological forces, is associated with the general processes of uneven capitalist development. In this sense, metropolitan decline is a further manifestation of the relationship between the built environment, the transience of economic activity and social change. More specifically the decline of the inner city relates to the incipient role of Britain in the development of capitalism and its current position in the world economy. The emergence of this as a ‘problem’ for the British state is combined with a convenient spatial determinism, which isolates the inner city as an anomaly even as the search for palliatives is erected to the status of a major social task.     

The melting relationships of a madupite from the Leucite Hills,Wyoming, to 30 Kb

The water-undersaturated melting relationships of a mafic, peralkaline, potassic madupite (with about 3% H₂O as shown by chemical analysis) from the Leucite Hills, Wyoming, have been studied at pressures up to 30 kb. At low pressures (<5 kb) leucite is the dominant liquidus phase, but it is replaced at higher pressures by clinopyroxene plus olivine (<5–7 kb), clinopyroxene (7–12.5 kb), clinopyroxene plus minor spinel (12.5–17.5 kb), and clinopyroxene alone (17.5–> 30 kb). At all pressures there is a reaction relationship with falling temperature between melt, olivine and probably clinopyroxene to yield phlogopite. Apatite is stable within the melting interval to pressures above 25 kb. Electron microprobe analyses demonstrate that the clinopyroxene is diopsidic, with low aluminium and titanium contents. Pressure has relatively little effect on the composition of the pyroxene. Phlogopite is also aluminium-poor and has only a moderate titanium content. The experimental results indicate that madupite is not the partial melting product of hydrous lherzolite or garnet lherzolite in the upper mantle and it seems improbable that it is derived by melting of mantle peridotite with a mixed H₂O-CO₂ volatile component. Madupite could, however, be the partial melting product of mica-pyroxenite or mica-olivine-pyroxenite in the upper mantle. It is pointed out that the chemistry of some potassium-rich volcanics may have been affected by volatile transfer and other such processes during eruption and that experimental studies of material affected in this way have little bearing upon the genesis of potassic magmas. Finally, the experimental results enable constraints to be placed upon the P-T conditions of the formation of richterite-bearing mica nodules found in kimberlites and associated rocks. Maximum conditions are 25 kb and 1,100 ° C.