Late quaternary sea‐level changes,crustal movements and coastal evolution in Northumberland,UK

Northumberland lies in the transition between Holocene emergence and submergence and is thus a critical zone for testing models of isostatic rebound. We have collected data from this area to reconstruct relative sea‐level changes and lateral coastline movements for the last 14000 y. These are deposits from tidal marsh, back‐barrier wetland and terrestrial environments producing 47 sea‐level index points from 12 sites. There is no unequivocal evidence for Late Devensian sea levels above present and the reliable sea‐level index points are restricted between −6 m and +2.5 m relative to present and 9.0–2.5 kyr cal. BP. Analysis of these quantifies differential responses to glacio‐ and hydroisostatic rebound, with the northern sites recording a mid‐Holocene sea‐level maximum ca. 2.5 m above present, whereas the southern sites show a maximum ca. 0.5 m above present. These observations show a reasonable fit with the predictions from quantitative models of glacio and hydroisostatic rebound, but there is currently no unique solution of Earth and ice model parameters that will explain all the sea‐level observations. Copyright © 2000 John Wiley & Sons, Ltd.     

Fluvial suspended sediment yields over hours to millennia in the High Arctic at proglacial Lake Linnévatnet,Svalbard

Sediment yield can be a sensitive indicator of catchment dynamics and environmental change. For a glacierized catchment in the High Arctic, we compiled and analyzed diverse sediment transfer data, spanning a wide range of temporal scales, to quantify catchment yields and explore landscape response to past and ongoing hydroclimatic variability. The dataset integrates rates of lake sedimentation from correlated varve records and repeated annual and seasonal sediment traps, augmented by multi‐year lake and fluvial monitoring. Consistent spatial patterns of deposition enabled reconstruction of catchment yields from varve‐ and trap‐based fluxes. We used hydroclimatic data and multivariate modeling to examine annual controls of sediment delivery over almost a century, and to examine shorter‐term controls of sediment transfer during peak glacier melt. Particle‐size analyses, especially for annual sediment traps, were used to further infer sediment transfer mechanisms and timing. Through the Medieval Warm Period and Little Ice Age, there were no apparent multi‐century trends in lake sedimentation rates, which were over three times greater than those during the mid‐Holocene when glaciers were diminished. Twentieth‐century sedimentation rates were greater than those of previous millennia, with a mid‐century step increase in mean yield from 240 to 425 Mg km^?2 yr^?1. Annual yields through the twentieth century showed significant positive relations with spring/summer temperature, rainfall, and peak discharge conditions. This finding is significant for the future of sediment transfer at Linnévatnet, and perhaps more broadly in the Arctic, where continued increases in temperature and rainfall are projected. For 2004–2010, annual yields ranged from 294 to 1330 Mg km^?2 yr^?1. Sediment trap volumes and particle‐size variations indicate that recent annual yields were largely dominated by spring to early summer transfer of relatively coarse‐grained sediment. Fluvial monitoring showed daily to hourly sediment transfer to be related to current and prior discharge, diurnal hysteresis, air temperature, and precipitation. Copyright © 2017 John Wiley & Sons, Ltd.     

The oxidative dissolution of arsenopyrite (FeAsS) and enargite (Cu3AsS4) by Leptospirillum ferrooxidans

Arsenopyrite (FeAsS) and enargite (Cu₃AsS₄) fractured in a nitrogen atmosphere were characterised after acidic (pH 1.8), oxidative dissolution in both the presence and absence of the acidophilic microorganism Leptospirillum ferrooxidans. Dissolution was monitored through analysis of the coexisting aqueous solution using inductively coupled plasma atomic emission spectroscopy and coupled ion chromatography-inductively coupled plasma mass spectrometry, and chemical changes at the mineral surface observed using X-ray photoelectron spectroscopy and environmental scanning electron microscopy (ESEM). Biologically mediated oxidation of arsenopyrite and enargite (2.5 g in 25 ml) was seen to proceed to a greater extent than abiotic oxidation, although arsenopyrite oxidation was significantly greater than enargite oxidation. These dissolution reactions were associated with the release of ∼917 and ∼180 ppm of arsenic into solution. The formation of Fe(III)-oxyhydroxides, ferric sulphate and arsenate was observed for arsenopyrite, thiosulphate and an unknown arsenic oxide for enargite. ESEM revealed an extensive coating of an extracellular polymeric substance associated with the L. ferrooxidans cells on the arsenopyrite surface and bacterial leach pits suggest a direct biological oxidation mechanism, although a combination of indirect and direct bioleaching cannot be ruled out. Although the relative oxidation rates of enargite were greater in the presence of L. ferrooxidans, cells were not in contact with the surface suggesting an indirect biological oxidation mechanism. Cells of L. ferrooxidans appear able to withstand several hundreds of ppm of As(III) and As(V).     

Carbon stars

In this paper, the present state of knowledge of the carbon stars is discussed. Particular attention is given to issues of classification, evolution, variability, populations in our own and other galaxies, and circumstellar material.     

Introduction to the JoPL special issue, “Holocene paleoenvironmental records from Arctic lake sediment”

The 18 papers in this Special Issue of the Journal of Paleolimnology report new records of Holocene environmental and climate change from Arctic lake sediment. At least 15 distinct physical, chemical, and biological properties were analyzed at lakes located across the North American Arctic and subarctic, and northwestern Europe. The studies are notable for their multi-proxy approach (eight present data for at least five different proxies), and for the high quality of their geochronological control. Three of the studies analyzed sediment from more than one lake to test the influence of contrasting physiographic settings on the response of proxies to the same climate forcing. The sedimentary sequences analyzed in seven studies extend beyond 11.5?cal?ka, providing evidence for pronounced climate shifts that took place during the late-glacial period. Two-thirds extend beyond 8?cal?ka; many of these records were interpreted in terms of the shift in temperature and moisture that occurred during the transition from the warm early to middle Holocene to the cooler late Holocene. These records contribute to the growing network of sites that is needed to reconstruct the spatial pattern of this pronounced paleoclimate transition, and to address how ocean-atmospheric circulation changed with the mean?state of climate.     

The Virtual Worlds Project: geological mapping and field skills

The Virtual Worlds Project is a UK collaboration between the School of Earth and Environment, University of Leeds, and the Leeds College of Art, to build a virtual environment in which to learn and practice basic geological mapping skills. Using the Unity game engine, a virtual landscape populated by rock outcrops with associated notebook entries has been created. This approach is not a replacement for field map work. Rather, it represents an in‐class tool with the appearance of a computer game with which to enhance basic mapping skills taught in the field in a virtual environment.     

Projected Reorganization of Florida Bay Seagrass Communities in Response to the Increased Freshwater Inflow of Everglades Restoration

Historic changes in water-use management in the Florida Everglades have caused the quantity of freshwater inflow to Florida Bay to decline by approximately 60% while altering its timing and spatial distribution. Two consequences have been (1) increased salinity throughout the bay, including occurrences of hypersalinity, coupled with a decrease in salinity variability, and (2) change in benthic habitat structure. Restoration goals have been proposed to return the salinity climates (salinity and its variability) of Florida Bay to more estuarine conditions through changes in upstream water management, thereby returning seagrass species cover to a more historic state. To assess the potential for meeting those goals, we used two modeling approaches and long-term monitoring data. First, we applied the hydrological mass balance model FATHOM to predict salinity climate changes in sub-basins throughout the bay in response to a broad range of freshwater inflow from the Everglades. Second, because seagrass species exhibit different sensitivities to salinity climates, we used the FATHOM-modeled salinity climates as input to a statistical discriminant function model that associates eight seagrass community types with water quality variables including salinity, salinity variability, total organic carbon, total phosphorus, nitrate, and ammonium, as well as sediment depth and light reaching the benthos. Salinity climates in the western sub-basins bordering the Gulf of Mexico were insensitive to even the largest (5-fold) modeled increases in freshwater inflow. However, the north, northeastern, and eastern sub-basins were highly sensitive to freshwater inflow and responded to comparatively small increases with decreased salinity and increased salinity variability. The discriminant function model predicted increased occurrences of Halodule wrightii communities and decreased occurrences of Thalassia testudinum communities in response to the more estuarine salinity climates. The shift in community composition represents a return to the historically observed state and suggests that restoration goals for Florida Bay can be achieved through restoration of freshwater inflow from the Everglades.     

Mineral-organic-microbe interactions: Environmental impacts from molecular to macroscopic scales

The role of microbes in geological processes is discussed with particular reference to the geochemical cycle involving iron. Microbial oxidation of Fe(II) minerals can occur via at least three mechanisms, the most important involving acidophilic prokaryotes which promote oxidation of iron sulphides. Accelerated breakdown of arsenopyrite is a good example, where multi-step electrochemical reactions are facilitated by the presence of organisms such as Leptospirillum ferrooxidans. Other organisms actively promote the reduction of Fe(III) to more soluble Fe(II). Reduction rates are highly variable, depending on mineral substrate, with oxyhydroxides being most reactive. Proper understanding of such redox processes requires knowledge of interactions at the molecular scale. Advances are being made through genetic studies of relevant organisms, and of mineral surfaces as exemplified by our experimental and computational studies of iron oxides such as magnetite, the reaction of which with simple organic molecules shows diverse behaviour. Mineral-organic interactions precede formation of bacterial biofilms, which can create local geochemical environments causing mineral precipitation. Biofilms and precipitate phases can have a major influence on fluid flow through fractures or porous media as we demonstrate using experiments from micro- to macro-scales.     

On the Vertical Thermal Structure of Pluto's Atmosphere

A radiative–conductive model for the vertical thermal structure of Pluto's atmosphere is developed with a non-LTE treatment of solar heating in the CH₄3.3 μm and 2.3 μm bands, non-LTE radiative exchange and cooling in the CH₄7.6 μm band, and LTE cooling by CO rotational line emission. The model includes the effects of opacity and vibrational energy transfer in the CH₄molecule. Partial thermalization of absorbed solar radiation in the CH₄3.3 and 2.3 μm bands by rapid vibrational energy transfer from the stretch modes to the bending modes generates high altitude heating at sub-microbar pressures. Heating in the 2.3 μm bands exceeds heating in 3.3 μm bands by approximately a factor of 6 and occurs predominantly at microbar pressures to generate steep temperature gradients ∼10–20 K km⁻¹forp> 2 μbar when the surface or tropopause pressure is ∼3 μbar and the CH₄mixing ratio is a constant 3%. This calculated structure may account for the “knee” in the stellar occultation lightcurve. The vertical temperature structure in the first 100 km above the surface is similar for atmospheres with Ar, CO, and N₂individually as the major constituent. If a steep temperature gradient ∼20 K km⁻¹is required near the surface or above the tropopause, then the preferred major constituent is Ar with 3% CH₄mixing ratio to attain a calculated ratio ofT/(= 3.5 K amu⁻¹) in agreement with inferred values from stellar occultation data. However, pure Ar and N₂ices at the same temperature yield an Ar vapor pressure of only ∼0.04 times the N₂vapor pressure. Alternative scenarios are discussed that may yield acceptable fits with N₂as the dominant constituent. One possibility is a 3 μbar N₂atmosphere with 0.3% CH₄that has 106 K isothermal region (T/= 3.8 K amu⁻¹) and ∼8 K km⁻¹surface/tropopause temperature gradient. Another possibility would be a higher surface pressure ∼10 μbar with a scattering haze forp> 2 μbar. Our model with appropriate adjustments in the CH₄density profile to Triton's inferred profile yields a temperature profile consistent with the UVS solar occultation data (Krasnopolsky, V. A., B. R. Sandel, and F. Herbert 1992.J. Geophys. Res.98, 3065–3078.) and ground-based stellar occultation data (Elliot, J. L., E. W. Dunham, and C. B. Olkin 1993.Bull. Am. Astron. Soc.25, 1106.).