Fluvial suspended sediment transfer and lacustrine sedimentation of recent flood turbidites in proglacial Eklutna Lake,western Chugach Mountains,Alaska

Suspended sediment delivery and deposition in proglacial lakes is generally sensitive to a wide range of hydrometeorologic and geomorphic controls. High discharge conditions are of particular importance in many glaciolacustrine records, with individual floods potentially recorded as distinctive turbidites. We used an extensive network of surface sediment cores and hydroclimatic monitoring data to analyse recent flood turbidites and associated sediment transfer controls over instrumental periods at Eklutna Lake, western Chugach Mountains, Alaska. Close to a decade of fluvial data from primary catchment tributaries show a dominating influence of discharge on sediment delivery, with various interconnections with other related hydroclimatic controls. Multivariate fluvial models highlight and help quantify some complexities in sediment transfer, including intra-annual variations, meteorological controls, and the influence of subcatchment glacierization. Sediments deposited in Eklutna Lake during the last half century are discontinuously varved and contain multiple distinctive turbidites. Over a 30-year period of stratigraphic calibration, we correlate the four thickest flood turbidites (1989, 1995, 2006, and 2012) to specific regional storms. The studied turbidites correlate with late-summer and early-autumn rainstorms with a magnitude of relatively instantaneous sedimentation 3–15 times greater than annual background accumulation. Our network of sediment core data captured the broad extent and sediment variability among the study turbidites and background sediment yield. Within-lake spatial modelling of deposition quantifies variable rates of downlake thinning and sediment focusing effects, and highlights especially large differences between the thickest flood turbidites and background sedimentation. This we primarily relate to strongly contrasting dispersion processes controlled by inflow current strength and turbidity. Sediment delivery is of interest for this catchment because of reservoir and water supply operations. Furthermore, although smaller floods may not be consistently represented, the lake likely contains a valuable proxy record of regional flooding proximal to major population centers of south-central Alaska including Anchorage.     

Surface fluxes of heat and water vapour from sites in the European Arctic

Summary  Measurements of the surface fluxes of heat and water vapour were taken at four sites across the European Arctic as part of the EU funded LAPP project. The sites cover a range of latitudinal, altitudinal and climatic conditions. The most northerly site is near Ny-?lesund, Svalbard, a polar semi-desert with continuous permafrost. A second permafrost site is a fen area in the Zackenberg valley, East Greenland. Finally two sites in northern Finland, Skalluvaara and Kaamanen are on the southern boundary of the region affected by permafrost. At all sites measurements were made of the turbulent fluxes of heat and water vapour using eddy correlation equipment for at least one active season. The net radiation totals for July and August are similar at all sites. At the sites with permafrost a substantial proportion (over 20%) of the net radiation goes into soil heat flux, to thaw the soil moisture in the top metre. Of the remaining energy just over half is used for evaporation. At the Finnish sites the vegetation is largely deciduous and this is seen in the record with higher evaporative ratios in July and August, after the vegetation becomes green. The Finnish sites tend to have higher surface resistance to evaporation; however, the evaporative demand is greater leading to slightly higher evaporation rates. The two Finnish sites have a similar seasonal pattern determined by the water table and seasonality of the vegetation. The two northern sites show a pattern that is determined primarily by the variation of water table only. It is concluded that the water balance through the active season is influenced primarily by the history of snow cover. The seasonality of the vegetation, the permafrost and the depth of water table are also important influences. Received November 1, 1999 Revised April 17, 2000     

Seasonal variations of net CO2 exchange in European Arctic ecosystems

Summary  The carbon dioxide exchange in arctic and subarctic terrestrial ecosystems has been measured using the eddy-covariance method at sites representing the latitudinal and longitudinal extremes of the European Arctic sea areas as part of the Land Arctic Physical Processes (LAPP) project. The sites include two fen (Kaamanen and Kevo) and one mountain birch ecosystems in subarctic northern Finland (69° N); fen, heathland, and snowbed willow ecosystems in northeastern Greenland (74° N); and a polar semidesert site in Svalbard (79° N). The measurement results, which are given as weekly average diurnal cycles, show the striking seasonal development of the net CO₂ fluxes. The seasonal periods important for the net CO₂ fluxes, i.e. winter, thaw, pre-leaf, summer, and autumn can be identified from measurements of the physical environment, such as temperature, albedo, and greenness. During the late winter period continuous efflux is observed at the permafrost-free Kaamanen site. At the permafrost sites, efflux begins during the thaw period, which lasts about 3–5 weeks, in contrast to the Kaamanen site where efflux continues at the same rate as during the winter. Seasonal efflux maximum is during the pre-leaf period, which lasts about 2–5 weeks. The summer period lasts 6 weeks in NE Greenland but 10–14 weeks in northern Finland. During a high summer week, the mountain birch ecosystem had the highest gross photosynthetic capacity, GP _max, followed by the fen ecosystems. The polar semidesert ecosystem had the lowest GP _max. By the middle of August, noon uptake fluxes start to decrease as the solar elevation angle decreases and senescence begins within the vascular plants. At the end of the autumn period, which lasts 2–5 weeks, topsoil begins to freeze at the end of August in Svalbard; at the end of September at sites in eastern Greenland; and one month later at sites in northern Finland. Received March 1, 2000 Revised October 2, 2000     

A Cerion-based chronostratigraphy and age model from the central Bahama Islands: Amino acid racemization and 14C in land snails and sediments

The taxonomy of the land-snail genus Cerion, and the relevance of hundreds of shell forms to phylogenetic and evolutionary processes has been the subject of much discussion over the past few decades. Fundamental to understanding evolutionary trends is the independent confirmation of the age, biostratigraphic, and chronostratigraphic order of a comprehensive set of fossil forms. Amino acid racemization (AAR) is a geochronological tool applicable to dating living and fossil Cerion shells. The extent of racemization of aspartic acid (Asp D/L) and glutamic acid (Glu D/L) were determined for 507 Cerion shells dating between the early last interglaciation (marine isotope stage (MIS) 5e, c. 125 ka) and the present from the Bahamas. The AAR data based on Cerion support the established morphostratigraphic succession of deposits younger than MIS 5e and provide greater resolution, particularly for biostratigraphic successions of Holocene age. Age models were constructed for Asp and Glu using D/L values paired with ¹⁴C ages and historical collection dates from 23 Cerion shells. In addition to the relative-age time series, the Holocene age models developed from D/L Glu and Asp apply to the last 7 ka and geographically within the central Bahamas. In two case studies, large numbers of AAR-generated ages provide insights into the age structure of accretionary soils and rates and age constraints on evolutionary processes related to Cerion land snails.     

A new model of tropical waves incorporating momentum mixing by cumulus convection

A comparison is made between the magnitudes of observed large-scale weather waves over the tropical Pacific and the magnitudes of the corresponding waves, predicted by wave-CISK theories, which are driven by the observed amount of latent heating (i.e., precipitation). The theoretical wave fields of meridional velocity, vorticity, and temperature rate are shown to exceed the observed quantities by an order of magnitude. An attempt is made to simulate the observed balance between the diabatic heating and adiabatic cooling within the context of the inviscid theories. For a broad class of heating profiles, geometries and basic states, it is found that this compensation without temperature change cannot be satisfactorily modelled, regardless of the vertical shape of the heating, when the vertical wavelength of the disturbance exceeds about 6 km.Scale analysis demonstrates that an important dynamical term has been neglected in the inviscid models, viz., the vertical transport of horizontal momentum by cumulus clouds. When this process is included in the wave model, velocities, relative vorticity, and the time rate of temperature change are all comparable to the observed values. The general behavior of a system where both forcing and cumulus “friction” are proportional to each other has not been previously examined. We find the behavior of such a system to have several novel features. For example, we find that for a wide range of precipitation amplitudes (from 1/4 to 4 times the precipitation amplitudes of waves in the western Pacific) we get essentially constant amplitudes for wind. The implications of this and other features for various aspects of tropical wave modelling are discussed.     

Predicted CO2 emissions from maceral concentrates of high volatile bituminous Kentucky and Illinois coals

A large collection of well-characterized coals, documented in the Center for Applied Energy Research's (CAER) database, was used to estimate the CO₂ content of maceral concentrates from Kentucky and Illinois high volatile bituminous coals. The data showed no correlation between CO₂ versus coal ranks and between CO₂ versus maceral content. Subsequently, eight sets of low-ash density-gradient centrifugation (DGC) maceral concentrates from five coal beds were examined, spanning in the high volatile rank range. Heating value was not determined on the concentrates, but instead was calculated using the Mott–Spooner formula. There was a good correlation between predicted CO₂ and maceral content for the individual iso-rank (based on vitrinite reflectance, analyzed on whole (parent) coal) sets. In general, the predicted CO₂ increases from liptinite-rich through vitrinite-rich to inertinite-rich concentrates (note: no “concentrates” are absolutely monomaceral).     

The oxidative dissolution of arsenopyrite (FeAsS) and enargite (Cu3AsS4) by Leptospirillum ferrooxidans

Arsenopyrite (FeAsS) and enargite (Cu₃AsS₄) fractured in a nitrogen atmosphere were characterised after acidic (pH 1.8), oxidative dissolution in both the presence and absence of the acidophilic microorganism Leptospirillum ferrooxidans. Dissolution was monitored through analysis of the coexisting aqueous solution using inductively coupled plasma atomic emission spectroscopy and coupled ion chromatography-inductively coupled plasma mass spectrometry, and chemical changes at the mineral surface observed using X-ray photoelectron spectroscopy and environmental scanning electron microscopy (ESEM). Biologically mediated oxidation of arsenopyrite and enargite (2.5 g in 25 ml) was seen to proceed to a greater extent than abiotic oxidation, although arsenopyrite oxidation was significantly greater than enargite oxidation. These dissolution reactions were associated with the release of ∼917 and ∼180 ppm of arsenic into solution. The formation of Fe(III)-oxyhydroxides, ferric sulphate and arsenate was observed for arsenopyrite, thiosulphate and an unknown arsenic oxide for enargite. ESEM revealed an extensive coating of an extracellular polymeric substance associated with the L. ferrooxidans cells on the arsenopyrite surface and bacterial leach pits suggest a direct biological oxidation mechanism, although a combination of indirect and direct bioleaching cannot be ruled out. Although the relative oxidation rates of enargite were greater in the presence of L. ferrooxidans, cells were not in contact with the surface suggesting an indirect biological oxidation mechanism. Cells of L. ferrooxidans appear able to withstand several hundreds of ppm of As(III) and As(V).     

Alkane and PAH biomarkers as tracers of terrigenous organic carbon in Arctic Ocean sediments

We present the first sedimentary biomarker study encompassing the entire Arctic Ocean. A large data set of organic markers for terrigenous, petroleum and combustion inputs [alkanes, hopanes and steranes, parent and alkyl polycyclic aromatic hydrocarbons (PAHs)] is examined for patterns in space and time using principal components analysis (PCA) and partial least squares (PLS). Biomarker patterns reveal the central Arctic Ocean basin sediments to be compositionally distinct from those of the Mackenzie River/Beaufort Sea and Barents Sea, but similar to those of the Laptev Sea. PAH distributions reflected in PAH ratios and PCA projections demonstrate that Arctic Ocean sediment is dominated by natural inputs to the extent that anthropogenic combustion PAHs are not significant. We find only modest changes between the glacial and post-glacial sediments for atmospherically transported hydrocarbon biomarkers, while particle associated biomarkers were captured strongly at basin edges during the glacial period, and much more evenly transported across basins during the post-glacial period. The orders of magnitude decreases in particle associated petrogenic alkanes and PAHs in central basins during glacial times, coupled with the uniformity of most petrogenic biomarker parameters for most basin and shelf locations, reflect a massive reduction in ice transport that makes the margins the most likely source of petrogenic material for the Pleistocene/Holocene central Arctic basins. The proximity of large coal deposits of various maturity levels along the Lena River, the overlap in PAH and biomarker composition of the Laptev Sea and surficial sediments from the central Arctic Ocean and the location of the Laptev Sea at the origin of the main Transpolar Drift all point to eroded coals from the Lena River/Laptev Sea as the likely source of petrogenic hydrocarbons to the central Arctic Ocean. The ubiquitous presence of allochthonous coal in Arctic Ocean surface sediments provides a major constraint on the use of petrogenic biomarkers to infer the presence of subsurface petroleum reserves.