Field Study of Soil Vapor Extraction for Reducing Off-Site Vapor Intrusion

Soil vapor extraction (SVE) is effective for removing volatile organic compound (VOC) mass from the vadose zone and reducing the potential for vapor intrusion (VI) into overlying and surrounding buildings. However, the relationship between residual mass in the subsurface and VI is complex. Through a series of alternating extraction (SVE on) and rebound (SVE off) periods, this field study explored the relationship and aspects of SVE applicable to VI mitigation in a commercial/light-industrial setting. The primary objective was to determine if SVE could provide VI mitigation over a wide area encompassing multiple buildings, city streets, and subsurface utilities and eliminate the need for individual subslab depressurization systems. We determined that SVE effectively mitigates offsite VI by intercepting or diluting contaminant vapors that would otherwise enter buildings through foundation slabs. Data indicate a measurable (5 Pa) influence of SVE on subslab/indoor pressure differential may occur but is not essential for effective VI mitigation. Indoor air quality improvements were evident in buildings 100 to 200 feet away from SVE including those without a measurable reversal of differential pressure across the slab or substantial reductions in subslab VOC concentration. These cases also demonstrated mitigation effects across a four-lane avenue with subsurface utilities. These findings suggest that SVE affects distant VI entry points with little observable impact on differential pressures and without relying on subslab VOC concentration reductions.     

The Challenge of Ground Water Quality Monitoring

"Valuable information pertaining to contaminant sources, contaminants, and ground water quality was derived using the state-supplied data."     

Eruptions of Comet Hale-Bopp at 6.5 AU

The prodigious output of dust and CO observed in comet Hale-Bopp at a heliocentric distance of 6.5 AU is strongly suggestive of high-pressure release of material from liquified subsurface domains rather than thermal evaporation from a sunlit patch of frozen CO. This revised version was published online in July 2006 with corrections to the Cover Date.     

Terrestrial microfossils in Antarctic ordinary chondrites

Abstract— Microfossils have been separated and identified in four high metamorphic grade chondrites from Allan Hills and Queen Alexandra Range, Antarctica. Diatoms and opal phytoliths representing both marine and terrestrial flora were recognized among the dust removed from cracks in all meteorites studied. It is likely that contamination of Antarctic meteorites with such biogenic material is ubiquitous. Standard clean room procedures to avoid laboratory introduction of microfossils into the meteorites were followed, and the genera and species identified so far are characteristic of marine, freshwater, and continental environments. The most probable mechanism for introduction of the microfossils into the meteorites is eolian transport to and on the polar ice cap. It is likely that wind-driven systems may sample atmospherically transported material from large portions of the southern hemisphere. Entrainment of terrestrial microfossils is probably a typical interaction of meteorites with the Antarctic environment and must be recognized and accounted for in any attempt to use Antarctic meteorites as sources of extraterrestrial life forms. Organic molecules derived from microfossils are likely to be pervasive throughout any crack network present in a meteorite at all scales from millimeter to submicron. Cracks are a ubiquitous consequence of weathering in and on the Antarctic ice and the probability that crack surfaces contain terrestrial organic materials is high.     

N2, N2O and O2Profiles in a Tagus Estuary Salt Marsh

Vertical gas profiles of N₂, N₂O and O₂were obtained in intact sediment cores from a Tagus estuary salt marsh using membrane inlet mass spectrometry. This technique allows direct measurements of dissolved gas concentrations with minimal disturbance. O₂concentrations decreased sharply with depth, becoming undetectable below 14mm. Denitrification products (N₂and N₂O) occurred in the surface layer of the sediment where O₂was present. Diffusion of N₂and N₂O from the anaerobic zone, denitrification in anaerobic microsites and aerobic denitrification are possible explanations for this observation. N₂was the sole product of denitrification in control sediment cores probably because of the great demand for electron acceptors in this sediment. The addition of NO₃ ⁻ and CH₃CO₂ ⁻ increased the concentrations of N₂and N₂O in the sediment. Significantly higher concentrations in treated cores occurred between 1·5 and 2·0cm for N₂and between 0·5 and 1·5cm for N₂O. The peak in N₂concentration occurred in the anaerobic zone of the sediment, close to the aerobic–anaerobic interface while the peak in N₂O concentration occurred above this interface where concentrations of O₂were approximately 10μM. This is indicative that, in this sediment, production of N₂O is less sensitive to the presence of O₂than reduction of N₂O to N₂.     

Rock–support interaction analysis based on numerical modelling

The use of yield in supports to control the final loading that develops upon a support system has been one of the most important deformation control techniques used by tunnelling engineers, both historically and currently. Successful use of this approach requires a thorough understanding of the process of rock–support interaction as it is an approach that can fail dramatically if incorrectly applied. There is a fine line between the yield support technique improving the conditions, and the approach resulting in the development of a large area of failed rock, which could ultimately be detrimental. The relationship between the support action and the rock has historically been studied using analytical approaches with the application of significant simplifying assumptions.This paper presents a new approach, where a state-of-the-art numerical model is run repeatedly to develop rock–support interaction curves. This has the advantage of allowing more realistic tunnel geometry, stress states and ground conditions to be simulated. It does, however, use the familiar output form of the relatively simple rock–support interaction curve as opposed to complex and voluminous graphics. Its disadvantage lies in the considerable number of computer runs required to develop the full solutions. Computer software has, however, been written to automate much of this process using a programming language within the modelling package.The analysis approach has been further improved by plotting not one rock–support interaction curve but a whole family of curves representing variations in the rock mass quality of the assumed ground, since this is the most variable of the input parameters for most tunnelling situations. This form of output allows engineers to study the practical range of yield they may require for their rock conditions and also to define at what rock mass quality they can expect the yielding approach to cease to be an effective strategy. This new approach has been presented on a test case history with idealized rock mass properties to illustrate the approach. However, it is an approach that can be specially tailored to any set of rock conditions, tunnel geometry or stress.     

Hurricane Katrina induced nutrient runoff from an agricultural area to coastal waters in Biscayne Bay,Florida

Water quality surveys conducted in Biscayne Bay, Florida, indicated enhanced nutrient input coupled with increased runoff as a result of precipitation associated with Hurricane Katrina. Nutrient concentrations before Katrina ranged from 0.06–24.2 μM (mean 3.3 μM) for nitrate and 0.01–0.18 μM (mean 0.1 μM) for soluble reactive phosphate. Five days after Katrina, nitrate concentrations ranged from 0.87–80.0 μM (mean 17.0 μM), with a bay-wide mean increase of 5.2-fold over pre-hurricane levels. Soluble reactive phosphate concentrations ranged from 0.07–0.62 μM (mean 0.2 μM), with a bay-wide mean increase of 2-fold over pre-hurricane levels. The maximum concentrations for both nitrate and soluble reactive phosphate were found at a water quality monitoring station near the mouth of Mowry Canal, which drains an agricultural area in the southern Biscayne Bay watershed near Homestead, Florida. At this station, nitrate and soluble reactive phosphate concentrations increased 7- and 10-fold, respectively. Storm-induced fertilizer runoff from this agricultural area caused a bay-wide increase in nutrient concentrations after Hurricane Katrina. Nutrient concentrations in the bay returned to pre-hurricane levels within three months after Hurricane Katrina, showing the resiliency of the Biscayne Bay ecosystem.     

Evidence and Implications of Recent Climate Change in Northern Alaska and Other Arctic Regions

The Arctic climate is changing. Permafrost is warming, hydrological processes are changing and biological and social systems are also evolving in response to these changing conditions. Knowing how the structure and function of arctic terrestrial ecosystems are responding to recent and persistent climate change is paramount to understanding the future state of the Earth system and how humans will need to adapt. Our holistic review presents a broad array of evidence that illustrates convincingly; the Arctic is undergoing a system-wide response to an altered climatic state. New extreme and seasonal surface climatic conditions are being experienced, a range of biophysical states and processes influenced by the threshold and phase change of freezing point are being altered, hydrological and biogeochemical cycles are shifting, and more regularly human sub-systems are being affected. Importantly, the patterns, magnitude and mechanisms of change have sometimes been unpredictable or difficult to isolate due to compounding factors. In almost every discipline represented, we show how the biocomplexity of the Arctic system has highlighted and challenged a paucity of integrated scientific knowledge, the lack of sustained observational and experimental time series, and the technical and logistic constraints of researching the Arctic environment. This study supports ongoing efforts to strengthen the interdisciplinarity of arctic system science and improve the coupling of large scale experimental manipulation with sustained time series observations by incorporating and integrating novel technologies, remote sensing and modeling.     

Accuracy of the linearized standard balance and asymmetric balance systems in a shallow-water numerical model

A numerical evaluation of the accuracy of the standard balance equations (BE) and the asymmetric balance equations (AB) in strong vortex applications is presented. Linearized equations for the evolution of disturbances on a symmetric hurricane-like vortex in a shallow-water model are used to compare forecasts using the AB and BE formulations with benchmark primitive equation forecasts. The validity of the BE and AB models is formally determined by the square of the Froude number, F², and the square of the local Rossby number for disturbances with azimuthal wavenumber n, , respectively. The numerical experiments demonstrate that accurate results can be achieved with BE and AB in situations where F² and , respectively, are not necessarily small. When the divergence of the asymmetric disturbance is not much smaller than its vorticity, and the azimuthal wavenumber of the disturbance is low, the AB system proves to be a useful alternative to BE.