Sediment geochemistry of the urban Lake Paulo Gorski

The objective of this study was to evaluate the concentration and distribution of heavy metals in the sediments of Paulo Gorski Lake, as well as the metals’ bioavailability and potential ecological risk, and to define the anthropogenic and natural heavy metal contributions to the lake. The chemical elements calcium (Ca), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), potassium (K), magnesium (Mg), manganese (Mn), sodium (Na), nickel (Ni), lead (Pb), and zinc (Zn) were quantified by flame atomic absorption spectrophotometry with two extraction methods to quantify the bioavailable and non-bioavailable fractions. The data were evaluated using multivariate statistics and sediment quality indices. All sediment collection points (S1, S2, S3, S4 and S5) are different in terms of the concentration of heavy metals, except for S4 and S5, which were statistically equal. The bioavailable fraction of the elements in the sediment follows the sequence Pb>Cu>Mn>Zn>Ni>Cr>phosphorus (P) for all points. The elements Co, Cr, Pb, and Zn showed moderate to considerable contamination at all points. Only points S3 and S5 had moderate ecological risk. Urbanization has been affecting Paulo Gorski Lake via the input of chemical elements, especially Co and Pb. The points most affected by heavy metal contamination are S3 and S5 when the sedimentological sensitivity factor is considered. The lake has high hydrodynamics, causing some of the contaminants that enter the system to leave it, leading to potential negative impacts downstream.     

Inter-annual changes in fish communities of a tropical bay in southeastern Brazil: What can be inferred from anthropogenic activities?

We assessed inter-annual changes in fish assemblages of a tropical bay which experienced a heavily industrialized process in the last decades. A highly significant difference in community structure among the bay zones, and a decrease in fish richness and abundance over time were found. Changes in fish richness and abundance between the two first (1987–1988 and 1993–1995) and the two latter time periods (1998–2001 and 2012–2013) were sharpest in the inner bay zone, the most impacted bay area, and in the middle zone, whereas the outer zone remained comparatively stable over time. These changes coincided with increased metal pollution (mainly, Zn and Cd) in the bay and with the enlargement of the Sepetiba Port. Spatial changes in the fish community structure among the bay zones were related to differences in salinity, transparency and depth with this latter variable acting as a buffer stabilizing temporal community changes.     

Effects of Paracentrotus lividus (Lamark, 1816) harvesting on benthic assemblages. An experimental approach

The effect of harvesting on the diversity and structure of benthic assemblages is nowadays a relevant component of fishery management. Invertebrate harvesting is increasing worldwide and sea urchins are one of the main invertebrate target species. However, current knowledge about the effects of sea urchin harvesting on benthic assemblages is still poor. The aim of this study is to evaluate the influence of Paracentrotus lividus (Lamark, 1816) harvesting on tide pool assemblages from intertidal rocky shores. To achieve this objective, a field removal experiment was done for 10 months. Results of univariate and multivariate analyses showed that P. lividus harvesting had a significant effect on the number of taxa and structure of the benthic assemblage. Assemblages from pools where P. lividus were removed showed significant differences against controls; namely, where P. lividus were eliminated, pools showed higher number of taxa than control pools. This result contrasts with previous studies assessing effects of invertebrate harvesting that generally have found a biodiversity reduction in the exploited habitat. Despite this apparently positive effect of P. lividus harvesting, we should be cautious because effects of P. lividus harvesting on higher trophic levels or during long periods of time remain unexplored.     

First evidence of an interglacial lake of Eemian age in northeast Italy

This paper assesses the age of the Tagliamento Morainic Amphitheatre (northeast Italy), one of the largest morainic bodies in the piedmont area of northern Italy, using new stratigraphical and thermoluminescence (TL) data obtained from a site located on the inner flank of the amphitheatre. Two samples from a 12-m-thick stratum of fluviolacustrine, non-varved, fine sand provided TL ages of approximately 110 ± 16 ka BP. This sandy layer lies below a 6-m-thick, massive (non-laminated), clayey stratum. It is hypothesised that a large but short-lived lake formed during the interglacial phase separating the penultimate and last glaciations. Assigning a ‘Riss’ age to the southeastern part of the amphitheatre therefore regains credence. © 1998 John Wiley & Sons, Ltd.     

Performance-based seismic design of integral abutment bridges

Integral abutment bridges (IAB) are experiencing increasing diffusion in the short to mid-range lengths, where they offer some advantages over traditional girder bridges with non-monolithic connection at the abutments. One challenging problem with their analysis and design is that consideration of the interaction between foundation soil, structure and backfill is unavoidable, also for the deck design. Further, the end of the construction is only one of the conditions that need to be verified during design. Cyclic deformations, such as those occurring during ground shaking, typically lead to an increase in stresses in the abutments and connections, due to progressive compaction (ratcheting) of the backfill soil. This problem is magnified when the bridge is comprised between two embankments, whose response may amplify the input motion and drive the deformation of the bridge. Performance-based design aims at superseding current design procedures by explicitly checking that the target performances set out are achieved, and not overly exceeded. Such a design paradigm naturally calls, on the one hand, for improved accuracy in response determination and more refined analyses, and, on the other, for taking into account the uncertainties entering into the problem by means of an explicitly probabilistic approach. With this objective in mind, the paper presents an inelastic dynamic model for the seismic analysis and design of IABs. The model, that features a balanced compromise between the setup and evaluation effort on one hand, and accuracy on the other, has been developed for implementation in typical commercial analysis packages. It builds on 1D site-response analysis and on inelastic Winkler-like modeling, to reproduce the main physical aspects of the seismic response of IABs. One example application to a highway overpass in Italy illustrates the model and the relevance of a fully probabilistic approach to performance-based design. The application offers also important insight into the choice of an efficient intensity measure for this type of structure.     

A Geophysical Study of the Carcavai Fault Zone, Portugal

The Algarve province is located a few hundred kilometres north of the crossing of the E–W Eurasia–Africa plate boundary in an area of diffuse seismicity and broad deformation. It is characterised by a moderate seismicity, with some important historical and instrumental earthquakes causing loss of lives and significant material damages. The area is affected not only by plate boundary earthquakes but also by moderate to large events generated by local sources. The assessment of onshore local sources is, therefore, of vital importance for an evaluation of the regional seismic hazard. This paper discusses the application of geophysical data to the study of the Carcavai fault zone, an outcropping structure more than 20?km long which is seen to deform sediments of the Plio-Quaternary age. The location of some sectors of the fault zone, as well as the vertical offsets of the structure, are still to be confirmed. In order to estimate these and to study the geometry of the fault zone at depth, geophysical data were acquired together with new geological data. Where the location of the fault was less certain, EM and seismic reflection profiles with coarse spatial sampling were carried out. After the detailed location of the fault zone, seismic reflection profiles with a more dense spatial resolution were acquired. The integrated interpretation of the geological and geophysical data confirmed the presence of a large fault zone. The total fault length is still unknown as its extension offshore is still being studied. Together with estimated values of the throw obtained, this data set has improved understanding the seismic hazard in the area by providing more refined estimates of co-seismic rupture, maximum expected earthquake and return periods.     

Effects of Surface Geology on Seismic Ground Motion Deduced from Ambient-Noise Measurements in the Town of Avellino, Irpinia Region (Italy)

The effects of surface geology on ground motion provide an important tool in seismic hazard studies. It is well known that the presence of soft sediments can cause amplification of the ground motion at the surface, particularly when there is a sharp impedance contrast at shallow depth. The town of Avellino is located in an area characterised by high seismicity in Italy, about 30?km from the epicentre of the 23 November 1980, Irpinia earthquake (M?=?6.9). No earthquake recordings are available in the area. The local geology is characterised by strong heterogeneity, with impedance contrasts at depth. We present the results from seismic noise measurements carried out in the urban area of Avellino to evaluate the effects of local geology on the seismic ground motion. We computed the horizontal-to-vertical (H/V) noise spectral ratios at 16 selected sites in this urban area for which drilling data are available within the first 40?m of depth. A Rayleigh wave inversion technique using the peak frequencies of the noise H/V spectral ratios is then presented for estimating Vs models, assuming that the thicknesses of the shallow soil layers are known. The results show a good correspondence between experimental and theoretical peak frequencies, which are interpreted in terms of sediment resonance. For one site, which is characterised by a broad peak in the horizontal-to-vertical spectral-ratio curve, simple one-dimensional modelling is not representative of the resonance effects. Consistent variations in peak amplitudes are seen among the sites. A site classification based on shear-wave velocity characteristics, in terms of Vs30, cannot explain these data. The differences observed are better correlated to the impedance contrast between the sediments and basement. A more detailed investigation of the physical parameters of the subsoil structure, together with earthquake data, are desirable for future research, to confirm these data in terms of site response.     

Origin of the color in cobalt-doped quartz

Synthetic Co-doped quartz was grown hydrothermally in steel autoclaves at the Technological Center of Minas Gerais (CETEC), Brazil. The quartz samples, originally yellow in the as-grown state acquired blue coloration after prolonged heat treatment times at 500°C near the alpha–beta transition temperature. UV–VIS–NIR absorption spectroscopy shows the characteristic spectra of Co³⁺ before heat treatment. After heat treatment, the optical absorption spectrum is dominated by two split-triplet bands the first in the near infrared region centered at about 6,700 cm⁻¹ (1,490 nm) and the second in the visible spectral range at about 16,900 cm⁻¹ (590 nm). Both split-triplet bands are typical for Co²⁺ ions in tetrahedral coordination environments. From the absence of electron paramagnetic resonance (EPR) spectra, we conclude that the Co²⁺ found in the optical absorption spectra of the blue quartz is not due to an isolated structural site in the quartz lattice. Instead, the blue color is associated with electronic transitions of Co²⁺ in small inclusions in which the Co site has tetrahedral symmetry. The non-observation of polarization-depend optical absorption spectra is also in agreement with this model. The results for Co²⁺ in quartz are different from Co-bearing spinel and staurolite and other silicates like orthopyroxene, olivine, and beryls. The formation process of the color center is discussed.     

The Simulation of the Opposing Fluxes of Latent Heat and CO<Subscript>2</Subscript> over Various Land-Use Types: Coupling a Gas Exchange Model to a Mesoscale Atmospheric Model

A mesoscale meteorological model (FOOT3DK) is coupled with a gas exchange model to simulate surface fluxes of CO₂ and H₂O under field conditions. The gas exchange model consists of a C3 single leaf photosynthesis sub-model and an extended big leaf (sun/shade) sub-model that divides the canopy into sunlit and shaded fractions. Simulated CO₂ fluxes of the stand-alone version of the gas exchange model correspond well to eddy-covariance measurements at a test site in a rural area in the west of Germany. The coupled FOOT3DK/gas exchange model is validated for the diurnal cycle at singular grid points, and delivers realistic fluxes with respect to their order of magnitude and to the general daily course. Compared to the Jarvis-based big leaf scheme, simulations of latent heat fluxes with a photosynthesis-based scheme for stomatal conductance are more realistic. As expected, flux averages are strongly influenced by the underlying land cover. While the simulated net ecosystem exchange is highly correlated with leaf area index, this correlation is much weaker for the latent heat flux. Photosynthetic CO₂ uptake is associated with transpirational water loss via the stomata, and the resulting opposing surface fluxes of CO₂ and H₂O are reproduced with the model approach. Over vegetated surfaces it is shown that the coupling of a photosynthesis-based gas exchange model with the land-surface scheme of a mesoscale model results in more realistic simulated latent heat fluxes.