Occurrence and conceptual sedimentary model of Cambrian gypsum-bearing evaporites in the Sichuan Basin,SW China

During the Cambrian, gypsum-bearing evaporites formed in the Sichuan Basin, SW China. These rocks are important for oil and gas sealing, but details of their distribution and origin are not well established. This study examines the regional distribution and origin of the gypsum-bearing evaporites using a comprehensive analysis of drilling data from 34 wells, 5 measured cross-sections in the basin and surrounding area, and 96 maps of area-survey data. Results show that in the stratigraphic succession, the gypsum-bearing evaporites occur mainly in the Lower Cambrian Longwangmiao Formation, the Middle Cambrian Douposi Formation, and the Middle-Upper Cambrian Xixiangchi Group. Geographically, the rocks are found mainly in the southeastern part of the basin, and the distribution of deposits shows an overall SW-NE trend. The sedimentary environments for evaporite formation were evaporative lagoon and inter-platform basin in a platform setting. Gypsum was generated by the underwater concentration of sea water in a strongly evaporative environment. Both an evaporative restricted platform and a mixeddeposition restricted platform model appear to be applicable to the development of gypsum in the Sichuan Basin. The gypsum-bearing evaporites with the best sealing capacity are located mostly in the southeastern part of the basin. These constraints can be applied directly to regional exploration, and have implications for the regional paleogeography and paleoclimate.     

The Fragmentation in a Protoplanetary Disk and the Properties of the Resultant Self-Gravitating Clumps

We study the fragmentation properties in the protoplanetary disk and properties of the resultant self-gravitating clumps using our newly constructed disk model. Our disk model includes the mass inflall term from a molecular cloud core and the photoevaporation winds effect. We adopt the conventional fragmentation criterion to judge whether a protoplanetary disk can fragment. In this work, we follow our previous work to investigate the properties of the resultant self-gravitating clumps. In our calculation, the initial masses of the resultant self-gravitating clumps lie in the range of tens of M_J to more than one hundred of M_J, where M_J is the Jupiter mass. These initial masses can seemingly account for the masses of extrasolar planets in magnitude. We also calculate the subsequent gas accretion of clumps in 1.27 × 10⁴ yr after the formation of self-gravitating clumps. We find that the subsequent gas accretion of self-gravitating clumps is very efficient, and the clump masses grow to hundreds of M_J and the physical radii R_c of clumps increase to about 10 AU. Additionally, we also calculate the orbital migration of clumps. We find that most clumps have short migration timescale to be accreted onto the protostar, and only a small fraction of clumps have long migration timescale (>10⁶ yr) to successfully become gas giant planets. These results are consistent with previous studies.     

Ensemble clustering for efficient robust optimization of naturally fractured reservoirs

In the development of naturally fractured reservoirs (NFRs), the existence of natural fractures induces severe fingering and breakthrough. To manage the flooding process and improve the ultimate recovery, we propose a numerical workflow to generate optimal production schedules for smart wells, in which the inflow control valve (ICV) settings can be controlled individually. To properly consider the uncertainty introduced by randomly distributed natural fractures, the robust optimization would require a large ensemble size and it would be computationally demanding. In this work, a hierarchical clustering method is proposed to select representative models for the robust optimization in order to avoid redundant simulation runs and improve the efficiency of the robust optimization. By reducing the full ensemble of models into a small subset ensemble, the efficiency of the robust optimization algorithm is significantly improved. The robust optimization is performed using the StoSAG scheme to find the optimal well controls that maximize the net-present-value (NPV) of the NFR’s development. Due to the discrete property of a natural fracture field, traditional feature extraction methods such as model-parameter-based clustering may not be directly applicable. Therefore, two different kinds of clustering-based optimization methods, a state-based (e.g., s _w profiles) clustering and a response-based (e.g., production rates) clustering, are proposed and compared. The computational results show that the robust clustering optimization could increase the computational efficiency significantly without sacrificing much expected NPV of the robust optimization. Moreover, the performance of different clustering algorithms varies widely in correspondence to different selections of clustering features. By properly extracting model features, the clustered subset could adequately represent the uncertainty of the full ensemble.     

The Middle Triassic evolution of the Bangong–Nujiang Tethyan Ocean: evidence from analyses of OIB-type basalts and OIB-derived phonolites in northern Tibet

International Journal of Earth Sciences - In this paper, we present new major and trace element chemical data for the basalts and phonolites of the Nare ocean island fragment (NaOI), as well as...     

Tectonic significance of Triassic mafic rocks in the June Complex,Sanandaj–Sirjan zone,Iran

This study concentrates on the petrological and geochemical investigation of mafic rocks embedded within the voluminous Triassic June Complex of the central Sanandaj–Sirjan zone (Iran), which are crucial to reconstruct the geodynamics of the Neotethyan passive margin. The Triassic mafic rocks are alkaline to sub-alkaline basalts, containing 43.36–49.09 wt% SiO₂, 5.19–20.61 wt% MgO and 0.66–4.59 wt% total alkalis. Based on MgO concentrations, the mafic rocks fall into two groups: cumulates (Mg# = 51.61–58.94) and isotropic basaltic liquids (Mg# = 24.54–42.66). In all samples, the chondrite-normalized REE patterns show enrichment of light REEs with variable (La/Yb)_N ratios ranging from 2.48 to 9.00, which confirm their amalgamated OIB-like and E-MORB-like signatures. Enrichment in large-ion lithophile elements and depletion in high field strength elements (HFSE) relative to the primitive mantle further support this interpretation. No samples point to crustal contamination, all having undergone fractionation of olivine + clinopyroxene + plagioclase. Nevertheless, elemental data suggest that the substantial variations in (La/Sm)_PM and Zr/Nb ratios can be explained by variable degrees of partial melting rather than fractional crystallization from a common parental magma. The high (Nb/Yb)_PM ratio in the alkaline mafic rocks points to the mixing of magmas from enriched and depleted mantle sources. Abundant OIB alkaline basalts and rare E-MORB appear to be linked to the drifting stage on the northern passive margin of the Neotethys Ocean.     

Comparative study for environmental performances of traditional manufacturing and directed energy deposition processes

Additive manufacturing is considered more sustainable than traditional manufacturing due to its efficient energy and materials usage. However, previous literature indicates that this suggestion is applicable only for the polymer materials, and the environmental issues of additive manufacturing with metallic materials are still not clear. With the method of life cycle assessment, this paper analyzes and compares the energy consumptions and environmental impacts of direct energy deposition and traditional machining processes for a typical metal part. Further, the article attempts to identify the significant issues in the two manufacturing options that contribute most to the environmental impacts. Six environmental impacts were assessed in this study: global warming potential (GWP); acidification potential (AP); eutrophication potential; ozone depletion potential (ODP); photochemical ozone creation potential (POCP); and abiotic depletion potential (ADP). The results show that the gear laser fabrication process consumes more energy and releases more negative emissions compared with traditional gear manufacturing processes. The results of GWP, AP, ODP, ADP and POCP of the traditional gear manufacturing are only 30.33, 43.42, 17, 65.05 and 54.68% of the gear laser fabrication.     

Photodegradation of dimethyl phthalate (DMP) by UV–TiO<Subscript>2</Subscript> in aqueous solution: operational parameters and kinetic analysis

In this paper, the adsorption and degradation phenomenon involved in the photocatalytic degradation of dimethyl phthalates (DMPs) by titanium dioxide (TiO₂) was studied. A variety of operating variables were selected firstly. Then, it was proved that even for such weak adsorption properties molecules as DMP, adsorption was still an important prerequisite for photolysis. A surface-mediated reaction process was proposed that the photodegradation of DMP assisted by TiO₂ particles occurred primarily at the surface of the photocatalyst rather than in the homogeneous phase. According to Langmuir–Hinshelwood model, the adsorption constant determined from the dark adsorption was far less than that obtained in the light condition. Enhanced DMP adsorption on the surface of TiO₂ under irradiation was the possible reason for the improvement of photodegradation efficiency. Under the irradiation of light, a synergistic mechanism of adsorption and photocatalysis was responsible for DMP degradation. The quantitative analysis by adding scavengers indicated that ^·OH radical was primarily responsible for the photodegradation of DMP. It was further verified that ^·OH was produced much more from conduction band electrons rather than valance band holes toward photodegradation of DMP by adding foreign Cu²⁺.     

Up-to-date urban rainstorm intensity formulas considering spatial diversity in China

With accelerating urbanization in China, urban waterlogging has had a serious impact on urban sustainable development and citizen welfare. Simple urban rainstorm intensity formulas with a monotonous frequency distribution type cannot meet the practical needs of urban drainage planning and design. This study focuses on the development of urban rainstorm intensity formulas based on spatial diversity in China. Using the annual maximum sampling method, rainstorm data of 607 cities throughout China were collected into a database, with a total of 24,933 rainfall samples (annual observations) under various specified precipitation durations. The database was used to verify that integrating the Pearson III and Gumbel distributions would constitute an optimal theoretical distribution type, owing to its small error and increased fitting precision. Modification and coordination of four important parameters in the rainstorm intensity formula were done using a digital elevation model, which improved the accuracy of the formula. In addition, precipitation distributions in China were treated from the perspective of topographic features to validate the calculations from up-to-date formulas. Accuracy assessment was accomplished using a national code (GB-50014-2006), GIS-based isograms, and authoritative results from the Hydrological Bureau of the Ministry of Water Resources. This work provides a comprehensive foundation for the establishment of an up-to-date rainstorm intensity formula for China, which can be used widely in different cities.     

Satellite altimetry for measuring river stages in remote regions

The advent in satellite altimetry with the most accurate satellite radar altimeter since 1992 and its successive missions have enabled the routine global monitoring of water-level (or stage) for surface waters and changes in the quantities of dammed water reservoirs. However, satellite altimeter measurements typically have spatial resolution capable of observing only large water bodies, such as major lakes and rivers. This paper addresses the challenges of how to investigate water levels in medium (~?1 km in width) to small (~?100 m and narrower) rivers. Comparisons between the ENVISAT altimetry ICE-1 waveform retracking height and standard water-level measurements for multiple sections of Ohio River, Columbia River, and Red River of the North in the United States (US) reveals that the satellite altimetry measured water levels agree well with those observed at nearby US Geological Survey gaging stations over the 10-year period starting from 2002. The significant results include those obtained at Thompson, North Dakota (ND, correlation coefficient or R value of 0.76 between satellite and in situ water-level measurements) and Fargo, ND (R?=?0.74), where the stream channels of Red River are merely?~?50 m and ~?40 m wide, respectively, under normal climatic conditions. In addition, demonstrations of the approach over largely inaccessible portions of Tigris–Euphrates Rivers and Helmand River in the Middle East aided in understanding hydrology in these systems. This study demonstrates the ability of satellite radar altimetry to characterize rivers in these study regions which are much narrower than 100 m in width.     

Preparation of integrative cubes as a novel biological permeable reactive barrier medium for the enhancement of in situ aerobic bioremediation of nitrobenzene-contaminated groundwater

Recent studies have indicated that in situ aerobic bioremediation is one of the most effective methods for remediating groundwater contaminated with nitrobenzene (NB). Aerobic bioremediation is largely dependent on the maintenance of adequate dissolved oxygen (DO) levels in the groundwater. Traditional in situ aeration has various disadvantages, such as high operational costs and nonuniform aeration. In this study, integrative cubes were prepared and utilized as a novel biological permeable reactive barrier (bio-PRB) medium to enhance the aerobic bioremediation of NB-contaminated groundwater. The results revealed an NB removal rate greater than 98.68% after 15–20 days of continuous oxygen release from the bio-PRB medium. DO concentrations reached 8.0 mg/L during treatment, and NB-degrading bacteria were able to tolerate a range of pH conditions. This multifaceted bio-PRB medium can simultaneously adsorb and biodegrade NB, release oxygen, and neutralize the pH with phosphate buffer. The results of this study suggest that this bio-PRB medium represents a highly effective in situ bioremediation method for NB-contaminated groundwater.