硫化物风化产酸对流域岩石风化和碳循环的影响——以黄河支流三川河流域为例

硫化物风化产酸可加速岩溶作用但抑制大气二氧化碳参与流域碳循环,其复杂的地球化学机制和过程待阐明。本文以黄河二级支流三川河流域为例,通过采集20个三川河及其支流地表水点样和30个柳林泉地下水点样,经实验测试获得了流域比较系统的水化学资料和δ¹³C、δ³⁴ S数据,运用碳、硫同位素分析与水化学平衡计量方法,量化了流域硫化物风化产酸对岩石风化作用的贡献以及对碳循环的影响。计算结果表明：煤系地层硫化物和矿床硫化物的氧化及大气酸沉降所形成的硫酸明显促进了流域碳酸盐岩的溶蚀,对碳酸盐岩溶蚀的贡献约占64.59%;柳林泉水石膏溶解来源的SO₄^2-占69%,河水中石膏溶解来源的SO₄^2-占30%,但这些部分SO₄^2-没有参与溶蚀作用,应当扣除;三川河流域平均岩石风化速率为10.02 mm/ka,其中碳酸盐岩、硅酸盐岩的风化速率分别为9.14 mm/ka和0.88 mm/ka,低于国内外很多流域;由于硫酸抵消了碳酸盐岩石风化作用对大气二氧化碳的吸收,流域岩石风化消耗大气/土壤CO₂通量为116.58 mmol/（km² ·a）,不足珠江流域的1/5,且硅酸盐岩风化的贡献占63.3%。

     

鄂尔多斯盆地南部延长组富铀凝灰岩地球化学特征及形成机制

本文系统地研究了鄂尔多斯盆地南部延长组凝灰岩元素和同位素地球化学特征。结果表明：凝灰岩主量元素具有高K、高Al、Si中等至高、低Na的特征; REE总体特征为轻稀土富集、重稀土亏损,∑REE在4857～40212 μg/g 之间变化,Eu呈现出负异常,在034～082内变化,δCe范围在080～208之间; 微量元素中U含量在312～144 μg/g 之间,Ba、U、Th、Hf和Ce呈明显正异常,Nb、P、Ti和Rb呈现负异常。详细的分析表明：U的富集和一些微量元素如Ta、Dy、Lu等相关,Th与∑REE存在明显的正相关性,这些变化可能和盆地中铀矿的富集有关; 凝灰岩的硫同位素总体呈现深源特征。根据以上的研究对凝灰岩的形成原因及形成环境进行了探讨。鄂尔多斯盆地南部延长组凝灰岩来源于秦岭造山带火山作用,其中的铀元素富集是由于砂岩型铀矿中铀向凝灰岩迁移而被还原所致。本研究对盆地砂岩型铀矿的铀运移和富集机理认识具有一定指导意义。     

Effects of nitrate on nitrite toxicity to Microcystis aeruginosa

The aim of this study was to investigate the effect of nitrate on nitrite toxicity to Microcystis aeruginosa. Short-term uptake experiment revealed nitrate could depress the nitrite active uptake. The long-term experiment of nitrate effects on nitrite toxicity showed a negative relationship between the growth and intracellular nitrite levels of M. aeruginosa. The net nitrite uptake displayed a decline in the range of 0-150 mg NO(3)(-)-NL(-1) and an elevation at 200mg NO(3)(-)-NL(-1), whereas the activities of nitrate reductase (NR) were more sensitive to nitrate than nitrite reductase (NiR). As a result, the total intracellular nitrite levels tended to decrease up to 100 mg NO(3)(-)-NL(-1) then increased at 150-200 mg NO(3)(-)-NL(-1). These results suggested the existence of external nitrate could affect the toxicity of nitrite to alga through changing intracellular nitrite content.     

Impacts of Climatic Factors on Runoff Coefficients in Source Regions of the Huanghe River

Runoff coefficients of the source regions of the Huanghe River in 1956–2000 were analyzed in this paper. In the 1990s runoff of Tangnaihai Hydrologic Station of the Huanghe River experienced a serious decrease, which had at- tracted considerable attention. Climate changes have important impact on the water resources availability. From the view of water cycling, runoff coefficients are important indexes of water resources in a particular catchment. Kalinin baseflow separation technique was improved based on the characteristics of precipitation and streamflow. After the separation of runoff coefficient (R/P), baseflow coefficient (Br/P) and direct runoff coefficient (Dr/P) were estimated. Statistic analyses were applied to assessing the impact of precipitation and temperature on runoff coefficients (including Dr/P, Br/P and R/P). The results show that in the source regions of the Huanghe River, mean annual baseflow coefficient was higher than mean annual direct runoff coefficient. Annual runoff coefficients were in direct proportion to annual pre- cipitation and in inverse proportion to annual mean temperature. The decrease of runoff coefficients in the 1990s was closely related to the decrease in precipitation and increase in temperature in the same period. Over different sub-basins of the source regions of the Huanghe River, runoff coefficients responded differently to precipitation and temperature. In the area above Jimai Hydrologic Station where annual mean temperature is –3.9oC, temperature is the main factor in- fluencing the runoff coefficients. Runoff coefficients were in inverse relation to temperature, and precipitation had nearly no impact on runoff coefficients. In subbasin between Jimai and Maqu Hydrologic Station Dr/P was mainly affected by precipitation while R/P and Br/P were both significantly influenced by precipitation and temperature. In the area be-tween Maqu and Tangnaihai hydrologic stations all the three runoff coefficients increased with the rising of annual precipitation, while direct runoff coefficient was inversely proportional to temperature. In the source regions of the Huanghe River with the increase of average annual temperature, the impacts of temperature on runoff coefficients be-come insignificant.     

美国南极科研投入的统计分析及其对我国的启示

近些年来南极科研越来越受到世界各国的重视,作为《南极条约》的发起者和南极条约体系的管理者,美国始终站在南极科学研究前沿,对维护其国际南极事务领导地位有着重要意义。1953—2016年美国国家科学基金资助了7 759个南极科研项目,通过统计分析对项目投入进行以下4个方面的分析:南极项目投入、南极科研各学科投入、科研大项目以及合作机构。研究发现:(1)1953年至今,美国国家科学基金会(NSF)对美国南极科研项目的资助力度和重视力度不断增加,促进了美国南极政策的落实和发展;(2)美国各大科学指导机构出台的前瞻性文件对引领美国南极科考发展方向起到重要作用;(3)NSF充分利用各高等院校和研究机构的资源设施,搭建科研支撑平台,与之展开长期南极科研项目合作;(4)NSF重视科研大项目的开展,这些大项目站在南极科学前沿,引领美国南极科研更好地发展;(5)NSF通过学校、社会、媒体多个渠道开展南极教育,增进群众对南极了解并培养科研人员来维护美国在南极的科考领先地位。上述研究发现为中国南极科研政策制定提供了相应的启示。     

腾格里沙漠地区水化学特征

水资源极为匮乏的腾格里沙漠区内所赋存的水主要有两种类型。一种是沙下潜水 ,主要是周边山区由高向低缓慢地向沙漠区运移所致 ,分布较为普遍 ;另一种是沙漠湖水 ,它是在沙漠区内之低洼地段 ,由于沙下潜水的长期溢出汇集于大小不等的长条状湖泊之中 ,以湖表水 (咸水和卤水 )的形式存在。沙下潜水矿化度在 0 .5～ 1 g/L之间 ,为本区的饮用水。湖表水咸苦 ,矿化度较高 ,就同一湖区而言 ,也有咸水和卤水之分 ,咸水矿化度为每升数十克 ,卤水则在 1 0 0～ 440 g/L之间 ,已达到了盐湖类沉积阶段     

松潘地区岩金统计成矿予测中泛克立格法的应用

川西北地区是国内重要的岩金普查靶区。本文对松潘地区的地质特征,泛克立格法原理,及在本区的应用情况作了介绍,对主要计算步骤,给出基本结果,对计算获得的有意义异常区,进行地质解释,并将此方法与趋势面分析进行对比。     

汉江上游郧县段黄土古土壤序列风化成壤特征以及成壤环境演变

对汉江上游进行野外实地详细调查,在湖北省郧县尚家河台地前沿发现了典型的全新世黄土-古土壤沉积剖面,通过粒度、磁化率、吸湿水和烧失量分析表明,黏粒、细粉砂、磁化率、吸湿水和烧失量在古土壤层S₀出现高值,在L₁、L_t、L₀为低值;而粗粉砂、细砂粒和粗砂粒在S₀为低值,在L₁、L_t、L₀为高值。这些指标的变化说明了全新世以来的气候和成壤环境的变化特征,即在古土壤S₀形成时期,气候温暖湿润,成壤作用非常强烈;黄土堆积时期气候相对干旱,成壤作用较弱。     

生物土壤结皮对一年生植物影响研究进展

生物土壤结皮在荒漠地区广泛分布,它的形成和演替深刻地改变了土壤表层的结构特征和理化性质,进而影响了荒漠地区一年生植物的种子传播、萌发、幼苗存活及生长过程。本文回顾了国内外有关生物土壤结皮对一年生植物影响的研究,综述了生物土壤结皮对一年生植物的土壤种子库、种子萌发、幼苗存活及生长过程的影响,分析了各研究结论中存在争议的原因,总结了生物土壤结皮对一年生植物种子传播、萌发、幼苗存活及生长影响的内在机理,指出了生物土壤结皮对荒漠地区植被组成的筛选作用,并对进一步的研究进行了展望。