Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

论γ射线的点放射源和非点放射源的辐射研究

本文讨论点放射源和非点放射源的辐射，为简化理论模型，暂不考虑二次γ射线，只讨论点源和线源和柱状源的辐射，本文的讨论有助于工业ＣＴ的设计及系统的优化。     

影响CT球管寿命的非质量因素

影响ＣＴ球管寿命的非质量因素是指对其使用寿命的长短产生影响的因素。笔者通过对多年工作实践的总结，从操作技术、维修保养等方面探讨诸因素对ＣＴ球管寿命的影响。     

草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

扬子地台钾镁煌斑岩 Nd、Sr、Pb 同位素特征

扬子地台周缘钾镁煌斑岩 Nd、Sr同位素特征介于南非Ⅰ、Ⅱ型金伯利岩和西澳与北美钾镁煌斑岩两种变化趋势之间，不同岩区间同位素组成差异反映地台周边构造性质不同，Pb同位素特征表明晚太古代地幔岩石圈具U亏损特征。     

Sr isotope evolution during chemical weathering of granites —Impact of relative weathering rates of minerals

The Sr isotopic systematics in the weathering profiles of biotite granite and granite porphyry in southern Jiangxi Province were investigated. The results showed that during the chemical weathering of granites, remarked fractionation occurred between Rb and Sr. During the early stages of chemical weathering of granites, the released Sr/Si and Sr/Ca ratios are larger than those of the parent rocks, and the leaching rate of Sr is higher than those of Si, Ca, K, Rb, etc. Dynamic variations in relative weathering rates of the main Sr-contributing minerals led to fluctuation with time in⁸⁷Sr/⁸⁶Sr ratios of inherent and released Sr in the weathering crust of granite. Successive weathering of biotite, plagioclase and K-feldspar made⁸⁷Sr/⁸⁶Sr ratios in the weathering residues show such a fluctuation trend as to decrease first, increase, and then decrease again till they maintain stable. This work further indicates that when Sr isotopes are used to trace biogeochemical processes on both the catchment and global scales, one must seriously take account of the preferential release of Sr from dissolving solid phase and the fluctuation of⁸⁷Sr/⁸⁶Sr ratios caused by the variations of relative weathering rates of Sr-contributing minerals.     

Typical basin-fill sequences and basin migration in Yanshan, North China--Response to Mesozoic tectonic transition

Basin-fill sequences of Mesozoic typical basins in the Yanshan area, North China may be divided into four phases, reflecting lithosphere tectonic evolution from flexure (T3), flexure with weak rifting (J1+2), tectonic transition (J3), and rifting (K). Except the first phase, the other three phases all start with lava and volcaniclastic rocks, and end with thick coarse clastic rocks and/or conglomerates, showing cyclic basin development rather than simple cyclic rift mechanism and disciplinary basin-stress change from extension to compression in each phase. Prototype basin analysis, based on basin-fill sequences, paleocurrent distribution and depositional systems, shows that single basin-strike and structural-line direction controlling basin development had evidently changed from east-west to northeast in Late Jurassic in the Yanshan area, although basin group still occurred in east-west zonal distribution. Till Early Cretaceous, main structural-line strike controlling basins just turned to northeast by north in the studied area.     

遂川—热水走滑断裂带特征及其对丰州盆地铀成矿的控制作用

本文以322矿田为例,对穿越矿田的遂川-热水走滑断裂带的特征及其对铀成矿的控制予以讨论。论述了矿田内铀矿床的形成、分布与遂川-热水走滑断裂带的关系,揭示了丰州拉分盆地的形成与铀成矿的内在联系,认为遂川-热水走滑断裂系是322矿田的主控条件,走滑断裂的脉动性控制了铀成矿的多期多阶段性。最后简要地分析了322矿田的找矿前景和走滑断裂的找矿意义。     

瞬态瑞雷面波在压密注浆地基处理效果评价中的应用

目前,压密注浆处理软弱地基的质量检测方法以载荷板试验、标贯、轻便触探和静力触探为主,上述方法虽然精度较高但是难以用来进行普测.近期我们将瞬态瑞雷面波技术应用某工程压密注浆地基加固处理效果评价之中,取得了一定效果.