Comparative organic petrology of interlayered sandstones,siltstones, mudstones and coals in the Upper Carboniferous Ruhr basin,Northwest Germany,and their thermal history and methane generation

In the coal-mining Ruhr-area, Upper Carboniferous rocks (ca. 4000 m) consist of interlayered sandstones, siltstones, mudstones and coals. They were deposited in a tropical, paralic environment where alternating fluvial sedimentation, occasional marine ingressions, and swamp growth resulted in an irregular cyclic succession. The total sedimentary package contains on an average 6 Vol.-% of organic matter. About 70 Vol.-% of the organic matter occurs in coal seams, the rest as dispersed organic matter in clastic rocks. The organic matter is autochthonous in the coals and allochthonous in associated sandstones and siltstones. It consists of about 70% vitrinite, 20% inertinite, and 10% liptinite. The overall maceral group composition is the same for coals and dispersed organic matter. This surprising similarity is caused by a nearly exclusive input of land-plant derived organic matter to swamps and fluvial systems and a similar degree of preservation. Highest average liptinite contents (% of total macerals) were found in unrooted mudstones, highest average inertinite contents in coarse-grained siltstones and highest average vitrinite percentages in sandstones.Maturities of the sediments studied are well within the hydrocarbon generation window, e. g. vitrinite reflectivities range from 0.6% to 1.6%. Reflectivities measured on dispersed particles in clastic rocks are similar to those measured in coal seams. Calculations of the amount of methane generated indicate that coal seams contributed more to the total hydrocarbon generation than dispersed organic matter.

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Zusammenfassung Das Oberkarbon des Ruhrgebietes besteht aus ca. 4000 Metern wechsellagernder Sandsteine, Siltsteine und Kohleflöze. Der Ablagerungsraum der Sedimente war eine Region mit tropischem Klima, genauer ein paralisches Environment mit unregelmäßig alternierenden Folgen von fluviatilen Sedimenten, marinen Transgressionen und verbreiteten Sumpfablagerungen. Der Anteil organischer Substanzen an der gesamten Sedimentmenge beträgt durchschnittlich 6%. 70% dieser organischen Masse ist in Kohleflözen angereichert, der Rest liegt verteilt in den klastischen Gesteinen vor. Die Herkunft der organischen Substanz in den Kohleflözen ist autochthon, die in den benachbarten Sand- und Siltsteinen allochton. Die Zusammensetzung des organischen Materials ist 70% Vitrinit, 20% Inertinit und 10% Liptinit. Die allgemeine Zusammensetzung nach Mazeral-Gruppen ist für die Kohleflöze und das verteilte Material in den Nachbargesteinen identisch. Diese Ähnlichkeit beruht auf der gemeinsamen Herkunft der organischen Substanz in Sümpfen und Flußsystemen, die fast ausschließlich von Landpflanzen bestimmt wird, und einer sich entsprechenden Konservierung.Der Reifegrad der analysierten Sedimente liegt innerhalb des Kohlenwasserstoff-Bildungsbereiches (die Vitrinit-Reflexionen reichen von 0,6–1,6%). Dabei entsprechen die in den klastischen Gesteinen beobachteten Reflexionswerte weitgehend denen der Kohleflöze. Anhand der Menge des erzeugten Methans läßt sich erkennen, daß der Anteil der Kohleflöze an der Kohlenwasserstoff-Produktion höher ist als der Anteil, den disperse organische Substanzen der Klastika beisteuern.

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Résumé Dans la région minière de la Ruhr, le Carbonifère supérieur constitue une succession, épaisse de 4.000 m environ, de grès, de siltites et de charbon. Leur dépôt, dans un milieu paralique tropical, a été marqué par des alternances de sédimentation fluiviale, de transgressions marines occasionnelles, et d'épisodes marécageux; il en résulte une disposition cyclique irrégulière. La série sédimentaire contient dans l'ensemble 6% de matière organique en moyenne. Environ 70% de cette matière organique se trouve dans les couches de charbon où elle est autochtone; le reste est allochtone et dispersé dans les grès et siltites. La matière organique se répartit approximativement en 70% de vitrinite, 20% d'inertinite et 10% de liptinite. La composition moyenne du groupe «macéral» est la même pour les charbons et la matière organique dispersée. Cette identité surprenante est l'expression d'une alimentation provenant exclusivement de plantes terrestres et d'un même degré de conservation.La maturité des sédiments étudiés se situe à l'intérieur du domaine de genèse des hydrocarbures: le pouvoir réflecteur de la vitrinite s'échelonne entre 0,6% et 1,6%. Les gradients du pouvoir réflecteur observés dans les roches détritiques et dans les couches de charbon sont analogues. Le calcul de la quantité de méthane engendré indique que la contribution des couches de charbon à la production totale d'hydrocarbure est supérieur à celle de la matière organique dispersée.

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Integrated 3D forward stratigraphic and petroleum system modeling of the Levant Basin,Eastern Mediterranean

The Eastern Mediterranean Levant Basin is a proven hydrocarbon province with recent major gas discoveries. To date, no exploration wells targeted its northern part, in particular the Lebanese offshore. The present study assesses the tectono‐stratigraphic evolution and related petroleum systems of the northern Levant Basin via an integrated approach that combines stratigraphic forward modeling and petroleum systems/basin modeling based on the previous published work. Stratigraphic modeling results provide a best‐fit realisation of the basin‐scale sedimentary filling, from the post‐rift Upper Jurassic until the Pliocene. Simulation results suggest dominant eastern marginal and Arabian Plate sources for Cenozoic siliciclastic sediments and a significant contribution from the southern Nilotic source mostly from Lower Oligocene to Lower Miocene. Basin modeling results suggest the presence of a working thermogenic petroleum system with mature source rocks localised in the deeper offshore. The generated hydrocarbons migrated through the deep basin within Jurassic and Cretaceous permeable layers towards the Latakia Ridge in the north and the Levant margin and offshore topographic highs. Furthermore, the basin model indicates a possibly significant influence of salt deposition during Messinian salinity crisis on formation fluids. Ultimately, the proposed integrated workflow provides a powerful tool for the assessment of petroleum systems in underexplored areas.     

Composition of organic matter in subducted and unsubducted sediments off the Nicoya peninsula, Costa Rica (ODP Leg 170, Sites 1039 and 1040)

Investigation of sediment samples from Sites 1039 and 1040 (ODP Leg 170) drilled off the Nicoya peninsula (Costa Rica) by organic geochemical and organic petrological methods has revealed that subduction has only little influence on the composition of the sedimentary organic matter. Organic carbon contents reached 1.5% in the Pleistocene samples but Miocene and Pliocene sediments had an average organic carbon content of less than 0.5%. Organic carbon/sulfur ratios are generally below 2.8, reflecting an intense sulfate reduction in the uppermost sediments which was enhanced by sulfate supply both from sea water and deeper strata. Microscopical examinations indicate that the organic matter is mainly derived from marine sources. A small amount of terrigenous organic matter is, however, present as well according to n-alkane and fatty acid distributions. The alkenone unsaturation index U₃₇^k′ shows only a slight decrease during the Miocene and Pliocene, and stronger variations in the Pleistocene, probably indicating more stable sea surface temperatures during the Miocene and Pliocene. Variations in the Pleistocene can possibly be related to glacial/interglacial changes.     

An overview on source rocks and the petroleum system of the central Upper Rhine Graben

International Journal of Earth Sciences - The petroleum system of the Upper Rhine Graben (URG) comprises multiple reservoir rocks and four major oil families, which are represented by four distinct...     

Numerical simulation of the thermal maturation, oil generation and migration in the Songliao Basin, Northeastern China

The discovery of the giant Daqing oil field in the Songliao Basin led to the realisation of the significant petroleum potential of non-marine basins. In order to reconstruct the basin evolution and oil formation, an integrated organic geochemical-basin modelling study along a regional transect across the Songliao Basin was conducted. It provided a regional heat flow evolution model, and revealed post-orogenic or late syn-orogenic maturation in the Central Depression and pre-orogenic maturation in the Southeast Uplift Zone. Kinetic parameters of petroleum generation for the lacustrine source formations are the basis for the simulation of oil generation and migration in the Songliao Basin. Using the principle activation energy peaking at 54 kcal/mol and a pre-exponential factor of about 4.2·10²⁷ Ma⁻¹, the simulation obtained a relatively good match with the measured transformation ratios. The Qingshankou Formation in the West and East Central Depressions constituted the major source in the basin. Major oil generation, migration and accumulation occurred during the Early Tertiary. In the West Central Depression, the generated oils migrated upwards into the Yaojia Formation followed by the updip migration into the Daqing Anticline and towards the local structural high along the West Slope. In contrast, the oil migration in the East Central Depression was dominated by the downward movement from the lower member of the Qingshankou Formation followed by the updip migration towards the Caoyang Anticline. The simulated oil accumulations are in good agreement with discovered oil fields, implying a potential application of the model for prediction and evaluation of new exploration targets in the basin.     

Distribution of polycyclic musks in water and particulate matter of the Lippe River (Germany)

The occurrence and distribution of polycyclic musks in the Lippe River system (a tributary of the Rhine River, Germany) was investigated in order to observe the dynamic transport and partitioning of these compounds between aqueous and particulate phases after their discharge into the river by sewage effluents. 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta[g]-2-benzopyrane (HHCB), 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene (AHTN), 6-acetyl-1,1,2,3,3,5-hexamethylindane (AHMI) and 4-acetyl-1,1-dimethyl-6-tert.-butylindane (ADBI) concentrations were determined in 19 water and surface sediment samples which were taken from a longitudinal section of the river. HHCB and AHTN were present in each of the water samples at concentrations ranging from <10 to 180 ng l⁻¹ and <10 to 70 ng l⁻¹, respectively. The load of dissolved HHCB and AHTN was calculated on the basis of compound concentrations in water and the corresponding river runoff data and ranged from 3 to 293 g day⁻¹ and from 1 to 108 g day⁻¹, respectively. Increasing loads of HHCB and AHTN along the river reflect a high input of sewage effluents to the densely populated areas along the central part of the river. Decreasing loads at the lower reaches indicate that in the corresponding river sections the rate of removal of musks was higher than the rate of input. Degradation and/or adsorption to particulate matter are processes that might explain this phenomenon. Consequently, high concentrations of HHCB and AHTN were detected in surface sediments from the Lippe River (from 5 to 191 μg kg⁻¹ and from 2 to 1399 μg kg⁻¹, respectively). HHCB/AHTN ratios in sediment samples were lower (average 1.2) than in water samples (average 2.9), suggesting the preferential adsorption of AHTN to particulate matter.     

Late- and post-Variscan cooling and exhumation history of the northern Rhenish massif and the southern Ruhr Basin: new constraints from fission-track analysis

Apatite fission-track analyses were carried out on outcrop and core samples from the Rhenish massif and the Carboniferous Ruhr Basin/Germany in order to study the late- and post-Variscan thermal and exhumation history. Apatite fission-track ages range from 291±15 Ma (lower Permian) to 136±7 Ma (lower Cretaceous) and mean track lengths vary between 11.6 m and 13.9 m, mostly displaying unimodal distributions with narrow standard deviations. All apatite fission-track ages are younger than the corresponding sample stratigraphic age, indicating substantial post-depositional annealing of the apatite fission-tracks. This agrees with results from maturity modelling, which indicates 3500–7000 m eroded Devonian and Carboniferous sedimentary cover. Numerical modelling of apatite fission-track data predicts onset of exhumation and cooling not earlier than 320 Ma in the Rhenish massif and 300 Ma in the Ruhr Basin, generally followed by late Carboniferous–Triassic cooling to below 50–60°C. Rapid late Variscan cooling was followed by moderate Mesozoic cooling rates of 0.1–0.2°C/Ma, converting into denudation rates of <1 mm/a (assuming a stable geothermal gradient of 30°C/km). Modelling results also give evidence for some late Triassic and early Jurassic heating and/or burial, which is supported by sedimentary rocks of the same age preserved at the rim of the lower Rhine Basin and in the subsurface of the Central and Northern Ruhr Basin. Cenozoic exhumation and cooling of the Rhenish massif is interpreted as an isostatic response to former erosion and major base-level fall caused by the subsidence in the lower Rhine Basin.     

Source rock potential of the Middle Jurassic to Middle Pliocene,onshore Nile Delta Basin,Egypt

Organic geochemical characterization of cutting samples from the Abu Hammad-1 and Matariya-1 wells elucidates the depositional environment and source rock potential of the Jurassic and Lower Cretaceous successions and the Middle Miocene to Pleistocene section in the southern and eastern Nile Delta Basin. The burial and thermal histories of the Mesozoic and Miocene sections were modeled using 1D basin modeling based on input data from the two wells. This study reveals fair to good gas-prone source rocks within the Upper Jurassic and Lower Cretaceous sections with total organic carbon (TOC) averaging 2.7% and hydrogen index (HI) up to 130 mg HC/g TOC. The pristane/n-C₁₇ versus phytane/n-C₁₈ correlation suggests mixed marine and terrestrial organic matter with predominant marine input. Burial and thermal history modeling reveals low thermal maturity due to low heat flow and thin overburden. These source rocks can generate gas in the western and northern parts of the basin where they are situated at deeper settings. In contrast, the thick Middle Miocene shows fair source rock quality (TOC averaging at 1.4%; HI maximizing at 183 mg HC/g TOC). The quality decreases towards the younger section where terrestrial organic matter is abundant. This section is similar to previously studied intervals in the eastern Nile Delta Basin but differs from equivalents in the central parts where the quality is better. Based on 1D modeling, the thick Middle Miocene source rocks just reached the oil generation stage, but microbial gas, however, is possible.     

Petroleum source rocks of the Tarfaya Basin and adjacent areas, Morocco

This work characterizes the source rock potential of the Tarfaya Basin and enabled us to reconstruct its geochemical history. Outcrop samples covering different stratigraphic intervals, plus the northwestern part of the Zag/Tindouf Basin (Bas Draa area), were analyzed for total organic carbon (C_org) and total inorganic carbon contents and total sulfur content. Rock-Eval analysis and vitrinite reflectance measurements were performed on 56 samples chosen on the basis C_org content. A set of 45 samples were extracted and non-aromatic hydrocarbons were analyzed by way of gas chromatography-flame ionization detection (GC-FID) and GC-mass spectrometry (GC-MS). Non-isothermal open system pyrolysis at different heating rates was applied to obtain kinetic parameters for modelling petroleum generation from four different source rocks.High quality petroleum source rocks with high C_org content and hydrogen index (HI) values were found for samples of Eocene, Coniacian, Turonian and Cenomanian age. Most samples were carbonate rich and organic/sulfur values were high to moderate. Various maturity parameters indicated immature or possibly early mature organic matter. Based on organic geochemical and petrological data, the organic matter is of marine/aquatic origin (Cenomanian) or a mixture of aquatic and terrigenous material (Eocene). The Early Cretaceous interval did not contain high quality source rocks, but indications of petroleum impregnation were found.