The role of moisture cycling in the weathering of a quartz chlorite schist in a tropical environment: findings of a laboratory simulation

Long‐term weathering of a quartz chlorite schist via wetting and drying was studied under a simulated tropical climate. Cubic rock samples (15 mm × 15 mm × 15 mm) were cut from larger rocks and subjected to time‐compressed climatic conditions simulating the tropical wet season climate at the Ranger Uranium Mine in the Northern Territory, Australia. Fragmentation, moisture content and moisture uptake rate were monitored over 5000 cycles of wetting and drying. To determine the impact of climatic variables, five climatic regimes were simulated, varying water application, temperature and drying. One of the climatic regimes reproduced observed temperature and moisture variability at the Ranger Uranium Mine, but over a compressed time scale. It is shown that wetting and drying is capable of weathering quartz chlorite schist with changes expected over a real time period of decades. While wetting and drying alone does produce changes to rock morphology, the incorporation of temperature variation further enhances weathering rates. Although little fragmentation occurred in experiments, significant changes to internal pore structure were observed, which could potentially enhance other weathering mechanisms. Moisture variability is shown to lead to higher weathering rates than are observed when samples are subjected only to leaching. Finally, experiments were conducted on two rock samples from the same source having only subtle differences in mineralogy. The samples exhibited quite different weathering rates leading to the conclusion that our knowledge of the role of rock type and composition in weathering is insufficient for the accurate determination of weathering rates. Copyright © 2005 John Wiley & Sons, Ltd.     

Reflectance spectroscopic characterisation of mineral alteration footprints associated with sediment-hosted gold mineralisation at Mt Olympus (Ashburton Basin,Western Australia)

Hydrothermal ore deposits are typically characterised by footprints of zoned mineral assemblages that extend far beyond the size of the orebody. Understanding the mineral assemblages and spatial extent of these hydrothermal footprints is crucial for successful exploration, but is commonly hindered by the impact of regolith processes on the Earth's surface. Hyperspectral drill core (HyLogger?-3) data were used to characterise alteration mineralogy at the Mt Olympus gold deposit located 35 km southeast of Paraburdoo along the Nanjilgardy Fault within the northern margin of the Ashburton Basin in Western Australia. Mineralogy interpreted from hyperspectral data over the visible to shortwave (400–2500 nm) and thermal (6000–14500 nm) infrared wavelength ranges was validated with X-ray diffraction and geochemical analyses. Spaceborne multispectral (ASTER) and airborne geophysical (airborne electromagnetic, AEM) data were evaluated for mapping mineral footprints at the surface and sub-surface. At the deposit scale, mineral alteration patterns were identified by comparing the most abundant mineral groups detected in the HyLogger data against lithology logging and gold assays. Potential hydrothermal alteration phases included Na/K-alunite, kaolin phases (kaolinite, dickite), pyrophyllite, white mica, chlorite and quartz, representing low-T alteration of earlier greenschist metamorphosed sediments. The respective zoned mineral footprints varied depending on the type of sedimentary host rock. Siltstones were mainly characterised by widespread white-mica alteration with proximal kaolinite alteration or quartz veining. Sandstones showed (1) distal white mica, intermediate dickite, and proximal alunite + kaolinite or (2) widespread white-mica alteration with associated intervals of kaolinite. In both, sandstones and siltstones, chlorite was distal to gold mineralisation. Conglomerates showed distal kaolinite/dickite and proximal white-mica/dickite alteration. Three-dimensional visualisation of the gold distribution and spatially associated alteration patterns around Mt Olympus revealed three distinct categories: (1) several irregular, poddy, SE-plunging zones of >0.5 ppm gold intersected by the Zoe Fault; (2) sulfate alteration proximal to mineralisation, particularly on the northern side of the Mt Olympus open pit; and (3) varying Al^IVAl^VISi^IV_–1(Mg,Fe)^VI_–1 composition of white micas with proximity to gold mineralisation. Chlorite that developed during regional metamorphic or later hydrothermal alteration occurs distal to gold mineralisation. ASTER mineral mapping products, such as the MgOH Group Content used to map chlorite (±white mica) assemblages, showed evidence of correlation to mapped, local structural features and unknown structural or lithological contacts as indicated by inversion modelling of AEM data.     

Anthropogenic impacts on nitrogen fixation rates between restored and natural Mediterranean salt marshes

To test the effects of site and successional stage on nitrogen fixation rates in salt marshes of the Venice Lagoon, Italy, acetylene reduction assays were performed with Salicornia veneta‐ and Spartina townsendii‐vegetated sediments from three restored (6–14 years) and two natural marshes. Average nitrogen fixation (acetylene reduction) rates ranged from 31 to 343 μmol C₂H₄·m^?2·h^?1 among all marshes, with the greatest average rates being from one natural marsh (Tezze Fonde). These high rates are up to six times greater than those reported from Southern California Spartina marshes of similar Mediterranean climate, but substantially lower than those found in moister climates of the Atlantic US coast. Nitrogen fixation rates did not consistently vary between natural and restored marshes within a site (Fossei Est, Tezze Fonde, Cenesa) but were negatively related to assayed plant biomass within the acetylene reduction samples collected among all marshes. Highest nitrogen fixation rates were found at Tezze Fonde, the location closest to the city of Venice, in both natural and restored marshes, suggesting possible site‐specific impacts of anthropogenic stress on marsh succession.     

Settlement-Size Larval Red Drum (<Emphasis Type="Italic">Sciaenops ocellatus</Emphasis>) Respond to Estuarine Chemical Cues

Planktonic larvae combine directed swimming and functional sensory systems to locate benthic habitats. Some adult marine fishes use chemical cues for orientation to specific habitats, but olfactory function for estuarine fish larvae has received little research attention. This laboratory study quantified behavioral responses of red drum (Sciaenops ocellatus) larvae to estuarine chemical cues to examine the role of water chemistry as an orientation cue for locating or remaining in settlement habitat. Spontaneous activity (kinesis) was measured for pre-settlement-size larvae exposed to artificial sea water (as a negative control) and one of six treatments (sterilized sea water, sea water from a channel at ebb tide, sea water from a channel at flood tide, sea water from seagrass habitat, tannic acid dissolved in sterilized sea water, or lignin dissolved in sterilized sea water). Larvae that reached a size of competency to settle (approximately 10 mm standard length) swam faster when exposed to lignin dissolved in sterilized sea water than in other treatments; smaller larvae showed no response. Olfactory preference (taxis) was tested using a paired-choice experiment. Settlement-size larvae preferred water from seagrass beds to artificial sea water. The observed chemokinesis and chemotaxis in response to lignin dissolved in sterilized sea water and sea water from a seagrass bed demonstrate that red drum larvae can distinguish and respond to different water masses and suggest that chemical stimuli from seagrass settlement habitat may aid in orientation and movement to or retention in suitable settlement sites.     

Evaluating the impact of visualization of wildfire hazard upon decision-making under uncertainty

The paper investigates whether the methods chosen for representing uncertain geographic information aid or impair decision-making in the context of wildfire hazard. Through a series of three human subject experiments, utilizing 180 subjects and employing increasingly difficult tasks, this research evaluates the effect of five different visualizations and a text-based representation on decision-making under uncertainty. Our quantitative experiments focus specifically on the task of decision-making under uncertainty, rather than the task of reading levels of uncertainty from the map. To guard against the potential for generosity and risk seeking in decision-making under uncertainty, the experimental design uses performance-based incentives. The experiments showed that the choice of representation makes little difference to performance in cases where subjects are allowed the time and focus to consider their decisions. However, with the increasing difficulty of time pressure, subjects performed best using a spectral color hue-based representation, rather than more carefully designed cartographic representations. Text-based and simplified boundary encodings were among the worst performers. The results have implications for the performance of decision-making under uncertainty using static maps, especially in the stressful environments surrounding an emergency.     

Measuring Urban Streetscapes for Livability: A Review of Approaches

Increasing interest in urban livability demands that geographers and planners more precisely define what constitutes a livable streetscape, a fundamental building block of urban places. Widespread examination of streetscape livability will require precise and efficient measurements of (1) physical characteristics at the spatial scale of individual streetscapes and (2) indicators of experiential quality based on revealed behavior or stated preference. This article reviews approaches to collecting both types of measurements, showing that innovative methods using geographic information systems (GIS), Internet-enabled surveys, and even social media could be useful complements to traditional qualitative methods for collecting streetscape measurements.     

Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...