Temperature and its control of isotope fractionation by a sulfate-reducing bacterium

A synthesis of previous results, which we dub the “standard model,” provides a prediction as to how isotope fractionation during sulfate reduction should respond to physiological variables such as specific rate of sulfate reduction and environmental variables such as substrate availability and temperature. The standard model suggests that isotope fractionation should decrease with increasing specific rates of sulfate reduction (rate per cell). Furthermore, the standard model predicts that low fractionations should be found at both high and low temperatures whereas the highest fractionations should be found in the intermediate temperature range. These fractionation trends are controlled, as a function of temperature, by the balance between the transfer rates of sulfate into and out of the cell and the exchange between the sulfur pools internal to the organism. We test this standard model by conducting experiments on the growth physiology and isotope fractionation, as a function of temperature, by the sulfate-reducing bacterium Desulfovibrio desulfuricans (DSMZ 642). Our results contrast with the “standard model” by showing a positive correlation between specific rates of sulfate reduction and fractionation. Also by contrast with the standard model, we found the highest fractionations at low and high temperatures and the lowest fractionations in the intermediate temperature range. We develop a fractionation model which can be used to explain both our results as well as the results of the “standard model.” Differences in fractionation with temperature relate to differences in the specific temperature response of internal enzyme kinetics as well as the exchange rates of sulfate in and out of the cell. It is expected that the kinetics of these processes will show strain-specific differences.     

Measurement of natural stresses in a Provence mine (Southern France)

Stress measurements were carried out in the Arc syncline using drifs in a lignite mine. Eleven sites were investigated using the flat jack and hydraulic fracturing (or stimulating) methods. Two stress states were found to coexist, one isotropic, the other highly anisotropic. The orientations of the principal stresses are not homogeneous and an orientation ranging from E-W to NE-SW predominates locally. This does not accord with the regional stress field. The vertical stresses are systematically underestimated.     

Global trends and patterns of drought from space

This paper analyzes changes in areas under droughts over the past three decades and alters our understanding of how amplitude and frequency of droughts differ in the Southern Hemisphere (SH) and Northern Hemisphere (NH). Unlike most previous global-scale studies that have been based on climate models, this study is based on satellite gauge-adjusted precipitation observations. Here, we show that droughts in terms of both amplitude and frequency are more variable over land in the SH than in the NH. The results reveal no significant trend in the areas under drought over land in the past three decades. However, after investigating land in the NH and the SH separately, the results exhibit a significant positive trend in the area under drought over land in the SH, while no significant trend is observed over land in the NH. We investigate the spatial patterns of the wetness and dryness over the past three decades, and we show that several regions, such as the southwestern United States, Texas, parts of the Amazon, the Horn of Africa, northern India, and parts of the Mediterranean region, exhibit a significant drying trend. The global trend maps indicate that central Africa, parts of southwest Asia (e.g., Thailand, Taiwan), Central America, northern Australia, and parts of eastern Europe show a wetting trend during the same time span. The results of this satellite-based study disagree with several model-based studies which indicate that droughts have been increasing over land. On the other hand, our findings concur with some of the observation-based studies.     

Species loss in the brown world: are heterotrophic systems inherently stable?

Determining the effects of species loss on ecosystems has received considerable attention given the current threats many ecosystems are facing. A significant body of research has yielded many insights to this question, but this work has been limited by a focus on ecosystems where primary production plays a significant role in energy transfer. As many ecosystems rely on energy sources that are not derived from in situ production, there is a need to better understand how species loss will affect ecosystems of varying trophic states. To examine the effects of species loss on an ecosystem that is not reliant on in situ primary production, we manipulated the larval amphibian community of temporary forest ponds. These ponds are heterotrophic systems that rely on allochthonous inputs of detritus as a basal energy source. The larvae of two amphibian species that are prone to local extinction, wood frogs (Lithobates sylvatica) and spotted salamanders (Ambystoma maculatum), were removed from ponds and net ecosystem production was monitored. We found no effects of the removal of these top consumers on ecosystem functioning or on lower trophic groups (i.e., zooplankton, algae, bacteria). While amphibians can influence food web dynamics in other systems, their influence on system processes in temporary forest ponds appears to be limited. We hypothesize that the lack of any effects is due to the microbial degradation of detritus ??swamping?? the system, providing more than enough energy to maintain the food web, and/or due to omnivory dampening species interactions. These data indicate that the functioning of heterotrophic systems may be inherently stable due to internal dynamics that minimize interaction strengths among trophic groups.     

Governing geoengineering research: why, when and how?

Research on geoengineering – deliberate management of the Earth’s climate system – is being increasingly discussed within the science and policy communities. While justified as necessary in order to expand the range of options available to policy makers in the future, geoengineering research has already engendered public controversy. Proposed projects have been protested or cancelled, and calls for a governance framework abound. In this paper, we consider the reasons why geoengineering research might be subject to additional governance and suggest mechanisms that might be usefully applied in developing such a framework. We consider criteria for governance as raised by a review of the growing literature on geoengineering and other controversial scientific topics. We suggest three families of concern that any governance research framework must respond to: the direct physical risks of the research; the transparency and responsibility in decision making for the research; and the larger societal meanings of the research. We review what mechanisms might be available to respond to these three families of concern, and consider how these might apply to geoengineering research.     

High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.     

A climate-isotope regression model with seasonally-varying and time-integrated relationships

This study investigates multivariable and multiscalar climate-??¹⁸O relationships, through the use of statistical modeling and simulation. Three simulations, of increasing complexity, are used to generate time series of daily precipitation ??¹⁸O. The first simulation uses a simple local predictor (daily rainfall amount). The second simulation uses the same local predictor plus a larger-scale climate variable (a daily NAO index), and the third simulation uses the same local and non-local predictors, but with varying seasonal effect. Since these simulations all operate at the daily timescale, they can be used to investigate the climate-??¹⁸O patterns that arise at daily-interannual timescales. These simulations show that (1) complex links exist between climate-??¹⁸O relationships at different timescales, (2) the short-timescale relationships that underlie monthly predictor-??¹⁸O relationships can be recovered using only monthly ??¹⁸O and daily predictor variables, (3) a comparison between the simulations and observational data can elucidate the physical processes at work. The regression models developed are then applied to a 2-year dataset of monthly precipitation ??¹⁸O from Dublin and compared with event-scale data from the same site, which illustrates that the methodology works, and that the third regression model explains about 55% of the variance in ??¹⁸O at this site. The methodology introduced here can potentially be applied to historic monthly ??¹⁸O data, to better understand how multiple-integrated influences at short timescales give rise to climate-??¹⁸O patterns at monthly-interannual timescales.     

Using paleoclimate proxy-data to select optimal realisations in an ensemble of simulations of the climate of the past millennium

We present and describe in detail the advantages and limitations of a technique that combines in an optimal way model results and proxy-data time series in order to obtain states of the climate system consistent with model physics, reconstruction of past radiative forcing and proxy records. To achieve this goal, we select among an ensemble of simulations covering the last millennium performed with a low-resolution 3-D climate model the ones that minimise a cost function. This cost function measures the misfit between model results and proxy records. In the framework of the tests performed here, an ensemble of 30 to 40 simulations appears sufficient to reach reasonable correlations between model results and reconstructions, in configurations for which a small amount of data is available as well as in data-rich areas. Preliminary applications of the technique show that it can be used to provide reconstructions of past large-scale temperature changes, complementary to the ones obtained by statistical methods. Furthermore, as model results include a representation of atmospheric and oceanic circulations, it can be used to provide insights into some amplification mechanisms responsible for past temperature changes. On the other hand, if the number of proxy records is too low, it could not be used to provide reconstructions of past changes at a regional scale.     

On the excitation of short-term variations in the length of the day and polar motion

Variations in the distribution of mass within the atmosphere, and changes in the pattern of winds produce fluctuations in all three components of the angular momentum of the atmosphere on time-scales upwards of a few days. It, has been shown that variations in theaxial component of atmospheric angular momentum during the Special Observing Periods in the recent First GARP Global Experiment (FGGE, where GARP is the Global Atmospheric Research Programme) are well correlated with short-term changes in the length of the day. They are consistent with the total angular momentum of the atmosphere and solid Earth being conserved on short timescales (allowing for lunar and solar effects), without requiring significant angular momentum transfer between the Earth's liquid core and solid mantle on timescales of weeks or months. It has also been shown that fluctuations, in the equatorial components of atmospheric angular momentum make a major contribution to the observed wobble of the instantaneous pole of the Earth's rotation with respect to the Earth's crust. A necessary step in the investigation was a re-examination of the underlying theory of non-rigid body rotational dynamics and angular momentum exchange between the atmosphere and solid Earth. Since only viscous or topographic coupling between the atmosphere and solid Earth can transfer angular momentum, no atmospheric flow that everywhere satisfied inviscid equations (including, but not solely, geostrophic flow) could affect the rotation of a spherical solid Earth. New effective angular momentum functions were introduced in order to exploit the available data and allow for rotational and surface loading deformation of the Earth. A theoretical basis has now been established for future routine determinations of atmopheric, angular momentum fluctuations for the purpose of meteorological and geophysical research, including the assessment of the extent to which movements in the solid Earth associated with very large earthquakes contribute to the excitation of the Chandlerian wobble.     

Spatial interpolation of snow water equivalency using surface observations and remotely sensed images of snow‐covered area

As demand for water continues to escalate in the western Unites States, so does the need for accurate monitoring of the snowpack in mountainous areas. In this study, we describe a simple methodology for generating gridded‐estimates of snow water equivalency (SWE) using both surface observations of SWE and remotely sensed estimates of snow‐covered area (SCA). Multiple regression was used to quantify the relationship between physiographic variables (elevation, slope, aspect, clear‐sky solar radiation, etc.) and SWE as measured at a number of sites in a mountainous basin in south‐central Idaho (Big Wood River Basin). The elevation of the snowline, obtained from the SCA estimates, was used to constrain the predicted SWE values. The results from the analysis are encouraging and compare well to those found in previous studies, which often utilized more sophisticated spatial interpolation techniques. Cross‐validation results indicate that the spatial interpolation method produces accurate SWE estimates [mean R² = 0·82, mean mean absolute error (MAE) = 4·34 cm, mean root mean squared error (RMSE) = 5·29 cm]. The basin examined in this study is typical of many mid‐elevation mountainous basins throughout the western United States, in terms of the distribution of topographic variables, as well as the number and characteristics of sites at which the necessary ground data are available. Thus, there is high potential for this methodology to be successfully applied to other mountainous basins. Copyright © 2010 John Wiley & Sons, Ltd.