氧化多壁碳纳米管对水中钠离子的吸附研究

本文研究了强酸(体积比为3︰1的硫酸与硝酸)氧化的多壁碳纳米管对水中钠离子的吸附特性,考察了温度、初始浓度、吸附时间对钠离子吸附的影响。实验结果表明:多壁碳纳米管对钠离子的吸附能力随温度升高而下降;其吸附过程符合Langmuir吸附等温模型,但是在钠离子浓度较高时多壁碳纳米管的吸附特性更符合Freundlich等温模型;在温度为274K条件下,多壁碳纳米管对钠离子的吸附能约为-5.53KJ/mol即-57.3meV;化学反应焓变约为-9.31KJ/mol,表明混酸氧化的多壁碳纳米管对钠离子的吸附过程基本为物理吸附。     

表层水温表测量结果不确定度评定

文章以表层水温表为研究对象,根据JJG 289—2005表层水温表检定规程的要求,以计量标准器二等标准铂电阻温度计及配套设备制冷恒温槽为基础,详细分析了表层水温表温度测量值的不确定度来源,从而得到表层水温表温度示值误差的扩展不确定度,并给出了减小合成标准不确定度的方法。     

Modelling rainfall interception losses of three plantations in the Loess Plateau

The forest canopy affects the water entering the forest ecosystem by intercepting rainfall. This is especially pertinent in forests that depend on rainfall for their ecological water needs, quantifying and simulating interception losses provide critical insights into their ecological hydrological processes. In the semi-arid areas of the Loess Plateau, afforestation has become an effective ecological restoration measure. However, the rainfall interception process of these plantations is still unclear. To quantify and model the canopy interception of these plantations, we conducted a two-year rainfall redistribution measurement experiment in three typical plantations, including a deciduous broadleaf plantation (Robinia pseudoacacia) and two evergreen coniferous plantations (Platycladus orientalis and Pinus tabuliformis). Based on this, the revised Gash model was used to simulate their interception losses, and the model applicability across varying rainfall types was further compared and verified. The experiment clarified the rainfall redistribution in the three plantations, and the proportions of throughfall to gross rainfall in Robinia pseudoacacia, Platycladus orientalis, and Pinus tabuliformis were 84.8%, 70.4%, and 75.6%; corresponding, the stemflow proportions were 2.0%, 2.2%, and 1.8%; the interception losses were 13.2%, 27.4%, and 22.6%, respectively. The dominant rainfall pattern during the experiment was characterized by low-amounts, moderate-intensity, and short-duration, during which the highest interception proportions across the three plantations were observed. We used the Penman-Monteith equation and the regression method, respectively, to estimate the canopy average evaporation rate of the revised Gash model, finding that the latter provides a closer match to the measured cumulative interception (NSE >0.7). When simulating interception under the three rainfall patterns, the model with the regression method better simulated the cumulative interception and event-scale interception for Platycladus orientalis and Pinus tabuliformis plantations under the dominant rainfall pattern. The results contribute valuable information to assess the impact of forest rainfall interception on regional hydrologic processes.     

一种基于短时傅立叶变换的脉冲星消色散算法

叙述了一种基于短时傅立叶变换的脉冲星消色散算法。首先介绍了脉冲星的色散形成原因以及几种当今流行的消色散算法。接着介绍了短时傅立叶变换,并在此基础上提出了一种基于短时傅立叶变换的消色散算法。然后详细讲述了这种消色散算法的具体实现步骤,并且比较了在选取不同长度的时间窗函数的情况下,消色散的处理过程和残余色散量。最后,通过将这种算法的计算量以及结果和其他几种算法做横向比较,得出了结论:这种消色散算法的计算量小,实现简单,可以有效的进行消色散处理。     

海底沉积物纵波波速与物理-力学性质的理论关系和比较

本文提出以密度变化比和等效弹性模量变化比为参数描述海底沉积物纵波波速,得到密度变化比是由孔隙率、海水密度和海底沉积物固相密度构成的复合参数,建立了以复合参数和等效弹性模量变化比为变量的泰勒多项式海底沉积物纵波波速公式。基于单因素分析法得出纵波波速可表示为参考声速与调制函数的乘积,沉积物的参考声速由海底底质物理性质确定,建立了复合参数-声速的近似理论模型。对该理论模型与现有的主要纵波波速经验公式的分析结果表明,孔隙率-纵波波速经验公式只是参考声速不同,但调制函数是互相等效的,验证了本文海底沉积物纵波波速理论关系的有效性。     

错列不等直径双圆柱绕流特性数值研究

为研究低亚临界雷诺数Re情况下错列角度θ对不等直径双柱体绕流特性的影响,利用Fluent软件模拟了Re为3 900、间距比G/D为2.0、直径比D/d为0.5、θ=0°~180°之间9种角度的绕流过程,得到了流场涡量图、斯特鲁哈数St_1和St_2、平均阻力系数C_(d1)和C_(d2)以及平均升力系数C_(l1)和C_(l2)。研究结果表明,随着θ的从小到大,St_1先增大后减小,且在θ=30°和180°时有两个值,St_2在θ=120°~150°时明显小于其它角度;C_(d1)和C_(d2)的整体趋势都是先增大后减小,C_(l1)在θ=150°时取得极大值,C_(l2)在θ=30°时取得极小值。θ=0°时,两柱后方有单一涡脱落形态;θ=30°时,小柱后方有稳定漩涡脱落产生,大柱后方涡脱落受到干扰,且大柱有两个涡脱落频率;θ=45°~90°时,在间隙流的作用下,两柱后方均有漩涡脱落,尾流中有两列涡街;θ=120°~180°时,大柱后有稳定漩涡脱落,小柱涡脱落受到抑制。研究结果可为相关海洋工程设计提供参考。     

Circulation and Heat Flux along the Western Boundary of the North Pacific

On the basis of the conductivity temperature depth(CTD)observation data off the coast of the Philippines(7.5°–18°N,130°E–the east coast of the Philippines)in the fall of 2005,the water mass distribution,geostrophic flow field,and heat budget are examined.Four water masses are present:the North Pacific Tropical Surface Water,the North Pacific Sub-surface Water,the North Pacific Intermediate Water,and the Antarctic Intermediate Water(AAIW).The previous three corresponded with the North Equatorial Current(NEC),the Kuroshio Current(KC),and the Mindanao Current(MC),respectively.AAIW is the source of the Mindanao Undercurrent.The mass transport of NEC,KC,and MC is 58.7,15,and 27.95Sv,respectively(relative to 1500db).NEC can be balanced by the transport across the whole transect 18°N(31.81 Sv)and 7.5°N(26.11 Sv)but not simply by KC and MC.Direct calculation is used to study the heat flux.In sum,1.45PW heat is transported outwards the observed region,which is much more than that released from the ocean to the air at the surface(0.05PW).The net heat lost decreased the water temperature by 0.75℃each month on average,and the trend agreed well with the SST change.Vertically,the heat transported by the currents is mainly completed in the upper 500 m.     

Spatial variability and temporal dynamics of surface water pCO2, ��O2/Ar and dimethylsulfide in the Ross Sea, Antarctica

We report results from two surveys of pCO₂, biological O₂ saturation (??O₂/Ar) and dimethylsulfide (DMS) in surface waters of the Ross Sea polynya. Measurements were made during early spring (November 2006-December 2006) and mid-summer (December 2005-January 2006) using ship-board membrane inlet mass spectrometry (MIMS) for high spatial resolution (i.e. sub-km) analysis. During the early spring survey, the polynya was in the initial stages of development and exhibited a rapid increase in open water area and phytoplankton biomass over the course of our ∼3 week occupation. We observed a rapid transition from a net heterotrophic ice-covered system (supersaturated pCO₂ and undersaturated O₂) to a high productivity regime associated with a Phaeocystis-dominated phytoplankton bloom. The timing of the early spring phytoplankton bloom was closely tied to increasing sea surface temperature across the polynya, as well as reduced wind speeds and ice cover, leading to enhanced vertical stratification. There was a strong correlation between pCO₂, ??O₂/Ar, DMS and chlorophyll a (Chl a) during the spring phytoplankton bloom, indicating a strong biological imprint on gas distributions. Box model calculations suggest that pCO₂ drawdown was largely attributable to net community production, while gas exchange and shoaling mixed layers also exerted a strong control on the re-equilibration of mixed layer ??₂ with the overlying atmosphere. DMS concentrations were closely coupled to Phaeocystis biomass across the early spring polynya, with maximum concentrations exceeding 100 nM.During the summer cruise, we sampled a large net autotrophic polynya, shortly after the seasonal peak in phytoplankton productivity. Both diatoms and Phaeocystis were abundant in the phytoplankton assemblages during this time. Minimum pCO₂ was less than 100 ppm, while ??O₂/Ar exceeded 30% in some regions. Mean DMS concentrations were ∼2-fold lower than during the spring, although the range of concentrations was similar between the two surveys. There was a significant correlation between pCO₂, ??O₂/Ar and Chl a across the summer polynya, but the strength of these correlations and the slope of O₂ vs. CO₂ relationship were significantly lower than during the early spring. Summertime DMS concentrations were not significantly correlated to phytoplankton biomass (Chl a), pCO₂ or ??O₂/Ar. In contrast to the early spring time, there were no clear temporal trends in summertime gas concentrations. Rather, small-scale spatial variability, likely resulting from mixing and localized sea-ice melt, was clearly evident in surface gas distributions across the polynya. Analysis of length-scale dependent variability demonstrated that much of the spatial variance in surface water gases occurred at scales of <20 km, suggesting that high resolution analysis is needed to fully capture biogeochemical heterogeneity in this system.     

南海北部—观测点内潮特征的初步分析

采用功率谱分析、调和分析等方法，对南海北部－观测点连续９ｄ（１９８８年５月８—１６日）的温度。盐度和海流及跨越该期间较长的（１９８８年４月２４日－７月２２日）潮位资料进行了分析研究。结果表明，观测点存在着一种内潮现象，其波动的周期在２４ｈ左右，它传播的方向大体是偏北。     

Historical Sediment Record of ~(137)Cs, δ-HCH,and δ~(13)C Reflects the Impact of Land Use on Soil Erosion

This paper reports the concentrations of 137 Cs, hexachlorocyclohexane(HCH), dichlorodiphenyltrichloroethanes(DDT) and its main degradation products, δ13C, and organic carbon in pond sediments(0-210 cm, sectioned by 2-20 cm interval) and surface soils(the 0-3 cm horizon) collected in 2010 from Chenjia catchment, which is located in Yanting county in the hilly central Sichuan of China. α-, δ-, and γ-HCH, DDT, and DDD were not detected throughout the sediment profile. Trace concentrations of δ-HCH(0.89-29.31 ng g-1) and p,p′-DDE(1.85-6.02 ng g-1) were detected only in top 40 cm sediment. The 137 Cs fallout peak in 1963(corresponding to the 55-60 cm depth), the sedimentary signature left by the last year of HCH use in 1989(an additional indicator at 20-25 cm), and the obvious original channel bed prior to the construction of the pond in 1956 were used as temporal markers to estimate changes in average sedimentation rate between different periods due to changes in land use. Continuous, marked decrease in average sedimentation rate(i.e., 3.79, 1.35 and 1.07 cm year-1 in 1956-1963, 1963-1989, and 1989-2010, respectively)over time was observed, probably due to the reforestation, abandoning of steep sloping farmland for afforestation and natural re-vegetation(implementation of the Grain for Green Program), and the conversion of part of gently sloping farmland terraces to orchard land since the 1980 s, especially since the 1990 s. This was corroborated by the observed decrease(more negative) in δ13C of sediment towards the surface, which indicates increased relative contribution of eroded soil particles coming from slopes with increased tree cover in sediment source area. Combined use of 137 Cs, δ-HCH, and δ13C record in sediments has been demonstrated to be a powerful approach to reconstruction of response in sedimentation rate to historical land use changes.