57Fe-Moessbauer spectra,electronic and crystal structure of members of the CuS2-FeS2 solid solution series

Members of the (Cu, Fe)S₂ solid solution crystallize in the pyrite structure type, space group Pa 3, Cu and Fe being statistically distributed on the metal sites. Within this series, a semiconductor to metal transition can be detected between 25 and 38 mole% CuS₂. Compositional dependent ⁵⁷Fe-Moessbauer spectra reveal Fe²⁺ in low-spin configuration. A minimum of the quadrupole splitting and the slope in the ⁵⁷Fe-isomer shift in the intermediate part of the system, near 30 mole% CuS₂, can be correlated with the onset of metallic conductivity, whereas the structural parameters are not influenced by this transition. The analysis of the compositional dependency of the quadrupole splitting, in comparison to the isotypic system (Co, Fe)S₂, leads to the conclusion that Cu in solid (Cu, Fe)S₂ compounds is Cu⁺ with an Ar -3 d¹⁰ electronic configuration.     

The frictional behavior of lizardite and antigorite serpentinites: Experiments,constitutive models,and implications for natural faults

Laboratory studies of the frictional behavior of rocks can provide important information about the strength and sliding stability of natural faults. We have conducted friction experiments on antigorite and lizardite serpentinites, rocks common to both continental and oceanic crustal faults. We conducted both velocity-step tests and timed-hold tests on bare surfaces and gouge layers of serpentinite at room temperature. We find that the coefficient of friction of lizardite serpentinite is quite low (0.15–0.35) and could explain the apparent low stresses observed on crustal transform faults, while that of antigorite serpentinite is comparable to other crustal rocks (0.50–0.85). The frictional behavior of both types of serpentinite is well described by a two-mechanism model combining state-variable-dominated behavior at high slip velocities and flow-dominated behavior at low velocities. The two-mechanism model is supported by data from velocity-step tests and timed-hold tests. The low velocity behavior of serpentinite is strongly rate strengthening and should result in stable fault creep on natural faults containing either antigorite or lizardite serpentinite.     

Explorations into the formal structure of drainage basins

Every basin of higher than first order is drained by a channel network composed of two subnetworks. Their basins are separated by a drainage divide line, called the basin divider, which is the primary organizing feature of the main basin. Each basin of magnitude n contains n – 1 subnetworks of higher order, and is therefore organized by a set of n – 1 dividers. The dividers and the basin boundary are interconnected in a graph called the divider network of the basin; in graph-theoretic terms this network forms a tree and has the same magnitude and link numbers as the channel network draining the basin. While the subbasins and subnetworks of a drainage basin form a nesting hierarchy, the corresponding dividers do not; indeed, any two dividers share at most one node in common, and whether they do so is independent of whether the corresponding subbasins are nesting or disjoint. However, the dividers of nesting basins are linked by recursive relationships which permit the derivation of a set of algebraic equations; these equations relate the dividers of a basin to other basin components; for example, their combined length is equal to half the length of all first-order basin boundaries minus the length of the main basin boundary. The second part of the paper explores the dependence of the divider length on other basin parameters. The expected length, as predicted by the assumption of topological randomness, is clearly rejected by the data. An alternative approach (regression) is based on the observed magnitudes of the subbasins separated by each divider, and is reasonably successful in estimating divider length. The last section introduces the concept of the standardized basin defined by a boundary length of unity; the estimated lengths of the basin divider and the basin boundary permit an approximate reconstruction of the idealized basin shape and the location of the divider in it.     

4He diffusion in specular hematite

In order to test the chronometer qualities of speculante for the (U + Th)/He dating method, ⁴He release experiments by stepwise heating of two specularites from the Rimbach mineralization locality in the southern Vosgues (France) have been carried out. The diffusion coefficients define linear Arrhenius plots within a temperature interval of 250 to 830 °C, which is suggestive of volume diffusion. Extrapolation of the diffusion behavior to 20° C yields diffusion coefficients (D₂₀ values) smaller than 10^?26 [cm² s^?1] for both hematites with activation energies at 116 [kJ/mole]. The results of our study suggest that specularite is a very helium retentive hematite variety which is capable of quantitatively retaining radiogenic helium over geologic periods of time.     

Effects of hopper dredging and sediment dispersion,chesapeake bay

Hopper dredging operations release suspended sediment into the environment by agitation of the bed and by discharge of overflow slurries. Monitoring of turbidity and suspended sediment concentrations in central Chesapeake Bay revealed two plumes: (1) an upper plume produced by overflow discharge and (2) a near-bottom plume produced by draghead agitation and rapid settling from the upper plume. The upper plume dispersed over 5.7 km² extending 5,200 meters form the discharge point. Redeposited sediment accumulated on channel flanks covering an area of 6.4 km² and reached a thickness of 19 cm. Altogether dredging redistributed into the environment an estimated 100,000 tons of sediment or 12 percent of the total material removed.Near-field concentrations of suspended sediment, less than 300 m from the dredge, reach 840 to 7,200 mg/L or 50 to 400 times the normal background level. Far-field concentrations (>300 m) are enriched 5 to 8 times background concentrations and persist 34 to 50 percent of the time during a dredging cycle (1.5 to 2.0 h). The overflow discharge plume evolves through three dispersion phases: (1) convective descent, (2) dynamic collapse, and (3) long-term passive diffusion (Clark and others 1971). The bulk of the material descends rapidly to the bottom during the convective descent phase, whereas the cloud that remains in suspension is dispersed partly by internal waves. Although suspended sediment concentrations in the water column exceed certain water quality standards, benthic communities survived the perturbation with little effect.     

Problems resulting from misinterpretations of natural resources and natural hazards in tropical countries. The example of Peru

Natural resources in a tropical country like Peru are often overestimated. Peru is characterized by a wide range of regional differences, varied physical settings, and numerous natural hazards. Some climatical and hydrological conditions are examined and the factors causing instability in agricultural and nonagricultural production are discussed. Natural resources must be evaluated in the framework of internal political, social, and economic circumstances. Several points are recommended to foster economic development when considering the constraints of the physical environment.     

Desorption and coagulation of trace elements during estuarine mixing

Mixing experiments of seawater and the Hudson and Mississippi riverwaters with radiotracer spikes show that Co, Mn, Cs, Cd, Zn and Ba will be desorbed from river suspended particles, while significant fractions of “dissolved” Fe, Sn, Bi, Ce and Hg will be coagulated during estuarine mixing.     

Partition of radiotracers between suspended particles and seawater

Distinctive uptake mechanisms of different radiotracers by red clays in seawater are elucidated from the magnitude and change of distribution coefficients (K_d) for up to 17 γ-emitting radiotracers as functions of equilibration time, suspended particle concentration and compositions of solids and seawaters. The adsorption of ionic metals onto colloids and subsequent coagulation of colloids onto larger particles are the dominant removal processes of metals in the aquatic environments of low suspended particle concentration.     

Multivariate analysis of species composition of shore-zone fish assemblages found in Long Island Sound

A nested design was used to analyze the variance of the proportions or percent species composition of shore-zone finfish assemblages in the vicinity of the Millstone Nuclear Power Station in eastern Long Island Sound. The relative importance of five selected shore-zone species was found to be significantly influenced by both station and season within a year. Also included in the nested ANOVA model were effects due to period of plant operation (no units operating, one unit operating and two units operating) and year within period. Neither of these two effects was found to influence the percent species composition. The results of this study suggest that a nested ANOVA of percent species composition can be useful for detecting changes in assemblages of finfish species over time and space.     

Rates of sulfur dioxide and particle emissions from White Island volcano,New Zealand,and an estimate of the total flux of major gaseous species

Airborne correlation spectrometry (COSPEC) was used to measure the rate of SO₂ emission at White Island on three dates, i.e., November 1983, 1230 ± 300 t/d; November 1984, 320 ± 120 t/d; and January 1985, 350 ± 150 t/d (t = metric tons). The lower emission rates are likely to reflect the long-term emission rates, whereas the November 1983 rate probably reflects conditions prior to the eruption of December 1983. The particle flux in the White Island plume, as determined with a quartz crystal microbalance/cascade in November 1983, was 1.3 t/d, unusually low for volcanic plumes. The observed plume particles, as shown from scanning electron microscopy, include halite, native sulfur, and silicates and are broadly similar to other volcanic plumes.Gas analyses from high-temperature volcanic fumaroles collected from June 1982 through November 1984 werde used together with the COSPEC data to estimate the flux of other gas species from White Island. The rates estimated are indicative of the long-term volcanic emission, i.e., 8000–9000 t/d H₂O, 900–1000 t/d CO₂, 70–80 t/d HCl, 1.5–2 t/d HF, and about 0.2 t/d NH₃. The long-term thermal power output at White Island is estimated at about 400 MW.