Gaps in cubic closest packing: from MgO via spinel to the pharmacosiderite crystal structure type

Numerous ordered defect structures are known that are related to the sodium chloride (or MgO) structure type, thus they are basically cubic closest packed (ccp) arrangements with vacancies. For example the NbO type is an MgO type in which one quarter each of the anions and the cations are missing compared to the ccp in such a way that both anions and cations are in square-planar coordination. In spinel, Al₂MgO₄, one half of the octahedrally coordinated cations are missing compared with the MgO type and only one eighth of the tetrahedrally coordinated sites within the ccp are occupied. What these cases have in common is that all these derivatives are rather dense. This is different in pharmacosiderite, K[Fe₄(OH)₄As₃O₁₂]. 6 to 7H₂O, where one half of the anion positions, three quarters of the octahedral sites and five eighth of the tetrahedral sites remain vacant, compared to the spinel type. Pharmacosiderite is a wide open porous structure with zeolitic properties. We are illustrating these relationships using a Bärnighausen symmetry tree and by tables relating the various structure types to each other.     

The use of tracers to assess drill-mud penetration depth into sandstone cores during deep drilling: method development and application

For the utilization of deep saline aquifers in the frame of geotechnical use, such as geological sequestration of CO₂, H₂ or energy storage, a baseline characterization of pristine reservoir rock cores is required to monitor changes in the indigenous microbial communities and pore fluids, and to study alterations in rock characteristics resulting from interaction with geological storage technologies. However, drilling procedures and technical fluids, particularly drill mud, are sources of core contamination. To measure the penetration of drill mud into the cores, three tracers (fluorescein, microspheres, and 4′,6-diamidino-2-phenylindole stained bacteria) were tested under laboratory conditions. The flow of drill mud into core samples was induced by applying uniaxial pressure differentials to the core, and the penetration depth was microscopically determined for each tracer. Fluorescein was extracted from the rock samples and quantified fluorometrically. The results indicate that all tested tracers are suitable for tracking drill-mud penetration. The actual penetration depth seems to be related to differences in mineral composition and texture as well as microfractures. Among all tested tracers, fluorescein labelling is the simplest, cheapest and most accurate method for analyzing the contamination of rock cores by technical fluids. The application of this tracer was successfully applied during two deep drilling campaigns at the CO₂ storage pilot site in Ketzin, Germany. The results highlight that the use of tracers is indispensable to ensure the quality of core samples for microbiological and biogeochemical analysis.     

Volatile emissions and gas geochemistry of Hot Spring Basin,Yellowstone National Park,USA

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H₂, and mildly enriched in CH₄ and H₂S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water–rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or ^40?Ar/^4?He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 °C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO₂ flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO₂ fluxes across all the thermal/altered area suggests that 410 ± 140 t d^− 1 CO₂ are emitted at HSB (vent emissions not included). Diffuse fluxes of H₂S were measured in Yellowstone for the first time and likely exceed 2.4 t d^− 1 at HSB. Comparing estimates of the total estimated diffuse H₂S emission to the amount of sulfur as SO₄²⁻ in streams indicates ~ 50% of the original H₂S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140–370 MW using CO₂ as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1–3% for CO₂, 2–8% for heat) of that estimated for the entire Yellowstone system.     

The influence of dimensionality on simulations of mass recovery from nonuniform dense non-aqueous phase liquid (DNAPL) source zones

The influence of model dimensionality on predictions of mass recovery from dense non-aqueous phase liquid (DNAPL) source zones in nonuniform permeability fields was investigated using a modified version of the modular three-dimensional transport simulator (MT3DMS). Thirty-two initial two- (2D) and three-dimensional (3D) tetrachloroethene–DNAPL source zone architectures, taken from a recent modeling study, were used as initial conditions for this analysis. Commonly employed source zone metrics were analyzed to determine differences between 2D and 3D predictions: (i) down-gradient flux-averaged contaminant concentration, (ii) reductions in contaminant mass flux through a down-gradient boundary, (iii) source zone ganglia-to-pool (GTP) ratio, and (iv) time required to achieve a remediation objective. 3D flux-averaged contaminant concentrations were approximately 3.5 times lower than concentrations simulated in 2D. This difference was attributed to dilution of the contaminant concentrations down gradient of the source zone. Contaminant flux reduction predictions for a given mass recovery were generally 5% higher in 3D simulations than in 2D simulations. The GTP ratio declined over time as mass was recovered in both 2D and 3D simulations. Although the source longevity (i.e., time required to achieve 99.99% mass recovery) differed between individual 2D and 3D realizations, the mean source longevity for the 2D and 3D simulation ensembles was within 2%. 2D simulations tended to over-predict the time required to achieve lower mass recovery levels (e.g. 50% mass recovery) due to a smaller contaminated area exposed to uncontaminated water. These findings suggest that ensemble averages of 2D numerical simulations of DNAPL migration, entrapment, dissolution, and mass recovery in statistically homogenous, nonuniform media may provide reasonable approximations to average behavior obtained using simulations conducted in fully three-dimensional domains.     

Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.     

Galaxies in Interaction

Posters: Because of the large number of contributions, some oral presentations had to be transferred into Posters. The reader is referred to the final programme for the actual allocation of Posters. A01 Chemical Enrichment of the Intracluster Medium A02 Structural analysis of high‐velocity clouds – Evidence for an interaction between the Milky Way and the Magellanic System A03 Multi‐Phase Chemo‐Dynamical SPH code for galaxy evolution A04 The proper motion of M33 A05 Wavelet analysis of Intra–group Light in Hickson Compact Groups A06 Evidence for an evolutionary connection between early and late type dwarf galaxies A07 Dwarf Galaxies in the NGC 5846 Group A08 X‐ray spectroscopy of serendipitous clusters of galaxies in XMM‐Newton observations A09 Evolution of smale scale systems of galaxies: X‐ray detected E+S galaxy pairs A10 Modelling Star Formation in Interacting Galaxies A11 NGC 1427A – the beginning of the end: a lonely dwarf irregular entering the dense core of the Fornax cluster A12 Dwarf galaxies in galaxy groups: Photo‐evaporation, orbits and gas stripping A13 High resolution stellar kinematics for the central component of the Polar Ring Galaxy NGC 4650A A14 The Influence of Environment on the Morphological Evolution of Disk‐Dominated Galaxies A15 Interactions and star formation in galaxies A16 Dust Condensations and Molecular Clouds in Interacting Spirals A17 Star formation rates and kinematics of modelled interacting galaxies A18 Evolution of Galaxies and the Tully–Fisher Relation A19 Evolution and Collision of Galaxies on the GRID A20 Multiwavelength observations of two S+E merger candidates: the Medusa and NGC 4441 A21 Interacting Galaxies in Small Galaxy Groups A22 Virial and total masses of galaxy triplets in the Local Supercluster A23 Simulations of Interaction Processes of Galaxies with the Intra‐Cluster Medium A24 Chemical evolution of the thick and thin disks of our Galaxy A25 Dust properties of UV‐bright galaxies at z ∼ 2 A26 Simulation of the Gravitational Collapse and Fragmentation of Rotating Molecular Clouds A27 NGC 5719/13: interacting spirals forming a counter‐rotating stellar disc A28 Starbursts in very metal‐poor dwarfs due to interactions and mergers: link to the processes in the high‐redshift young galaxies A29 Testing galaxy evolution in the field: morphology and properties of the diffuse X‐ray emission in shell galaxies A30 Effects of galactic winds on dIrrs with particular emphasis on NGC 1569 and the refill of superbubble cavities A31 Galaxy formation through merging at z ≈ 2 A32 3D simulations of the ISM‐ICM interaction of disk galaxies in clusters A33 Gas replenishment in ram pressure stripped disk galaxies A34 New Results on the Kinematics of the Outer Cluster System of NGC 1399 A35 Chemical gradient evolution in massive galaxy disk due to its minor merger with dwarf galaxy A36 The complex kinematics of galaxies in Hickson 62 A37 Dust in the outer regions of interacting galaxies A38 Dynamical interaction of M31 and M32 A39 A comparative study of galaxy properties in low‐ and high density environment A40 Compact Groups in Dense Environment: The Case of IC1370 A41 The Star Formation History of CG J1720‐67.8 A42 Galaxy populations in the infall regions of intermediate redshift clusters A43 The study of gravitational fragmentation in two‐clumps collisions A44 Star Formation Activity in Galaxy Clusters Near and Far A45 An Exploration of the Merging History of the Local Starburst Galaxy, NGC 3310 A46 The high‐velocity clouds of M31: tracers of galactic evolution A47 The Properties of Fossil Groups     

用电子束CT作冠状动脉血管造影

本文介绍用电子束ＣＴ作冠状动脉可视化造影的方法,说明本项成就的特征和在应用这项技术的局限性,并指出这种技术在临床上,可能成为新无创伤性的诊断工具。