Intercalibration of Solar Soft X-Ray Broad Band Measurements from SOLRAD 9 through GOES-12

The two-band soft X-ray observations of solar flares made by the Naval Research Laboratory’s (NRL) SOLar RADiation (SOLRAD) satellites and by the Geostationary Orbiting Environmental Satellites (GOES) operated by the National Oceanic and Atmospheric Administration’s (NOAA) Space Weather Prediction Center have produced a nearly continuous record of solar flare observations over a period of more than forty years (1969 – 2011). However, early GOES observations (i.e., GOES-2) and later (GOES-8 and subsequent missions) are not directly comparable due to changes in the conversion of measured currents to integrated fluxes in the two spectral bands that were adopted: 0.05 – 0.3 (or 0.4) nm, which we refer to as XS and 0.1 – 0.8 nm (XL). Furthermore, additional flux adjustments, using overlapping data sets, were imposed to provide consistency of flare-flux levels from mission to mission. This article evaluates the results of these changes and compares experimental GOES-8/GOES-2 results with changes predicted from modeled flare spectra. The factors by which recent GOES observations can be matched to GOES-2 are then optimized by adapting a technique first used to extrapolate GOES X-ray fluxes above saturation using ionospheric VLF radio phase enhancements. A nearly 20% increase in published GOES-8 XL data would be required to match to GOES-2 XL fluxes, which were based on observed flare spectra. On the other hand, a factor of 1.07 would match GOES-8 and later flat-spectrum 0.1 – 0.8 nm fluxes to GOES-2 XL if the latter data were converted to a flat-spectrum basis. Finally, GOES-8 observations are compared to solar soft X-ray estimates made concurrently with other techniques. Published GOES-8 0.1 – 0.8 nm fluxes are found to be 0.59 of the mean of these other determinations. Rescaling GOES to a realistic flare spectrum and removing a 30% downward adjustment applied to the GOES-8 measurements during initial data processing would place GOES-8 and later GOES XL fluxes at 0.94 of this XL mean. GOES-2 on the same scale would lie at about 0.70 of this mean. Significant uncertainties in the absolute levels of broad band soft X-ray fluxes still remain, however.     

Emulating the OPAL equation of state

The equation of state for the structure of the Sun and stars has to be precise to allow comparisons with observations, i.e., helioseismic inversions of thermodynamic quantities. Among the two of the most popular formalisms are (1) the OPAL equation of state developed at Livermore and (2) the Mihalas-Hummer-Däppen (MHD) equation of state. While OPAL has a solid theoretical foundation, and matches the observational data better, the MHD formalism is more intuitive, easy to realize, and has the possibility of adjustable parameters. Furthermore, it an open-source product in contrast to the proprietary OPAL. Recently a version of MHD has been obtained by including the so-called “Plank-Larkin partition function” and by adding scattering-state terms. The resulting formalism matches OPAL rather well. Here, we report on the next logical step, the implementation of this MHD upgrade into the simple and popular CEFF equation of state. Such an implementation will make it a flexible and convenient tool, allowing an approximative on-line implementation of OPAL in solar and stellar models.     

EC 11481–2303—a peculiar subdwarf OB star revisited

EC?11481–2303 is a peculiar, hot, high-gravity pre-white dwarf. Previous optical spectroscopy revealed that it is a sdOB star with T _eff=41?790 K, log?g=5.84, and He/H = 0.014 by number. We present an on-going spectral analysis by means of non-LTE model-atmosphere techniques based on high-resolution, high-S/N optical (VLT-UVES) and ultraviolet (FUSE, IUE) observations.We are able to reproduce the optical and UV observations simultaneously with a chemically homogeneous NLTE model atmosphere with a significantly higher effective temperature and lower He abundance (T _eff=55?000 K, log?g=5.8, and He/H=0.0025 by number). While C, N, and O appear less than 0.15 times solar, the iron-group abundance is strongly enhanced by at least a factor of ten.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.     

Biological influences on modern sulfates: Textures and composition of gypsum deposits from Guerrero Negro,Baja California Sur,Mexico

Gypsum (CaSO₄·2H₂O) deposits from a range of sedimentary environments at Guerrero Negro, Baja California Sur, Mexico were investigated for microscale texture and composition in order to differentiate features formed under substantial microbial influence from those for which microbial effects were relatively minor or absent. Gypsum deposits were classified according to their sedimentary environment, textures, crystal habit, brine composition and other geochemical factors. The environments studied included subaqueous sediments in anchialine pools and in solar salterns, as well as subsurface sediments of mudflats and saltpans. Gypsum that developed in the apparent absence of biofilms included crystals precipitated in the water column and subsedimentary discs that precipitated from phreatic brines. Subsedimentary gypsum developed in sabkha environments exhibited a sinuous microtexture and poikilitically enclosed detrital particles. Water column precipitates had euhedral prismatic habits and extensive penetrative twinning. Gypsum deposits influenced by biofilms included bottom nucleated crusts and gypsolites developing in anchialine pools and saltern ponds. Gypsum precipitating within benthic biofilms, and in biofilms within subaerial sediment surfaces provided compelling evidence of biological influences on crystal textures and habits. This evidence included irregular, high relief surface textures, accessory minerals (S°, Ca-carbonate, Sr/Ca-sulfate and Mg-hydroxide) and distinctive crystal habits such as equant forms and crystals having distorted prism faces.     

Resource allocation for regional earthquake risk mitigation: a case study of Tehran,Iran

This paper presents a new optimization model to help cities in seismically active developing countries decide (1) How much to spend on pre-earthquake mitigation versus waiting until after an event and paying for reconstruction or simply not rebuilding damaged buildings? (2) Which buildings to mitigate and how? and (3) Which buildings to reconstruct and how? It extends previously developed optimization models to consider the particular issues that arise in such countries. First, the model allows for the possibility that some damaged buildings will not be reconstructed immediately and keeps track of any lost building inventory. Second, buildings can be mitigated to, or when damaged, reconstructed to, any appropriate structural type and seismic design level. Finally, the model objectives include minimizing the chance of an extremely high death toll in any one earthquake and minimizing the average annual death toll across earthquakes. The model is illustrated through a case study analysis for Tehran, Iran.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

Sampling and Characterizing Rare Earth Elements in Groundwater in Deep-Lying Fractures in Granitoids Under In Situ High-Pressure and Low-Redox Conditions

Several countries are preparing to dispose of radioactive nuclear waste deep underground in crystalline rock. This type of bedrock is commonly extensively fractured and consequently carries groundwater that serves as a medium for transporting metals and radionuclides. A group of metals of particular interest in this context is the rare earth elements (REEs), because they are analogues of actinides contained within radioactive waste and are tracers of hydrological pathways and geochemical processes. Concentrations of REEs are commonly low in these groundwaters, leading to values below detection limits of standard monitoring methods, particularly for the heavy REEs. We present a new technical set-up for monitoring REEs (and other trace metals) in groundwater in fractured crystalline rock. The technique consists of passing the fracture groundwater, commonly under high pressure and containing reduced chemical species, through a device that maintains the physicochemical character of the groundwater. Within the device, diffusive gradient in thin-film (DGT) discs are installed in triplicate. With this set-up, we studied REEs in groundwater in fractures at depths of approximately ?144, ?280, and ?450 m in granitoids in the Äspö Hard Rock Laboratory in southern Sweden. The entire REE suite was detected (concentrations down to 0.1 ng L^?1) and was differently fractionated among the groundwaters. The shallowest groundwater, composed of dilute modern Baltic Sea water, was enriched in the heavy REEs, whereas the deeper groundwaters, dominated by old saline water, were depleted in the heavy REEs. Deployment periods varying from 1 to 4 weeks delivered similar REE concentrations, indicating stability and reproducibility of the experimental set-up. The study finds that 1 week of deployment may be enough. However, if the overall setting and construction allow for longer deployment times, 2–3 weeks will be optimal in terms of reaching reliable REE concentrations well above the detection limit while maintaining the performance of the DGT samplers.