Expanding the application of the Eu‐oxybarometer to the lherzolitic shergottites and nakhlites: Implications for the oxidation state heterogeneity of the Martian interior

Abstract— Experimentally rehomogenized melt inclusions from the nakhlite Miller Range 03346 (MIL 03346) and the lherzolitic shergottite Allan Hills 77005 (ALH 77005) have been analyzed for their rare earth element (REE) concentrations in order to characterize the early melt compositions of these Martian meteorites and to calculate the oxygen fugacity conditions they crystallized under. D(Eu/Sm)_{pyroxene/melt} values were measured at 0.77 and 1.05 for ALH 77005 and MIL 03346, respectively. These melts and their associated whole rock compositions have similar REE patterns, suggesting that whole rock REE values are representative of those of the early melts and can be used as input into the pyroxene Eu‐oxybarometer for the nakhlites and lherzolitic shergottites. Crystallization fO₂ values of IW + 1.1 (ALH 77005) and IW + 3.2 (MIL 03346) were calculated. Whole rock data from other nakhlites and lherzolitic shergottites was input into the Eu‐oxybarometer to determine their crystallization fO₂ values. The lherzolitic shergottites and nakhlites have fO₂ values that range from IW + 0.4 to 1.6 and from IW + 1.1 to 3.2, respectively. These values are consistent with some previously determined fO₂ estimates and expand the known range of fO₂ values of the Martian interior to four orders of magnitude. The origins of this range are not well constrained. Possible mechanisms for producing this spread in fO₂ values include mineral/melt fractionation, assimilation, shock effects, and magma ocean crystallization processes. Mineral/melt partitioning can result in changes in fO₂ from the start to the finish of crystallization of 2 orders of magnitude. In addition, crystallization of a Martian magma ocean with reasonable initial water content results in oxidized, water‐rich, late‐stage cumulates. Sampling of these oxidized cumulates or interactions between reduced melts and the oxidized material can potentially account for the range of fO₂ values observed in the Martian meteorites.     

Vulnerability and its discontents: the past,present, and future of climate change vulnerability research

The agri-food sector must adapt to changes in climate variability, while also helping to mitigate climate change. Measures termed ‘triple-win’ mitigate and adapt to climate change, while also improving soil health, thereby increasing yields. These measures might appear to be the easiest to implement, but in practice, barriers prevent full realisation. This study aims to move beyond previous research efforts that identify and categorise barriers by (i) revealing hidden barriers, (ii) understanding the interactions between barriers and (iii) exploring ways to address barriers. A case study focusing on crop rotation as a triple-win strategy in Ukraine demonstrates how a participant-driven iterative research approach can achieve these objectives. During semi-structured interviews with farmers and stakeholders, crop rotation emerged as an area of considerable dissensus with stakeholders commonly citing the greedy behaviour of producers as the problem. Further discussion indicated that the political economy of Ukraine caused financial constraints for producers and Q methodology allowed for additional clarity on the opposing views of crop rotation. Three factors emerged: producer insecurity, national insecurity and business insecurity. These three perspectives reveal contrasting priorities with producer insecurity and business insecurity concerned with the conditions under which producers must operate, while national insecurity has a focus on improving agricultural production to benefit the nation. Consensus statements across all factors could provide first steps to addressing barriers and an opportunity to open discussions amongst stakeholders. Finally, barriers arising from political processes demonstrate that climate policy needs to be integrated with other sector-specific policy decisions.     

Changes in the rainfall–streamflow regimes related to climate change in a small catchment in Northern Italy

Theoretical and Applied Climatology - Climate change has become an important issue for scientific community, for its numerous impacts, especially on agriculture and environment. To shed light on...     

Geomorphology, Stratigraphy, and Radiocarbon Chronology of LlanquihueDrift in the Area of the Southern Lake District, Seno Reloncaví, and Isla Grande de Chiloé, Chile

Glacial geomorphologic features composed of (or cut into) Llanquihue drift delineate former Andean piedmont glaciers in the region of the southern Chilean Lake District, Seno Reloncav', Golfo de Ancud, and northern Golfo Corcovado during the last glaciation. These landforms include extensive moraine belts, main and subsidiary outwash plains, kame terraces, and meltwater spillways. Numerous radiocarbon dates document Andean ice advances into the moraine belts during the last glacial maximum (LGM) at 29,363–29,385 ¹⁴C yr BP , 26,797 ¹⁴C yr BP , 22,295–22,570 ¹⁴C yr BP , and 14,805–14,869 ¹⁴C yr BP . Advances may also have culminated at close to 21,000 ¹⁴C yr BP , shortly before 17,800 ¹⁴C yr BP , and shortly before 15,730 ¹⁴C yr BP . The maximum at 22,295–22,567 ¹⁴C yr BP was probably the most extensive of the LGM in the northern part of the field area, whereas that at 14,805–14,869 ¹⁴C yr BP was the most extensive in the southern part. Snowline depression during these maxima was about 1000 m. Andean piedmont glaciers did not advance into the outer Llanquihue moraine belts during the portion of middle Llanquihue time between 29,385 ¹⁴C yr BP and more than 39,660 ¹⁴C yr BP . In the southern part of the field area, the Golfo de Ancud lobe, as well as the Golfo Corcovado lobe, achieved a maximum at the outermost Llanquihue moraine prior to 49,892 ¹⁴C yr BP . Pollen analysis of the Taiquemmire, which is located on this moraine, suggests that the old Llanquihue advance probably corresponds to the time of marine isotope stage 4. The implication is that the Andean snowline was then depressed as much as during the LGM. A Llanquihue-age glacier expansion into the outer moraine belts also occurred more than about 40,000 ¹⁴C yr BP for the Lago Llanquihue piedmont glacier.     

Paleoecology of The Southern Chilean Lake District-Isla Grande de Chiloé During Middle–late Llanquihue Glaciation and Deglaciation

Subantarctic Parkland and Subantarctic–North Patagonian Evergreen Forest, embracing >40,000 ¹⁴ C years of middle and late Llanquihue glaciation, are reconstructed from pollen contained in multiple interdrift deposits and cores of lake sediments. The subantarctic plant communities at low elevations have since been replaced by temperate Valdivian Evergreen Forest. Data in support of the vegetation reconstruction derive from close-interval sampling (>1400 pollen analysed stratigraphic levels) and high-resolution chronology (>200 AMS and conventional radiocarbon-dated horizons). Pollen sequences are from 15 sites, eight of which are exposures and seven mires, located in relation to lobes of piedmont glaciers that occupied Lago Llanquihue, Seno Reloncav', Golfo de Ancud, and the east-central sector of Isla Grande de Chiloí at the northern limit of the Golfo Corcovado lobe. Recurring episodes of grass maxima representing Subantarctic Parkland, when grass and scrub became widespread among patches of southern beech (Nothofagus), bear a relationship to glacial advances. The implication of the maxima, prominent with advances at 22,400 and 14,800 ¹⁴C yr BP during late Llanquihue glaciation in marine oxygen-isotope Stage 2, is of successive intervals of cold climate with summer temperatures estimated at 6–8°C below the modern mean. The earliest recorded maximum at >50,000 ¹⁴C yr BP is possibly during late Stage 4. At the time of middle Llanquihue glaciation in Stage 3, cool, humid interstades on Isla Grande de Chiloé with Subantarctic Evergreen Forest, which under progressive cooling after 47,000 ¹⁴C yr BP was increasingly replaced by parkland. During stepwise deglaciation, when transitional beech woodland communities supplanting parkland became diversified by formation of thermophilous North Patagonian Evergreen Forest, warming in the order of 5–6°C was abrupt after 14,000 ¹⁴C yr BP . Closed-canopy North Patagonian Evergreen Forest was established by 12,500 ¹⁴C yr BP . Later, after c. 12,000 until 10,000 ¹⁴C yr BP , depending on location, forest at low elevations became modified by expansion of a cold-tolerant element indicative of ≥2–3°C cooler climate. This stepwise climatic sequence is seen at all late-glacial sites. Cool, humid interstadial conditions, punctuated by cold stadial climate, are characteristic of the last ≥40,000 ¹⁴C years of the Pleistocene at midlatitude in the Southern Hemisphere. Pollen sequences from southern South America and terrestrial–marine records from the New Zealand–Tasmania sector express a broad measure of synchrony of vegetational/climatic change for marine oxygen-isotope Stages 2–3. The data, combined with the timing of glacial maxima in the Southern Andes, Southern Alps of New Zealand, and in the Northern Hemisphere, are indicative of synchronous, millennial-scale, midlatitude climatic changes in the polar hemispheres.     

Interhemispheric Linkage of Paleoclimate During the Last Glaciation

Combined glacial geologic and palynologic data from the southern Lake District, Seno Reloncaví, and Isla Grande de Chiloé in middle latitudes (40°35’–42°25’S) of the Southern Hemisphere Andes suggest (1) that full-glacial or near-full-glacial climate conditions persisted from about 29,400 to 14,550 ¹⁴C yr BP in late Llanquihue time, (2) that within this late Llanquihue interval mean summer temperature was depressed 6°–8°C compared to modern values during major glacier advances into the outer moraine belt at 29,400, 26,760, 22,295–22,570, and 14,550–14,805 ¹⁴C yr BP , (3) that summer temperature depression was as great during early Llanquihue as during late Llanquihue time, (4) that climate deteriorated from warmer conditions during the early part to colder conditions during the later part of middle Llanquihue time, (5) that superimposed on long-term climate deterioration are Gramineae peaks on Isla Grande de Chiloé that represent cooling at 44,520–47,110 ¹⁴C yr BP (T-11), 32,105–35,764 ¹⁴C yr BP (T-9), 24,895–26,019 ¹⁴C yr BP (T-7), 21,430–22,774 ¹⁴C yr BP (T-5), and 13,040–15,200 ¹⁴C yr BP (T-3), (6) that the initial phase of the glacial/interglacial transition of the last termination involved at least two major steps, one beginning at 14,600 ¹⁴C yr BP and another at 12,700–13,000 ¹⁴ C yr BP , and (7) that a late-glacial climate reversal of ≥2–3° C set in close to 12,200 ¹⁴C yr BP , after an interval of near-interglacial warmth, and continued into Younger Dryas time. The late-glacial climate signal from the southern Chilean Lake District ties into that from proglacial Lago Mascardi in the nearby Argentine Andes, which shows rapid ice recession peaking at 12,400 ¹⁴C yr BP , followed by a reversal of trend that culminated in Younger-Dryas-age glacier readvance at 11,400–10,200 ¹⁴C yr BP . Many full- and late-glacial climate shifts in the southern Lake District match those from New Zealand at nearly the same Southern Hemisphere middle latitudes. At the last glacial maximum (LGM), snowline lowering relative to present-day values was nearly the same in the Southern Alps (875 m) and the Chilean Andes (1000 m). Particularly noteworthy are the new Younger-Dryas-age exposure dates of the Lake Misery moraines in Arthur's Pass in the Southern Alps. Moreover, pollen records from the Waikato lowlands on North Island show that a major vegetation shift at close to 14,700 ¹⁴C yr BP marked the beginning of the last glacial/interglacial transition (Newnham et al. 1989). The synchronous and nearly uniform lowering of snowlines in Southern Hemisphere middle-latitude mountains compared with Northern Hemisphere values suggests global cooling of about the same magnitude in both hemispheres at the LGM. When compared with paleoclimate records from the North Atlantic region, the middle-latitude Southern Hemisphere terrestrial data imply interhemispheric symmetry of the structure and timing of the last glacial/interglacial transition. In both regions atmospheric warming pulses are implicated near the beginning of Oldest Dryas time (～14,600 ¹⁴C yr BP) and near the Oldest Dryas/Bölling transition (～12,700–13,000 ¹⁴ C yr BP ). The second of these warming pulses was coincident with resumption of North Atlantic thermohaline circulation similar to that of the modern mode, with strong formation of Lower North Atlantic Deep Water in the Nordic Seas. In both regions, the maximum Bölling-age warmth was achieved at 12,200–12,500 ¹⁴ C yr BP , and was followed by a reversal in climate trend. In the North Atlantic region, and possibly in middle latitudes of the Southern Hemisphere, this reversal culminated in a Younger-Dryas-age cold pulse. Although changes in ocean circulation can redistribute heat between the hemispheres, they cannot alone account either for the synchronous planetary cooling of the LGM or for the synchronous interhemispheric warming steps of the abrupt glacial-to-interglacial transition. Instead, the dominant interhemispheric climate linkage must feature a global atmospheric signal. The most likely source of this signal is a change in the greenhouse content of the atmosphere. We speculate that the Oldest Dryas warming pulse originated from an increase in atmospheric water-vapor production by half-precession forcing in the tropics. The major thermohaline switch near the Oldest Dryas/Bölling transition then couldhave triggered another increase in tropical water-vapor production to near-interglacial values.     

Using computational intelligence techniques to model subglacial water systems

Measurements of water pressure beneath Trapridge Glacier, Yukon Territory, Canada show that the basal water system is highly heterogeneous. Three types of behaviour were recorded: pressure records which are strongly correlated, records which are strongly anticorrelated, and records which alternate between strong correlation and strong anticorrelation. We take the pressure in bore-holes that are connected to the evacuation route for basal water as the forcing, and the other pressures as the response to this forcing. Previous work (Murray and Clarke 1995) has shown that these relationships can be modelled using low-order nonlinear differential equations optimized by inversion. However, despite optimizing the model parameters we cannot be sure that the final model forms are themselves optimal. Computational intelligence techniques provide alternative methods for fitting models and are robust to missing or noisy data, applicable to non-smooth models, and attempt to derive optimal model forms as well as optimal model parameters. Four computational intelligence techniques have been used and the results compared with the more conventional mathematical model. These methods were genetic programming, artificial neural networks, fuzzy logic and self-organizing maps. We compare each technique and offer an evaluation of their suitability for modelling the pressure data. The evaluation criteria are threefold: (1) goodness of fit and an ability to predict subsequent data under different surface weather conditions; (2) interpretability, and the extent and significance of any new insights offered into the physics of the glacier; (3) computation time. The results suggest that the suitability of the computational intelligence techniques to model these data increases with the complexity of the system to be modelled.     

Deglacial palaeoclimate at Puerto del Hambre,subantarctic Patagonia,Chile

The primary objective of this study is to further substantiate multistep climatic forcing of late‐glacial vegetation in southern South America. A secondary objective is to establish the age of deglaciation in Estrecho de Magallanes–Bahía Inútil. Pollen assemblages at 2‐cm intervals in a core of the mire at Puerto del Hambre (53°36′21″S, 70°55′53″W) provide the basis for reconstructing the vegetation and a detailed account of palaeoclimate in subantarctic Patagonia. Chronology over the 262‐cm length of core is regulated by 20 AMS radiocarbon dates between 14 455 and 10 089 ¹⁴C yr BP. Of 13 pollen assemblage zones, the earliest representing the Oldest Dryas chronozone (14 455–13 000 ¹⁴C yr BP) records impoverished steppe with decreasing frequencies and loss of southern beech (Nothofagus). Successive 100‐yr‐long episodes of grass/herbs and of heath (Empetrum/Ericaceae) before 14 000 ¹⁴C yr BP infer deglacial successional communities under a climate of increased continentality prior to the establishment of grass‐dominated steppe. The Bølling–Allerød (13 000–11 000 ¹⁴C yr BP) is characterised by mesic grassland under moderating climate that with abrupt change to heath dominance after 12 000 ¹⁴C yr BP was warmer and not as humid. At the time of the Younger Dryas (11 000–10 000 ¹⁴C yr BP), grass steppe expanded with a return of colder, more humid climate. Later, with gradual warming, communities were invaded by southern beech. The Puerto del Hambre record parallels multistep, deglacial palaeoclimatic sequences reported elsewhere in the Southern Andes and at Taylor Dome in Antarctica. Deglaciation of Estrecho de Magallanes–Bahía Inútil is dated close to 14 455 ¹⁴C yr BP, invalidating earlier dates of between 15 800 and 16 590 ¹⁴C yr BP. Copyright © 2000 John Wiley & Sons, Ltd.     

The influence of channel morphology on bedload path lengths: Insights from a survival process model

Tracer studies are a commonly used tool to develop and test Einstein-type stochastic bedload transport models. The movements of these tracers are controlled by many factors including grain characteristics, hydrologic forcing, and channel morphology. Although the influence of these sediment storage zones related to morphological features (e.g., bars, pools, riffles) have long been observed to “trap” bedload particles in transport, this influence has not been adequately quantified. In this paper we explore the influence of channel morphology on particle travel distances through the development of a Bayesian survival process model. This model simulates particle path length distributions using a location-specific “trapping probability” parameter (p_i ), which is estimated using the starting and ending locations of bedload tracers. We test this model using a field tracer study from Halfmoon Creek, Colorado. We find that (1) the model is able to adequately recreate the observed multi-modal path length distributions, (2) particles tend to accumulate in trapping zones, especially during large floods, and (3) particles entrained near a trapping zone will travel a shorter distance than one that is further away. Particle starting positions can affect path lengths by as much as a factor of two, which we confirm by modelling “starting-location-specific” path length probability distributions. This study highlights the importance of considering both tracer locations and channel topography in examinations of field tracer studies. © 2020 John Wiley & Sons, Ltd.