The use of tracers to assess drill-mud penetration depth into sandstone cores during deep drilling: method development and application

For the utilization of deep saline aquifers in the frame of geotechnical use, such as geological sequestration of CO₂, H₂ or energy storage, a baseline characterization of pristine reservoir rock cores is required to monitor changes in the indigenous microbial communities and pore fluids, and to study alterations in rock characteristics resulting from interaction with geological storage technologies. However, drilling procedures and technical fluids, particularly drill mud, are sources of core contamination. To measure the penetration of drill mud into the cores, three tracers (fluorescein, microspheres, and 4′,6-diamidino-2-phenylindole stained bacteria) were tested under laboratory conditions. The flow of drill mud into core samples was induced by applying uniaxial pressure differentials to the core, and the penetration depth was microscopically determined for each tracer. Fluorescein was extracted from the rock samples and quantified fluorometrically. The results indicate that all tested tracers are suitable for tracking drill-mud penetration. The actual penetration depth seems to be related to differences in mineral composition and texture as well as microfractures. Among all tested tracers, fluorescein labelling is the simplest, cheapest and most accurate method for analyzing the contamination of rock cores by technical fluids. The application of this tracer was successfully applied during two deep drilling campaigns at the CO₂ storage pilot site in Ketzin, Germany. The results highlight that the use of tracers is indispensable to ensure the quality of core samples for microbiological and biogeochemical analysis.     

Interhemispheric Linkage of Paleoclimate During the Last Glaciation

Combined glacial geologic and palynologic data from the southern Lake District, Seno Reloncaví, and Isla Grande de Chiloé in middle latitudes (40°35’–42°25’S) of the Southern Hemisphere Andes suggest (1) that full-glacial or near-full-glacial climate conditions persisted from about 29,400 to 14,550 ¹⁴C yr BP in late Llanquihue time, (2) that within this late Llanquihue interval mean summer temperature was depressed 6°–8°C compared to modern values during major glacier advances into the outer moraine belt at 29,400, 26,760, 22,295–22,570, and 14,550–14,805 ¹⁴C yr BP , (3) that summer temperature depression was as great during early Llanquihue as during late Llanquihue time, (4) that climate deteriorated from warmer conditions during the early part to colder conditions during the later part of middle Llanquihue time, (5) that superimposed on long-term climate deterioration are Gramineae peaks on Isla Grande de Chiloé that represent cooling at 44,520–47,110 ¹⁴C yr BP (T-11), 32,105–35,764 ¹⁴C yr BP (T-9), 24,895–26,019 ¹⁴C yr BP (T-7), 21,430–22,774 ¹⁴C yr BP (T-5), and 13,040–15,200 ¹⁴C yr BP (T-3), (6) that the initial phase of the glacial/interglacial transition of the last termination involved at least two major steps, one beginning at 14,600 ¹⁴C yr BP and another at 12,700–13,000 ¹⁴ C yr BP , and (7) that a late-glacial climate reversal of ≥2–3° C set in close to 12,200 ¹⁴C yr BP , after an interval of near-interglacial warmth, and continued into Younger Dryas time. The late-glacial climate signal from the southern Chilean Lake District ties into that from proglacial Lago Mascardi in the nearby Argentine Andes, which shows rapid ice recession peaking at 12,400 ¹⁴C yr BP , followed by a reversal of trend that culminated in Younger-Dryas-age glacier readvance at 11,400–10,200 ¹⁴C yr BP . Many full- and late-glacial climate shifts in the southern Lake District match those from New Zealand at nearly the same Southern Hemisphere middle latitudes. At the last glacial maximum (LGM), snowline lowering relative to present-day values was nearly the same in the Southern Alps (875 m) and the Chilean Andes (1000 m). Particularly noteworthy are the new Younger-Dryas-age exposure dates of the Lake Misery moraines in Arthur's Pass in the Southern Alps. Moreover, pollen records from the Waikato lowlands on North Island show that a major vegetation shift at close to 14,700 ¹⁴C yr BP marked the beginning of the last glacial/interglacial transition (Newnham et al. 1989). The synchronous and nearly uniform lowering of snowlines in Southern Hemisphere middle-latitude mountains compared with Northern Hemisphere values suggests global cooling of about the same magnitude in both hemispheres at the LGM. When compared with paleoclimate records from the North Atlantic region, the middle-latitude Southern Hemisphere terrestrial data imply interhemispheric symmetry of the structure and timing of the last glacial/interglacial transition. In both regions atmospheric warming pulses are implicated near the beginning of Oldest Dryas time (～14,600 ¹⁴C yr BP) and near the Oldest Dryas/Bölling transition (～12,700–13,000 ¹⁴ C yr BP ). The second of these warming pulses was coincident with resumption of North Atlantic thermohaline circulation similar to that of the modern mode, with strong formation of Lower North Atlantic Deep Water in the Nordic Seas. In both regions, the maximum Bölling-age warmth was achieved at 12,200–12,500 ¹⁴ C yr BP , and was followed by a reversal in climate trend. In the North Atlantic region, and possibly in middle latitudes of the Southern Hemisphere, this reversal culminated in a Younger-Dryas-age cold pulse. Although changes in ocean circulation can redistribute heat between the hemispheres, they cannot alone account either for the synchronous planetary cooling of the LGM or for the synchronous interhemispheric warming steps of the abrupt glacial-to-interglacial transition. Instead, the dominant interhemispheric climate linkage must feature a global atmospheric signal. The most likely source of this signal is a change in the greenhouse content of the atmosphere. We speculate that the Oldest Dryas warming pulse originated from an increase in atmospheric water-vapor production by half-precession forcing in the tropics. The major thermohaline switch near the Oldest Dryas/Bölling transition then couldhave triggered another increase in tropical water-vapor production to near-interglacial values.     

Partition of radiotracers between suspended particles and seawater

Distinctive uptake mechanisms of different radiotracers by red clays in seawater are elucidated from the magnitude and change of distribution coefficients (K_d) for up to 17 γ-emitting radiotracers as functions of equilibration time, suspended particle concentration and compositions of solids and seawaters. The adsorption of ionic metals onto colloids and subsequent coagulation of colloids onto larger particles are the dominant removal processes of metals in the aquatic environments of low suspended particle concentration.     

收缩情境下城市用地结构时空格局演变及动力机制——以中国东北地区为例

构建城市用地结构时空格局演变分析框架,引入信息熵和偏移份额模型定量剖析2000-2017年中国东北地区城市用地结构时空格局演变特征,通过计量经济模型分阶段对比分析收缩情境下东北地区城市用地结构演变的动力机制.结果表明:东北地区城市用地总面积持续增长,用地结构信息熵整体呈现先上升、后下降的趋势.2011年以后,城市用地结...     

Biological influences on modern sulfates: Textures and composition of gypsum deposits from Guerrero Negro,Baja California Sur,Mexico

Gypsum (CaSO₄·2H₂O) deposits from a range of sedimentary environments at Guerrero Negro, Baja California Sur, Mexico were investigated for microscale texture and composition in order to differentiate features formed under substantial microbial influence from those for which microbial effects were relatively minor or absent. Gypsum deposits were classified according to their sedimentary environment, textures, crystal habit, brine composition and other geochemical factors. The environments studied included subaqueous sediments in anchialine pools and in solar salterns, as well as subsurface sediments of mudflats and saltpans. Gypsum that developed in the apparent absence of biofilms included crystals precipitated in the water column and subsedimentary discs that precipitated from phreatic brines. Subsedimentary gypsum developed in sabkha environments exhibited a sinuous microtexture and poikilitically enclosed detrital particles. Water column precipitates had euhedral prismatic habits and extensive penetrative twinning. Gypsum deposits influenced by biofilms included bottom nucleated crusts and gypsolites developing in anchialine pools and saltern ponds. Gypsum precipitating within benthic biofilms, and in biofilms within subaerial sediment surfaces provided compelling evidence of biological influences on crystal textures and habits. This evidence included irregular, high relief surface textures, accessory minerals (S°, Ca-carbonate, Sr/Ca-sulfate and Mg-hydroxide) and distinctive crystal habits such as equant forms and crystals having distorted prism faces.     

Matching solute breakthrough with deterministic and stochastic aquifer models

Two different deterministic and two alternative stochastic (i.e., geostatistical) approaches to modeling the distribution of hydraulic conductivity (K) in a nonuniform (sigma2ln(K)) = 0.29) glacial sand aquifer were used to explore the influence of conceptual model selection on simulations of three-dimensional tracer movement. The deterministic K models employed included a homogeneous effective K and a perfectly stratified 14 layer model. Stochastic K models were constructed using sequential Gaussian simulation and sequential i ndicator simulation conditioned to available K values estimated from measured grain size distributions. Standard simulation software packages MODFLOW, MT3DMS, and MODPATH were used to model three-dimensional ground water flow and transport in a field tracer test, where a pulse of bromide was injected through an array of three fully screened wells and extracted through a single fully screened well approximately 8 m away. Agreement between observed and simulated transport behavior was assessed through direct comparison of breakthrough curves (BTCs) and selected breakthrough metrics at the extraction well and at 26 individual multilevel sample ports distributed irregularly between the injection and extraction wells. Results indicate that conceptual models incorporating formation variability are better able to capture observed breakthrough behavior. Root mean square (RMS) error of the deterministic models bracketed the ensemble mean RMS error of stochastic models for simulated concentration vs. time series, but not for individual BTC characteristic metrics. The spatial variability models evaluated here may be better suited to simulating breakthrough behavior measured in wells screened over large intervals than at arbitrarily distributed observation points within a nonuniform aquifer domain.     

UML‐Based Approach to Developing a CityGML Application Domain Extension

Recently a national 3D standard was established in the Netherlands as a CityGML Application Domain Extension (called IMGeo). In line with the Dutch practice of modeling geo‐information, the ADE is developed using a model driven approach. The classes are designed in UML and automatically mapped to GML schema. The current OGC CityGML specification does not provide rules or guidance on correctly modeling an ADE in UML. This article fills this gap by studying how CityGML can be extended for specific applications starting from the UML diagrams. Six alternatives for modeling ADEs in UML are introduced and compared. The optimal alternative is selected and applied to obtain the national 3D standard. The approach was extensively discussed with international experts, who were members of both SIG3D and other working groups. As a consequence the approach was adopted by the SIG3D, the Special Interest Group 3D which, among other things, work on the 3D standard CityGML in cooperation with OGC. Therefore the approach contains many issues that can be generalized and reused by future domain extensions of CityGML. To further support this, the article formulates a model‐driven framework to model CityGML ADEs. Open issues are described in the conclusions.