The uptake and solubility of water in quartz at elevated pressure and temperature

The uptake of water in quartz at 1.5 GPa total pressure, 1173 K and high water fugacity, over times up to 24 h, has been investigated using a newly developed assembly to prevent microcracking. It is found that the uptake is small, and below the detectability of the presently used technique of infrared spectroscopy and serial sectioning. This observation reflects either a low value for the diffusivity or the solubility or a combination of both, and is in agreement with the observations of Kronenberg et al. (1986) and Rovetta et al. (1986). It brings into question the interpretation of the early experiments on water weakening by Griggs and Blacic (1964) and the recent estimates of the solubility and diffusivity by Mackwell and Paterson (1985). Rults of a combined T.E.M., light-scattering and infrared-spectroscopy investigation of ‘wet’ synthetic quartz before and after heating at 0.1, 300 and 1500 MPa total pressure and 1173 K, strongly suggest that the water in ‘wet’ quartz is mainly in the form of H₂O in inclusions, consistent with the solubility being low, possibly less than 100 H/10⁶Si. From these observations, water-containing inclusions appear to play a major role in the plasticity of quartz, while any role of water in solid solution remains to be clarified.     

Effects of multiple stressors on lakes in south-central Ontario: 15 years of change in lakewater chemistry and sedimentary diatom assemblages

Freshwater ecosystems are increasingly affected by human influences. Since the pre-industrial era, lakes of the Muskoka–Haliburton region of south-central Ontario have had increases in shoreline residential development and acid deposition. Previous research on 54 of these lakes, using sediment cores and diatom-based transfer functions, showed changes in lakewater pH and total phosphorus concentration between the preindustrial era and 1992. Since 1992, there has been further change, which we have documented for the same set of lakes, using similar methods. For example, dissolved organic carbon has increased and there have been significant increases in planktonic diatoms (e.g. Cyclotella stelligera) commonly associated with climate warming. More striking diatom changes have occurred in the past 15 years than between pre-industrial times and 1992. Significant changes observed in both chemical (e.g. pH, Ca, DOC) and biological data suggest that novel stressors, such as declines in lake calcium concentrations, acting in conjunction with climate and land-use change, have created ecosystems for which there are no historical analogs.     

The Effectiveness of Arsenic Remediation from Groundwater in a Private Home

Private wells are the source of drinking water for approximately 15% of households in the United States, but these wells are not regulated or monitored by government agencies. The well waters can contain arsenic, a known carcinogen that occurs in groundwater throughout the nation at concentrations that can exceed the Maximum Contaminant Level defined by the U.S. Environmental Protection Agency (10 ppb). In order to reduce arsenic exposure, homeowners can either rely on bottled water for drinking or install in-house water treatment systems for arsenic removal. Here, we document the arsenic levels associated with these options. We examined 24 different major bottled water brands and found that all have arsenic levels <1.5 parts per billion (ppb), and more than half have levels below our measurement detection limit of 0.005 ppb. For in-house treatment systems, we examined the performance of arsenic removal by point-of-use reverse osmosis filtration, and by whole-house and point-of-use filters containing granulated ferric oxide. Our results show that long-term (2 years) filtration with granulated ferric oxide reduced arsenic in well water from an initial concentration of 4 to 9 ppb down to <0.005 ppb, validating this technology as an effective form of arsenic remediation for private homes.     

Drought in Northeast Brazil—past,present, and future

This study provides an overview of the drought situation in Northeast Brazil for the past, present, and future. Droughts affect more people than any other natural hazard owing to their large scale and long-lasting nature. They are recurrent in the region and while some measures have been taken by the governments to mitigate their impacts, there is still a perception that residents, mainly in rural areas, are not yet adapted to these hazards. The drought affecting the Northeast from 2012 to 2015, however, has had an intensity and impact not seen in several decades and has already destroyed large swaths of cropland, affecting hundreds of cities and towns across the region, and leaving ranchers struggling to feed and water cattle. Future climate projections for the area show large temperature increases and rainfall reductions, which, together with a tendency for longer periods with consecutive dry days, suggest the occurrence of more frequent/intense dry spells and droughts and a tendency toward aridification in the region. All these conditions lead to an increase in evaporation from reservoirs and lakes, affecting irrigation and agriculture as well as key water uses including hydropower and industry, and thus, the welfare of the residents. Integrating drought monitoring and seasonal forecasting provides efficient means of assessing impacts of climate variability and change, identifying vulnerabilities, and allowing for better adaptation measures not only for medium- and long-term climate change but also for extremes of the interannual climate variability, particularly droughts.

     

A new mechanism for the magnetic enhancement of hematite during heating: the role of clay minerals

The magnetic properties of loess, lake, and ocean sediments are often used as indicators for paleoclimatic/paleoenvironmental changes. Thermomagnetic analysis is a conventional approach for identifying magnetic phases and thermal alteration of samples. Magnetic concentration parameters are often enhanced after thermal treatment. In this study, the role of clay minerals in magnetic enhancement at elevated temperatures is systematically investigated. The results indicate that the clay minerals (saponite, Ca-montmorillonite, kaolinite, and chlorite) are dominated by paramagnetic behaviour and that the magnetic properties remain relatively stable after heating to 700°C in argon. In contrast, mixtures of hematite and chlorite have a high degree of magnetic enhancement after heating in argon, which indicates that clay minerals play important role in magnetic enhancement. These results improve our understanding of the processes involved in complicated mineral transformations, which is important for retrieving paleoclimatic/paleoenvironemntal signals from magnetic proxies.     

Adaptations of microphytobenthos assemblages to sediment type and tidal position

Tagus intertidal microphytobenthos (MPB) assemblages were characterized over a wide range of sediment type and tidal height and the possible effects of these variables on MPB spatial distribution and photo-adaptation mechanisms were investigated. Two transects with six different sediment type and different tidal height sites were sampled once every two months from 2002 to 2004. Upper shore and sandy sites showed higher chlorophyll a (chl a) content, with sandy sediments showing a biomass peak in late winter–early spring, and muddy sites showing no obvious seasonal pattern. Stepwise multiple linear regressions showed that only SiO₂, tidal height and sediment particle size <63 μm were significant variables (p<0.05), explaining 50% of MPB biomass spatial–temporal variability. However, when data were separated by transect, only tidal height remained significant at both transects. Sandier sediments exhibited higher zeaxanthin/chl a and lower fucoxanthin/chl a ratios characteristic of a mixed cyanobacteria/diatom assemblages, showing an alternate seasonality with cyanobacteria increasing in summer and diatoms dominating in spring. Diatom biofilms showed contrasting features depending on the sediment type. Epipsammic diatoms were small with an average length of around 10 μm, while epipelic diatoms showed a wider size range with size distribution peaks at 10–15 μm, 25–35 μm and >60 μm. Epipelic biofilms showed evidence of being low light-acclimated (high fucoxanthin/chl a) and of photo-regulating by vertical migration movements (presence of endogenous vertical rhythms and lower diatoxanthin/diadinoxanthin). Epipsammic biofilms showed higher diatoxanthin/diadinoxanthin ratios and no vertical migration rhythms. Thus, the two diatom biofilm types had distinct strategies to photo-regulate: epipelic diatoms using vertical migration to position themselves at the sediment depth of optimum light conditions, and epipsammic diatoms using the xanthophyll cycle to photo-regulate. Further studies comparing epipsammic and epipelic assemblages are necessary to better understand MPB photo-regulation mechanisms.     

Meteoric diagenesis during sea-level lowstands: Evidence from modern hydrochemical studies on northern Guam

Hydrochemical data for meteoric waters of the uplifted carbonate platform of northern Guam show that, contrary to recent models of lowstand diagenesis, phreatic dissolution is active beneath a 60–180 m thick vadose zone. Overland flow during high intensity rainfall events is focussed into surface detention ponds, which drain very rapidly via the epikarst and vertical fissures to the freshwater lens. We estimate that these waters contribute 13% of dissolved calcium in samples from pumping wells but may also deliver aggressive and/or organic-rich waters to the lens. Fast-flow vadose waters mix with lens-top waters to form fresher cap that discharges rapidly coastwards via cavernous porosity. Slower vadose percolation, sampled as cave drips, equilibrates with bedrock within the upper 30 m of the vadose zone, accounting for some 46% of dissolved calcium in the lens waters. The remaining 41% calcium is generated by net dissolution within the lens.     

Igneous origin of K-feldspar megacrysts in deformed granite of the Papoose Flat Pluton, California, USA

Many points of evidence, especially igneous microstructures and structures resulting from solid-state deformation, indicate that K-feldspar megacrysts in deformed granites of the Papoose Flat pluton are residual phenocrysts, not porphyroblasts. Evidence of an igneous origin includes features such as crystal shapes, simple twinning, zonally arranged euhedral plagioclase inclusions, oscillatory compositional zoning, and local occurrence in microgranitoid enclaves. Evidence of solid-state deformation of the megacrysts (which is consistent with their existence prior to the mylonitic deformation) includes marginal recrystallization and neocrystallization, microcline twinning, marginal replacement by myrmekite, and recrystallized/neocrystallized “tails”. Evidence of porphyroblastic growth, such as overgrown inclusion trails, is absent. This appears to be the situation in most felsic augen gneisses and mylonites.     

Analysis of a core through the Meighen Ice Cap,Arctic Canada,and its paleoclimatic implications

Analyses of crystal size, bubble content, oxygen isotope ratio, specific electrolytic conductivity, and the distribution of firn and dirt layers in a core, 121.2 m long, from surface to bedrock near the highest point of the Meighen Ice Cap, leads to the following outline of the ice cap's history. The ice cap, which has always been stagnant, originated in the cold period that followed the postglacial Climatic Optimum. After initial growth came a period of negative mass balance in which the area and thickness of the ice cap diminished and the surface slope at the core site steepened. The end of this period, at least 600 y.a., is marked by a discontinuity at 54 m depth in the core; above this level, the values of most parameters differ significantly from their values below. There followed a period of growth by the end of which, some 80 y.a., the ice cap had attained its maximum thickness; this period included the coldest interval in the ice cap's history. Ablation has predominated since then and up to 13 m of ice have been lost at the core site. This history resembles that of the Ward Hunt Ice Shelf.