时域反射仪在监测青藏高原活动层水分变化过程中的应用

时域反射仪（ＴＤＲ）是一种利用电磁脉冲方法,根据电磁波在土层中的传播速度测试不同土层 的介电常数,接介电常数值可获不同土类在冻融状态下的未冻水含量和总体积含水量．ＴＤＲ仪可在 野外环境下无破损地测得融土和冻土的液态水含量,尤其是能测出不同负温下冻土中未冻水的变 化．该仪器最适用于测量均质细颗粒土的体积含水量,经与烘干称重法对比,ＴＤＲ仪应用在青藏高 原上不同融土类所测含水量值的误差范围：粉土和细砂为±２．５％,粘土和亚粘土为±３．０％,砂砾石 土和碎石土为±５％．经过反复的野外实践证明,用 ＴＤＲ仪测上层含水量具有简便、快速及稳定等 优点,是值得推广的方法．根据青藏公路沿线８个场地埋置的ＴＤＲ仪和地温仪所获的一个年周期的 水、热资料（１９９７．８～１９９８．７）,分析了高原活动层在冻融过程中温度场和水分场的耦合所导致的水分迁移及水分场重分布的规律     

Solar flare injection and propagation of low-energy protons and electrons in the event of 7–9 July, 1966

Simultaneous observations of the 7–9 July 1966 solar particle event by energetic particle detectors on three satellites, IMP-III, OGO-III and Explorer 33 are utilized to show that large spatial gradients are present in the fluxes of 0.5–20 meV protons and 45 keV electrons. The event is divided into three parts: the ordinary diffusive component, the halo, and the core. The core corotates with the interplanetary field, and therefore it and the surrounding halo are interpreted as spatial features which are connected by the interplanetary magnetic field lines to the vicinity of the flare region. Upper limits to the interplanetary transverse diffusion coefficient for 4–20 meV protons at 1 AU are derived from the width of the halo. These are at least two orders of magnitude less than the parallel diffusion coefficient for the same energy particles.It is argued that the observed flux variations cannot be explained by an impulsive point source injection for any physically reasonable diffusion model. Instead, since the interplanetary transverse-diffusion coefficient is small for these low-energy particles, the observed spatial features are interpreted as the projection to 1 AU by the interplanetary field lines of an extensive injection profile at the sun. The geometry of the injection mechanism is discussed and it is suggested that some temporary storage of the flare particles occurs near the sun.Now at NASA, Goddard Space Flight Center, Greenbelt, Md., U.S.A.     

基于遥感的江苏省大陆岸线岸滩时空演变

基于江苏省1984-2016年61景多源遥感影像数据和部分实测潮位、坡度数据,利用遥感技术结合改进的水边线方法提取了多时相的海岸线和平均大潮低潮线,研究了江苏省绣针河口至连兴河口大陆岸线岸滩的时空演变特征。结果表明：1984-2016年,由于海岸带开发,江苏省的海岸线整体以向海推进为主,自然岸线由458.24 km逐渐减少至166.74 km,人工岸线由163.66 km快速增加至598.74 km,大陆岸线长度由621.90 km增加至765.48 km。发生位置和长度变化的岸段中,淤长岸段长127.62 km,年均向海推进83.03 m;围垦岸段长401.21 km,年均向海推进87.63 m;冲刷岸段长71.17 km,年均离海后退10.81 m;围垦被侵蚀岸段长25.95 km,年均离海后退8.64 m。海岸线的空间变化导致江苏省沿海陆地面积净增加104332 hm²,其中由于围垦增加的陆地面积98520 hm²,围垦是陆地面积增加的主要原因。海岸线的离海后退主要发生在废黄河三角洲岸段,但是到2008-2016年,岸线的侵蚀范围已向南扩大至新洋河口至斗龙港岸段。受围垦活动及岸线侵蚀影响,江苏省潮间带坡度不断变陡,统计断面的平均坡度由1.4‰增加至1.9‰,其中废黄河三角洲岸段的中山河口至扁担河口岸段坡度最陡,基本在3~14‰之间;辐射沙洲陆岸岸段坡度最为平缓,但坡度也在逐渐陡化,由0.9‰增加至1.5‰。潮间带面积由271747 hm²减少至168645 hm²,减幅38%;潮间带平均宽度由5064 m减少至3096 m,减幅39%。     

混合吸附剂分离富集-电感耦合等离子体质谱法测定地质样品中铂钯金

贵金属分析应用火试金法分离富集时,试金配料复杂、耗时较长,分析成本相对较高,空白较难控制.本文建立了采用过氧化氢-盐酸湿法分解样品,电感耦合等离子体质谱同时测定地质样品中Pt、Pd、Au的分析方法.在10％的盐酸介质中,以LSC-400巯基树脂和活性炭为混合吸附剂,采用动态吸附方式对样品中的Pt、Pd、Au分离富集,用Lu作内标元素,195 Pt、197 Au、108 Pd为待测同位素消除了非谱线干扰和谱线干扰,三元素的回收率均大于96.4％.方法检出限(3σ):Pt为0.06 ng/g,Pd为0.08 ng/g,Au为0.12 ng/g,优于火试金等其他分离富集方法的检出限.应用于测定国家标准物质,Pt、Pd、Au的测定结果与标准值相符,12次测定的相对标准偏差均小于16.1％,满足区域地球化学调查样品的分析要求.该方法操作简便、成本低廉,提高了分析速度,有效地降低了测试过程的空白值.     

海南岛“0810”特大暴雨物理量诊断及多普勒特征分析

应用常规观测、海口多普勒回波及NCEP1×1°再分析等资料,对2008年10月12～15日海南特大暴雨成因进行诊断分析,并揭示了暴雨过程中的多普勒回波特征。结果表明：导致海南岛产生强降水的主要原因是热带低压移动缓慢和弱冷空气的低层入侵;当冷暖空气交绥,大气温湿结构发生突变,θse面陡立造成对流系统斜压发展,激发位势不稳定能量释放。正差动假相当位温平流意味着低层暖湿空气的平流大于高层,加强了层结对流不稳定发展;在斜压扰动作用下,对流层中层正差动涡度平流和低压东侧的暖平流破坏了海南岛的准地转平衡,动力强迫和热力强迫共同作用激发了次级环流,导致暴雨区上空的垂直运动的发展,促使暴雨增强。充沛的水汽输送及水汽的强烈辐合,为暴雨发生的有利水汽条件。多普勒径向速度揭示了暴雨区低层冷平流高层暖平流、风向风速的垂直切变大的垂直结构以及持续性的强烈辐合等等特征,回波停滞和＂列车效应＂使降水增幅,降水回波的性质差异,可造成强降水区域分布的不同。     

台湾地形对台风Meranti(1010)经过海峡地区时迅速增强的影响研究

台风在趋近大陆过程中强度一般衰减, 但Meranti(1010)北上进入台湾海峡过程中却迅速加强, 且在登陆福建时达到最强。采用中国气象局台风资料、NCEP GFS 0.5°×0.5°再分析资料及台湾雷达资料, 结合中尺度数值模式WRF(The Weather Research and Forecasting Model)开展台湾地形敏感性试验, 研究Meranti进入台湾海峡过程中的结构变化及迅速加强机理。结果表明:台湾地形是Meranti迅速加强的一个重要影响因子。Meranti北上过程中, 一方面通过台湾岛地形分流作用及其背风坡效应在台湾海峡内诱生中尺度涡旋, 形成正负相间的涡度分布, 激发出与台风相关的扰动波列。地形强迫抬升及扰动波列可加强垂直运动和积云对流, 有利于台风对流发展。另一方面, 台湾地形还通过改变环境气流使台风高空辐散场加强, 环境风垂直切变减小, 形成有利于台风发展的环流背景。比较不同高度台湾地形试验中台风动能收支发现, 台湾地形激发的扰动波列和积云对流增强了次网格尺度系统与台风间能量的交换, 成为Meranti登陆前迅速加强的主要动能源。     

Ca, Al-rich inclusions in Yamato 791717 (CO3) carbonaceous chondrite: Formation and alteration

In three polished thin sections of Yamato 791717 (CO3). fifty-five Ca, Al-rich inclusions were found, which include two hibonite-bearing, eight melilite-rich and forty-five spinel-pyroxene inclusions. Based on the petrography and mineral chemistry of the inclusions, it is proposed that the melilite-rich inclusions and spinel-pyroxene inclusions condensed in the solar nebula, and the hibonite-bearing inclusions crystallized from melts. The heavy alteration of the inclusions in Yamato 791717, which probably took place under a very oxidizing condition in the solar nebular, is also confirmed. Project supported by the National Natural Science Foundation of China (Grant No. 49673200). and by the Japanese Society for Promotion of Sciences (JSPS).     

Influence of Surfactants on Degradation of 1‐(2‐Chlorobenzoyl)‐3‐(4‐chlorophenyl) Urea by Nanoscale Zerovalent Iron

Nanoscale zerovalent iron (NZVI) has been proved to be effective in the degradation of environmental pollutants and exhibits advantages in the removal of 1‐(2‐chlorobenzoyl)‐3‐(4‐chlorophenyl) urea (CCU), an analog of diflubenzuron. This present study focused on the influence of surfactants in the degradation procedure with NZVI in order to provide a simple and rapid removal method for CCU. Triton X‐100, Tween 20, Tween 80, sodium dodecyl sulfonate (SDS), and cetyltrimethylammonium bromide (CTAB) were investigated under anaerobic conditions. The experimental results demonstrated that the degradation rate increased sharply with the presence of SD during the first 15 min, up to 99.97% with addition of 0.01 g L^?1 SDS, whereas the presence of Triton X‐100, Tween 80, and Tween 20 resulted in a slight enhancement of the degradation of CCU. The enhancement strength of them was in the order Tween 20, Triton X‐100, and Tween 80. However, addition of the cationic surfactant CTAB resulted in a significant inhibitive effect. In contrast, the mixed surfactants did not result in the expected performance, and the performance was lower than that using some certain single surfactant among the mixed surfactants.     

台风“梅花”风浪场和涌浪场特征分析

基于第三代海浪数值模式WAVEWATCHⅢ(v3.14),在WRF模式提供模式风场驱动下,对1109号台风"梅花"的风浪场、涌浪场和混合浪场进行了数值模拟,并在我国东部沿海选取了3个关注站点,探讨涌浪和风浪波高随时间变化与台风中心位置的关系以及台风影响下海浪二维谱、风浪场和涌浪场分布和变化特征。结果表明,新版的海浪模式能较好表现福建和浙江沿海、长江口附近、山东半岛南端的3个关注区域的台风涌浪先于风浪到达的事实;距台风中心不同距离,混合浪波高的组成和波高变化不同;台风的外围区涌浪场的高值区对应着风浪场的低值区,台风的大风区风浪场的高值区对应着涌浪场的低值区,台风眼区则为涌浪区。涌浪多分布在台风风浪影响范围之外,波向由台风中心向外辐射。     

Concentrations of metallic elements in long-range-transported aerosols measured simultaneously at three coastal sites in China and Japan

To determine the effects of long-range transport of aerosols from an upwind area in East Asia to a downwind area in Japan, we chemically analyzed aerosols collected simultaneously on Tuoji Island (Shandong Province, China), Fukue Island (Nagasaki Prefecture, Japan), and Cape Hedo (Okinawa Prefecture, Japan). We focused on changes in the metallic composition of PM_2.5 aerosols during long-range transport. The average mass concentrations of PM_2.5 at the three sites decreased in the order Tuoji Island > Fukue Island ≈ Cape Hedo (48.3 ± 4.5, 13.9 ± 1.5, and 13.2 ± 0.9 μg/m³, respectively). The fraction of coarse particles in total suspended particles estimated by (1–PM_2.5/TSP) was highest on Cape Hedo, indicating that the contribution of sea salts was increased by long-range transport of the aerosols over the ocean. Enrichment factor analysis revealed that at all three sites, Al, K, Ca, Mn, Fe, Co, Sr, and Ba originated from soil; whereas Cr, Ni, Cu, Zn, As, Mo, Ag, Cd, Sn, Sb, Tl, and P appeared to be of anthropogenic origin. Na was the most abundant element on Cape Hedo, indicating the addition of sea salts during aerosol transport. The V concentration was highest at Fukue Island, which was ascribed to V emission from ships. Sixty-one percent of the V on Fukue Island and 62% of the V on Cape Hedo were determined to have originated from ships, implicating of data obtained on dates during which backward trajectory analysis indicated that the same air mass passed over Tuoji Island, Fukue Island, and Cape Hedo in that order.